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Thin Films of La1-xSmxVO4:Ca Luminescent Vanadate Nanoparticles Deposited with Various Methods on Glass Substrates

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Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications (NANO 2020)

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Abstract

Thin films containing luminescent active vanadate nanoparticles were applied by spin-coating, solution evaporation and pulsed laser deposition methods on glass substrates. The films are formed by pure vanadate layers as well as by silicon gel layers used as matrices and incorporated with vanadate nanocrystallites. Morphology of the films was studied using optical, atomic force and scanning electron microscopy. It was shown that films obtained from the same compositions but under different procedures have different morphology. Optical properties of the films were studied using absorption, reflection and luminescence spectroscopy in comparison with properties of the initial vanadate nanoparticles. Influence of procedure methods and growth conditions on spectral characteristics of the films was discussed. Advantages and disadvantages of the noted methods of luminescent films growing from vanadate nanoparticles were studied and discussed.

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Abbreviations

LED:

Light emitting diode

PLD:

Pulsed laser deposition

RE:

Rare earth

SC:

Spin coating

SE:

Solution evaporation

SEM:

Scanning electron microscopy

UV:

Ultraviolet

XRD:

X-ray diffraction.

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Acknowledgements

This work has received funding from Ministry of Education and Science of Ukraine (University’s Science Grant Program and Bilateral Grant Program) and from the EU-H2020 research and innovation program under grant agreement No 654360 having benefited from the access provided by Institute of Electronic Structure & Laser (IESL) of Foundation for Research & Technology Hellas (FORTH) in Heraklion, Crete, Greece, Division of Microscopy, Universitat Autonoma de Barcelona, Spain, and Paul Scherrer Institut (PSI), Villigen, Switzerland, within the framework of the NFFA-Europe Transnational Access Activity. Authors thank Dr. Dimitrios Kazazis (PSI) for his kind support with the thin film metrology experiments.

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Correspondence to O. V. Chukova .

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Chukova, O.V. et al. (2021). Thin Films of La1-xSmxVO4:Ca Luminescent Vanadate Nanoparticles Deposited with Various Methods on Glass Substrates. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . NANO 2020. Springer Proceedings in Physics, vol 263. Springer, Cham. https://doi.org/10.1007/978-3-030-74741-1_25

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