Abstract
Rare earth elements, by virtue of their role in technological advancements, have become critical commodities over the last few decades. The emerging awareness of environmental pollution associated with primary ore mining and the need for processes to preserve these non-renewable minerals, coupled with the attempt to break China’s monopoly of the REEs production and commercialization, has led to research into alternative sources. The crusade for beneficial use of coal combustion products and the proposal that these CCPs are REE-rich sources have therefore received a widespread attention among other alternatives. This chapter seeks to explain the feasibility of the extraction of REEs from CCPs using ionic liquids. The ability to modify ILs to suit the application necessities allows for extraction at better experimental conditions reducing the overall waste generation of the process. Different types of ionic liquids have been studied for rare earth elements recovery and recycling from secondary sources (scraps, electronic waste) using nonfunctional, monofunctional, and bifunctional ionic liquids. However, the recovery of REEs from the by-products of coal combustion has not been studied in depth despite of them being a rich source of these technological key elements.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Abbott, A. P., et al. (2011). Processing of metals and metal oxides using ionic liquids. Green Chemistry, 13(3), 471–481. https://doi.org/10.1039/c0gc00716a.
Adams, T. H. (2019). Coal ash recycling rate declines amid shifting production and use patterns, 19 November, pp. 1–5. Available at: https://www.prnewswire.com/news-releases/coal-ash-recycling-rate-declines-amid-shifting-production-and-use-patterns-300961238.html
American Coal Ash Association (2017). Beneficial use of coal combustion products, pp. 1–8.
American Coal Ash Association (2019). Coal combustion products production & use statistics, production & use reports.
Chauhan, G., et al. (2018). Novel technologies and conventional processes for recovery of metals from waste electrical and electronic equipment: Challenges & opportunities—A review. Journal of Environmental Chemical Engineering, 6(1), 1288–1304. https://doi.org/10.1016/j.jece.2018.01.032.
Chen, J., et al. (2016a). Extraction behavior of bifunctional ionic liquid [N1888][SOPAA] and TBP for rare earth elements. Journal of Rare Earths, 34(12), 1252–1259. https://doi.org/10.1016/S1002-0721(16)60161-8.
Chen, L., et al. (2016b). Comprehensive appraisal and application of novel extraction system for heavy rare earth separation on the basis of coordination equilibrium effect. Hydrometallurgy, 165, 351–357. https://doi.org/10.1016/j.hydromet.2015.12.007.
Chou, M.-I. M. (2012). Fly Ashfly ash. In R. A. Meyers (Ed.), Encyclopedia of sustainability science and technology (pp. 3820–3843). New York, NY: Springer New York. https://doi.org/10.1007/978-1-4419-0851-3_121.
Cueva Sola, A. B., et al. (2020). Rare-earth metal recovery for green technologies, rare-earth metal recovery for green technologies. In R. K. Jyothi (Ed.). Cham: Springer International Publishing. https://doi.org/10.1007/978-3-030-38106-6.
Davis, J. H. (2004). Task-specific ionic liquids., 33(9), 1072–1077. https://doi.org/10.1246/cl.2004.1072.
Dietz, M. L. (2006). Ionic liquids as extraction solvents: Where do we stand? In Separation science and technology (pp. 2047–2063). Taylor & Francis Group. https://doi.org/10.1080/01496390600743144.
Dong, Y., et al. (2017). A separation processing for industrial rare earth feed solution by phosphonium ionic liquid type saponification strategy. Journal of Rare Earths, 35(3), 290–299. https://doi.org/10.1016/S1002-0721(17)60912-8.
Dupont, D., & Binnemans, K. (2015). Recycling of rare earths from NdFeB magnets using a combined leaching/extraction system based on the acidity and thermomorphism of the ionic liquid [Hbet][Tf2N]. Green Chemistry, 17(4), 2150–2163. https://doi.org/10.1039/c5gc00155b.
Dutta, T., et al. (2016). Global demand for rare earth resources and strategies for green mining. Environmental Research, 150, 182–190. https://doi.org/10.1016/j.envres.2016.05.052.
Gasparotto, J., & Da Boit Martinello, K. (2020). Coal as an energy source and its impacts on human health. Energy Geoscience. https://doi.org/10.1016/j.engeos.2020.07.003.
Guo, L., et al. (2014). Highly selective extraction and separation of rare earths(III) using bifunctional ionic liquid extractant. ACS Sustainable Chemistry and Engineering, 2(8), 1968–1975. https://doi.org/10.1021/sc400541b.
Habashi, F. (1997). Handbook of extractive metallurgy. Wiley (Handbook of Extractive Metallurgy). from https://books.google.co.kr/books?id=S6BlxwEACAAJ.
Habashi, F. (2005). A short history of hydrometallurgy. Hydrometallurgy, 79(1–2), 15–22. https://doi.org/10.1016/j.hydromet.2004.01.008.
Harris, D., Heidrich, C. and Feuerborn, J. (2019). Global Aspects on Coal Combustion products. Available at: https://www.coaltrans.com/insights/article/global-aspects-on-coal-combustion-products
Heidrich, C., Feuerborn, H. and Weir, A. (2013) ‘Coal Combustion Products : a Global Perspective’, in 2013 World of Coal Ash (WOCA) Conference. Lexington. Available at: http://www.flyash.info/2013/171-Heidrich-Plenary-2013.pdf
Hidayah, N. N., & Abidin, S. Z. (2017). The evolution of mineral processing in extraction of rare earth elements using solid-liquid extraction over liquid-liquid extraction: A review. Minerals Engineering, 112(March), 103–113. https://doi.org/10.1016/j.mineng.2017.07.014.
Huang, C., et al. (2017). Efficient and sustainable regeneration of bifunctional ionic liquid for rare earth separation. ACS Sustainable Chemistry and Engineering, 5(4), 3471–3477. https://doi.org/10.1021/acssuschemeng.7b00159.
Huang, C., et al. (2019). The recovery of rare earth elements from coal combustion products by ionic liquids. Minerals Engineering, 130(August 2018), 142–147. https://doi.org/10.1016/j.mineng.2018.10.002.
Huddleston, J. G. et al. (1998). ‘Room temperature ionic liquids as novel media for “clean” liquid—liquid extraction’, Chem. Commun., (16), pp. 1765–1766. https://doi.org/10.1039/A803999B.
Hurst, C. (2010). ‘China ’ s Rare Earth Elements Industry’, Institute for the Analysis of Global Security (IAGS), (March), p. 6.
Jacobson, T. A., et al. (2019). Direct human health risks of increased atmospheric carbon dioxide. Nature Sustainability, 2(8), 691–701. https://doi.org/10.1038/s41893-019-0323-1.
Jensen, M. P., et al. (2003). Mechanisms of metal ion transfer into room-temperature ionic liquids: The role of anion exchange. Journal of the American Chemical Society, 125(50), 15466–15473. https://doi.org/10.1021/ja037577b.
Kitto, J. (1996). Developments in pulverized coal-fired boiler technology, Missouri Valley Electric Association Engineering Conference, (September), pp. 1–11.
Ku, T., et al. (2017). Synergistic effects of particulate matter (PM2.5) and sulfur dioxide (SO2) on neurodegeneration via the microRNA-mediated regulation of tau phosphorylation. Toxicology Research, 6(1), 7–16. https://doi.org/10.1039/c6tx00314a.
Li, J., et al. (2018). A review on the applications of coal combustion products in China. International Geology Review, 60(5–6), 671–716. https://doi.org/10.1080/00206814.2017.1309997.
Lin, C. K., et al. (2019). A global perspective on coal-fired power plants and burden of lung cancer. Environmental Health: A Global Access Science Source, 18(1), 1–11. https://doi.org/10.1186/s12940-019-0448-8.
Liu, H. (2016) RARE EARTHS : SHADES OF GREY—Can China Continue To Fuel Our Global Clean & Smart Future, pp. 1–63.
Looney, B. (2020). ‘Statistical Review of World Energy’, Bp, 69, p. 66. Available at: https://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdfs/energy-economics/statistical-review/bp-stats-review-2020-full-report.pdf.
Mancheri, N. A., et al. (2019). Effect of Chinese policies on rare earth supply chain resilience. Resources, Conservation and Recycling, 142, 101–112. https://doi.org/10.1016/j.resconrec.2018.11.017.
Mehdi, H., et al. (2010). Hydrophobic ionic liquids with strongly coordinating anions. Chemical Communications, 46(2), 234–236. https://doi.org/10.1039/b914977e.
Miller, B. G. (2017). The effect of coal usage on human health and the environment. Clean Coal Engineering Technology. https://doi.org/10.1016/b978-0-12-811365-3.00003-x.
Mohapatra, P. K., et al. (2013). A novel CMPO-functionalized task specific ionic liquid: Synthesis, extraction and spectroscopic investigations of actinide and lanthanide complexes. Dalton Transactions, 42(13), 4343–4347. https://doi.org/10.1039/c3dt32967d.
Munawer, M. E. (2018). Human health and environmental impacts of coal combustion and post-combustion wastes. Journal of Sustainable Mining, 17(2), 87–96. https://doi.org/10.1016/j.jsm.2017.12.007.
Nakashima, K., et al. (2003). Ionic liquids as a novel solvent for lanthanide extraction. Analytical Sciences, 19(8), 1097–1098. https://doi.org/10.2116/analsci.19.1097.
Nakashima, K., et al. (2005). Feasibility of ionic liquids as alternative separation media for industrial solvent extraction processes. Industrial and Engineering Chemistry Research, 44(12), 4368–4372. https://doi.org/10.1021/ie049050t.
Renner, R. (2001). Ionic liquids: An industrial cleanup solution. Environmental Science and Technology. https://doi.org/10.1021/es012505a.
Rose, J. J., et al. (2017). Carbon monoxide poisoning: Pathogenesis, management, and future directions of therapy. American Journal of Respiratory and Critical Care Medicine, 195(5), 596–606. https://doi.org/10.1164/rccm.201606-1275CI.
Rout, A., & Binnemans, K. (2014). Solvent extraction of neodymium(III) by functionalized ionic liquid trioctylmethylammonium dioctyl diglycolamate in fluorine-free ionic liquid diluent. Industrial and Engineering Chemistry Research, 53(15), 6500–6508. https://doi.org/10.1021/ie404340p.
Rout, A., et al. (2011). Room temperature ionic liquid diluent for the mutual separation of europium(III) from americium(III). Separation and Purification Technology, 81(2), 109–115. https://doi.org/10.1016/j.seppur.2011.04.033.
Rout, A., et al. (2013). Liquid-liquid extraction of neodymium(iii) by dialkylphosphate ionic liquids from acidic medium: The importance of the ionic liquid cation. Physical Chemistry Chemical Physics, 15(39), 16533–16541. https://doi.org/10.1039/c3cp52218k.
Rout, A., Wellens, S. and Binnemans, K. (2014). Separation of rare earths and nickel by solvent extraction with two mutually immiscible ionic liquids. RSC Advances, 4(11), 5753–5758. https://doi.org/10.1039/c3ra46261g.
Rudnick, R. L., & Gao, S. (2003). Composition of the continental crust. In Treatise on geochemistry (pp. 1–64). Elsevier. https://doi.org/10.1016/B0-08-043751-6/03016-4.
Seredin, V. V. (1996). Rare earth element-bearing coals from the Russian Far East deposits. International Journal of Coal Geology, 30(1–2), 101–129. https://doi.org/10.1016/0166-5162(95)00039-9.
Seredin, V. V., & Dai, S. (2012). Coal deposits as potential alternative sources for lanthanides and yttrium. International Journal of Coal Geology, 67–93. https://doi.org/10.1016/j.coal.2011.11.001.
Seredin, V. V., et al. (2009). New data on the REY hydrothermal ores with extraordinarily high concentrations of rare earth elements. Doklady Earth Sciences, 425(2), 403–408. https://doi.org/10.1134/s1028334x0903012x.
Smith, R. C., et al. (2019). Selective recovery of rare earth elements from coal fly ash leachates using liquid membrane processes. Environmental Science and Technology, 53(8), 4490–4499. https://doi.org/10.1021/acs.est.9b00539.
Taggart, R. K., et al. (2016). Trends in the rare earth element content of U.S.-based coal combustion fly ashes. Environmental Science and Technology, 50(11), 5919–5926. https://doi.org/10.1021/acs.est.6b00085.
Tukker, A. (2014). Rare earth elements supply restrictions: Market failures, not scarcity, hamper their current use in high-tech applications. Environmental Science and Technology. American Chemical Society, 9973–9974. https://doi.org/10.1021/es503548f.
U.S. Geological Survey (2020). Mineral commodity summaries 2020, U.S Departtment OF The Interior, U.S Geological Survey.
Wang, W., et al. (2011). Application of bifunctional ionic liquid extractants [A336][CA-12] and [A336][CA-100] to the lanthanum extraction and separation from rare earths in the chloride medium. Industrial and Engineering Chemistry Research, 50(12), 7534–7541. https://doi.org/10.1021/ie2001633.
Wang, K., et al. (2017). Recovery of rare earth elements with ionic liquids. Green Chemistry, 19(19), 4469–4493. https://doi.org/10.1039/C7GC02141K.
Wilde, R. (2020). Coal Demand and the Industrial Revolution, ThoughtCo. Available at: https://www.thoughtco.com/coal-in-the-industrial-revolution-1221634 (Accessed: 30 November 2020).
Wilkes, J. S. (2002). A short history of ionic liquids—From molten salts to neoteric solvents. Green Chemistry, 4(2), 73–80. https://doi.org/10.1039/b110838g.
Wübbeke, J. (2013). Rare earth elements in China: Policies and narratives of reinventing an industry. Resources Policy, 38(3), 384–394. https://doi.org/10.1016/j.resourpol.2013.05.005.
Xu, G. & Shi, X. (2018). Characteristics and applications of fly ash as a sustainable construction material: A state-of-the-art review. Resources, Conservation and Recycling, 136(August 2017), 95–109. https://doi.org/10.1016/j.resconrec.2018.04.010.
Zhang, W., et al. (2020). A comprehensive review of rare earth elements recovery from coal-related materials. Minerals, 10(5), 451. https://doi.org/10.3390/min10050451.
Zhang, X. (2014) Management of coal combustion wastes. Available at: https://usea.org/publication/management-coal-combustion-wastes-ccc231.
Zhou, B., Li, Z., & Chen, C. (2017). Global potential of rare earth resources and rare earth demand from clean technologies. Minerals, 7(11). https://doi.org/10.3390/min7110203.
Acknowledgments
This work was supported by the National Research Council of Science & Technology (NST) grant by the Korea government (MSIT) (No. CRC-15-06-KIGAM).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Danso, I.K., Cueva-Sola, A.B., Masaud, Z., Lee, JY., Jyothi, R.K. (2021). Ionic Liquids for the Recovery of Rare Earth Elements from Coal Combustion Products. In: Jyothi, R.K., Parhi, P.K. (eds) Clean Coal Technologies. Springer, Cham. https://doi.org/10.1007/978-3-030-68502-7_25
Download citation
DOI: https://doi.org/10.1007/978-3-030-68502-7_25
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-68501-0
Online ISBN: 978-3-030-68502-7
eBook Packages: EnergyEnergy (R0)
