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Fundamental of Electrokinetic Processes

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Electrochemically Assisted Remediation of Contaminated Soils

Part of the book series: Environmental Pollution ((EPOL,volume 30))

Abstract

There are three transport processes associated with the application of electric fields in soils, which affects the mobility of ions (electromigration), colloids (electrophoresis), and pore water (electroosmosis). These processes are influenced by other physical, chemical, and electrochemical processes in a complex soil matrix and their rates depend linearly on the electric field and also on the properties of the species to be transported and/or pore water or soil particle properties. In this chapter, the fundamentals of these processes are described, as well as how they are used in real soil treatment processes.

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References

  1. A.T. Yeung, Y.-Y. Gu, A review on techniques to enhance electrochemical remediation of contaminated soils. J. Hazard. Mater. 195, 11–29 (2011)

    Article  CAS  Google Scholar 

  2. A.T. Yeung, Contaminant extractability by electrokinetics. Environ. Eng. Sci. 23, 202–224 (2006)

    Article  CAS  Google Scholar 

  3. A.N. Alshawabkeh, A.T. Yeung, M.R. Bricka, Practical aspects of in-situ electrokinetic extraction. J. Environ. Eng.-ASCE 125, 27–35 (1999)

    Article  CAS  Google Scholar 

  4. J. Lyklema, Fundamentals of Interface and Colloid Science: Soft Colloids. 5, Elsevier, Amsterdam, Netherlands (2005)

    Google Scholar 

  5. K.R. Reddy, A. Urbanek, A.P. Khodadoust, Electroosmotic dewatering of dredged sediments: bench-scale investigation. J. Environ. Manag. 78, 200–208 (2006)

    Article  CAS  Google Scholar 

  6. M.A. Rodrigo, N. Oturan, M.A. Oturan, Electrochemically assisted remediation of pesticides in soils and water: a review. Chem. Rev. 114, 8720–8745 (2014)

    Article  CAS  Google Scholar 

  7. R. Lopez-Vizcaino, C. Risco, J. Isidro, S. Rodrigo, C. Saez, P. Canizares, V. Navarro, M.A. Rodrigo, Scale-up of the electrokinetic fence technology for the removal of pesticides. Part I: Some notes about the transport of inorganic species. Chemosphere 166, 540–548 (2017)

    Article  CAS  Google Scholar 

  8. R. Lopez-Vizcaino, C. Risco, J. Isidro, S. Rodrigo, C. Saez, P. Canizares, V. Navarro, M.A. Rodrigo, Scale-up of the electrokinetic fence technology for the removal of pesticides. Part II: Does size matter for removal of herbicides? Chemosphere 166, 549–555 (2017)

    Article  CAS  Google Scholar 

  9. S. Barba, R. Lopez-Vizcaino, C. Saez, J. Villasenor, P. Canizares, V. Navarro, M.A. Rodrigo, Electro-bioremediation at the prototype scale: what it should be learned for the scale-up. Chem. Eng. J. 334, 2030–2038 (2018)

    Article  CAS  Google Scholar 

  10. E. Mena, S. Barba, C. Saez, V. Navarro, J. Villasenor, M.A. Rodrigo, P. Canizares, Prescale-Up of Electro-Bioremediation Processes, in Geo-Chicago 2016: Sustainable Waste Management and Remediation, ed. by N. Yesiller, D. Zekkos, A. Farid, A. De, K. R. Reddy, (Geotechnical Special Publication, Reston, 2016), pp. 264–273

    Chapter  Google Scholar 

  11. B.S. Ramadan, G.L. Sari, R.T. Rosmalina, A.J. Effendi, Hadrah, An overview of electrokinetic soil flushing and its effect on bioremediation of hydrocarbon contaminated soil. J. Environ. Manag. 218, 309–321 (2018)

    Article  CAS  Google Scholar 

  12. R. Lopez-Vizcaino, C. Saez, E. Mena, J. Villasenor, P. Canizares, M.A. Rodrigo, Electro-osmotic fluxes in multi-well electro-remediation processes. J Environ Sci Health A Tox Hazard Subst Environ Eng 46, 1549–1557 (2011)

    Article  CAS  Google Scholar 

  13. Y.B. Acar, R.J. Gale, A.N. Alshawabkeh, R.E. Marks, S. Puppala, M. Bricka, R. Parker, Electrokinetic remediation—basics and technology status. J. Hazard. Mater. 40, 117–137 (1995)

    Article  CAS  Google Scholar 

  14. C. Cameselle, Enhancement of electro-osmotic flow during the electrokinetic treatment of a contaminated soil. Electrochim. Acta 181, 31–38 (2015)

    Article  CAS  Google Scholar 

  15. P.R. Buchireddy, R.M. Bricka, D.B. Gent, Electrokinetic remediation of wood preservative contaminated soil containing copper, chromium, and arsenic. J. Hazard. Mater. 162, 490–497 (2009)

    Article  CAS  Google Scholar 

  16. R. Lopez Vizcaino, A. Yustres, L. Asensio, C. Saez, P. Canizares, M.A. Rodrigo, V. Navarro, Enhanced electrokinetic remediation of polluted soils by anolyte pH conditioning. Chemosphere 199, 477–485 (2018)

    Article  CAS  Google Scholar 

  17. R. Lopez-Vizcaino, V. Navarro, J. Alonso, A. Yustres, P. Canizares, M.A. Rodrigo, C. Saez, Geotechnical behaviour of low-permeability soils in surfactant-enhanced electrokinetic remediation. J Environ Sci Health A Tox Hazard Subst Environ Eng 51, 44–51 (2016)

    Article  CAS  Google Scholar 

  18. R. Lopez-Vizcaino, V. Navarro, M.J. Leon, C. Risco, M.A. Rodrigo, C. Saez, P. Canizares, Scale-up on electrokinetic remediation: engineering and technological parameters. J. Hazard. Mater. 315, 135–143 (2016)

    Article  CAS  Google Scholar 

  19. E. Mena, C. Ruiz, J. Villasenor, M.A. Rodrigo, P. Canizares, Biological permeable reactive barriers coupled with electrokinetic soil flushing for the treatment of diesel-polluted clay soil. J. Hazard. Mater. 283, 131–139 (2015)

    Article  CAS  Google Scholar 

  20. C. Weng, Coupled Electrokinetics-Permeable Reactive Barriers, in Electrochemical Remediation Technologies for Polluted Soils, Sediments and Groundwater, ed. by K. R. Reddy, C. Cameselle, (John Wiley & Sons, Inc., Hoboken, 2009), pp. 483–503

    Chapter  Google Scholar 

  21. H.I. Chung, M. Lee, A new method for remedial treatment of contaminated clayey soils by electrokinetics coupled with permeable reactive barriers. Electrochim. Acta 52, 3427–3431 (2007)

    Article  CAS  Google Scholar 

  22. A.D. Henderson, A.H. Demond, Long-term performance of zero-valent iron permeable reactive barriers: a critical review. Environ. Eng. Sci. 24, 401–423 (2007)

    Article  CAS  Google Scholar 

  23. P.L. Palmer, Permeable Treatment Barriers, In Situ Treatment Technology, 2nd edn. (Lewis Publishers, Boca Raton, 2001), pp. 459–482

    Google Scholar 

  24. J. Vidal, C. Saez, P. Canizares, V. Navarro, R. Salazar, M.A. Rodrigo, ZVI—reactive barriers for the remediation of soils polluted with clopyralid: are they really worth? Chem. Eng. J. 350, 100–107 (2018)

    Article  CAS  Google Scholar 

  25. C. Ruiz, E. Mena, P. Canizares, J. Villasenor, M.A. Rodrigo, Removal of 2,4,6-trichlorophenol from spiked clay soils by electrokinetic soil flushing assisted with granular activated carbon permeable reactive barrier. Ind. Eng. Chem. Res. 53, 840–846 (2014)

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support from the Spanish Ministry of Economy, Industry and Competitiveness and European Union through project CTM2016-76197-R (AEI/FEDER, UE) is gratefully acknowledged.

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Correspondence to M. A. Rodrigo .

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Rodrigo, M.A. (2021). Fundamental of Electrokinetic Processes. In: Rodrigo, M.A., Dos Santos, E.V. (eds) Electrochemically Assisted Remediation of Contaminated Soils. Environmental Pollution, vol 30. Springer, Cham. https://doi.org/10.1007/978-3-030-68140-1_2

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