Abstract
This chapter describes the relevant physical processes of luminescence, including excitation, emission, oxygen quenching, and thermal quenching. The kinetic models for conventional and porous PSPs are discussed, while the model for TSP is considered a reduced case. These models provide the physical foundations for the design and characterization of PSP and TSP, measurement uncertainty analysis, and data processing.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
R.S. Becker, Theory and Interaction of Fluorescence and Phosphorescence (Wiley Interscience, New York, 1969)
J.H. Bell, E.T. Shairer, L.A. Hand, R.D. Mehta, Surface pressure measurements using luminescent coatings. Annu. Rev. Fluid. Mech. 33, 155–206 (2001)
R.G. Bennett, P.J. McCartin, Radiationless deactivation of the fluorescent state of substituted anthracenes. J. Chem. Phys. 44(5), 1969–1973 (1966)
J.B. Butt, Reaction Kinetics and Reactor Design (Prentice Hall, Englewood Cliffs, NJ, 1980)
E.R. Carraway, J.N. Demas, B.A. DeGraff, Luminescence quenching mechanism for microheterogeneous systems. Anal. Chem. 63(4), 332–336 (1991a)
E.R. Carraway, J.N. Demas, B.A. DeGraff, Photophysics and oxygen quenching of transition-metal complexes on fumed silica. Langmuir 7(12), 2991 (1991b)
D.L. Freeman, J.D. Doll, The influence of diffusion on surface reaction kinetics. J. Chem. Phys. 78(10), 6002 (1983)
P.M. Gewehr, D.T. Delpy, Optical oxygen sensor based on phosphorescence lifetime quenching and employing a polymer immobilised metalloporphyrin probe. Med. Biol. Eng. Comput. 31, 2–10 (1993)
P. Hartmann, M.J.P. Leiner, M.E. Lippitsch, Response characteristics of luminescent oxygen sensors. Sens. Actuators B Chem. 29, 251–257 (1995)
C.W. Hinshelwood, Kinetics of Chemical Change (Claredon, Oxford, 1940)
J.P. Hubner, B.F. Carroll, Application of dual sorption theory to pressure-sensitive paints. AIAA J. 35(11), 1790–1792 (1997)
V.E. Mosharov, V.N. Radchenko, S.D. Fonov, Luminescent Pressure Sensors in Aerodynamic Experiments (Central Aerohydrodynamic Institute (TsAGI), CWA International Corporation, Moscow, 1997)
C.A. Parker, Photoluminescence of Solutions (Elsevier, New York, 1968)
J.F. Rabek, Mechanisms of Photophysical Processes and Photochemical Reactions in Polymer — Theory and Applications (Wiley, New York, 1987)
H. Sakaue, Porous Pressure Sensitive Paints for Aerodynamic Applications. MS thesis, School of Aeronautics and Astronautics, Purdue University, West Lafayette, IN, 1999
J. Samuel, M. Ottolenghi, D. Avnir, Diffusion-controlled reactions on porous silicas: Mechanisms, surface diffusion coefficients, and effects of geometry. J. Phys. Chem. 96, 6398 (1992)
K.S. Schanze, B.F. Carroll, S. Korotkevitch, M.J. Morris, Temperature dependence of pressure sensitive paints. AIAA J. 35(2), 306–310 (1997)
L. Song, M.D. Fayer, Temperature dependent intersystem crossing and triplet-triplet absorption of rubrene in solid solution. J. Luminesc. 50, 75–81 (1991)
S. Wolfgang, H. Gafney, Quenching of Ru(bpy)32+ ionically bound to porous vycor glass by O2, N2O, and SO2. J Phys Chem 87, 5395 (1983)
W. Xu, R.C. McDonough, B. Langsdorf, J.N. Demas, B.A. DeGraff, Oxygen sensors based on luminescence quenching: Interactions of metal complexes with the polymer supports. Anal. Chem. 66, 4133–4141 (1994)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Liu, T., Sullivan, J.P., Asai, K., Klein, C., Egami, Y. (2021). Basic Photophysics. In: Pressure and Temperature Sensitive Paints. Experimental Fluid Mechanics. Springer, Cham. https://doi.org/10.1007/978-3-030-68056-5_2
Download citation
DOI: https://doi.org/10.1007/978-3-030-68056-5_2
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-68055-8
Online ISBN: 978-3-030-68056-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)