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Evidence for Atmospheric Depositions Using Attic Dust, Spatial Mapping and Multivariate Stats

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Contaminant Levels and Ecological Effects

Abstract

Atmospheric deposition poses significant ecological concerns. It is very important in air pollution researches to provide fast and efficient access to qualitative and quantitative characterization. Case study was introduced in order to implement the multidisciplinary approach in the investigations. When monitoring the distribution of certain substances in the air, it is necessary to choose very carefully the medium that will reflect not only the current but also the long-term atmospheric deposition. Attic dust was examined as historical archive of anthropogenic emissions, with the aim of elucidating the pathways of enrichments associated with exploitation of Cu, Pb and Zn minerals in the Bregalnica river basin region. Attic dust samples were collected from 84 settlements. At each location for attic dust sampling, topsoil samples from the house yards were also collected. Mass spectrometry with inductively coupled plasma (ICP-MS) was applied as an analytical technique for multi-element determination. The universal kriging method with linear variogram interpolation was applied for the construction of spatial distribution maps. Data interpretation was considered in correlation with dominant geological units. Significantly enriched contents for Cd, Cu, Pb and Zn have been correlated with the lithogenic dominance of Rifeous shales. Both Pb-Zn mine environs were identified as the most affected areas with lead and zinc enrichments, due to the continually long-time wind dust dispersion from the flotation tailings. Atypical deposition was revealed for In, Te and W, as silent tracker for air pollution.

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References

  • Ajmone-Marsan F, Biasioli M, Kralj T, Grčman H, Davidson CM, Hursthouse AS, Madrid L, Rodrigues S (2008) Metals in particle-size fractions of the soils of five European cities. Environ Pollut 152(1):73–81

    Article  CAS  Google Scholar 

  • Alijagić J (2008) Distribution of chemical elements in an old metallurgic area, Zenica (Central Bosnia). MSc thesis, Faculty of Science, Masaryk University, Brno, Czech Republic

    Google Scholar 

  • Alijagić J, Šajn R (2011) Distribution of chemical elements in an old metallurgical area, Zenica (Bosnia and Herzegovina). Geoderma 162(1):71–85

    Google Scholar 

  • Angelovska S, Stafilov T, Šajn R, Balabanova B (2016) Geogenic and anthropogenic moss responsiveness to element distribution around a Pb–Zn mine, Toranica, Republic of Macedonia. Arch Environ Contam Toxicol 70(3):487–505

    Article  CAS  Google Scholar 

  • Arsovski M (1997) Tectonics of Macedonia. Faculty of Mining and Geology, Štip, 1–306

    Google Scholar 

  • Artiola JF, Pepper I, Brussean L (2004) Environmental monitoring and characterization. Elsevier Academic Press, San Diego

    Google Scholar 

  • Athar M, Vohora S (1995) Heavy metals and environment. New Age International publishers, New Delhi

    Google Scholar 

  • Bačeva K, Stafilov T, Šajn R (2012) Monitoring of air pollution with heavy metals in the vicinity of ferronickel smelter plant by deposited dust. Maced J Ecol Environ 1(1–2):17–24

    Google Scholar 

  • Balabanova B, Stafilov T, Šajn R, Bačeva K (2011) Distribution of chemical elements in attic dust as reflection of their geogenic and anthropogenic sources in the vicinity of the copper mine and flotation plant. Arch Environ Contam Toxicol 61(2):173–184

    Article  CAS  Google Scholar 

  • Balabanova B, Stafilov T, Šajn R (2019) Enchasing anthropogenic element trackers for evidence of long-term atmospheric depositions in mine environs. J Environ Sci Health A 54(10):988–998

    Article  CAS  Google Scholar 

  • Beelen R, Hoek G, Pebesma E, Vienneau D, de Hoogh K, Briggs DJ (2009) Mapping of background air pollution at a fine spatial scale across the European Union. Sci Total Environ 407(6):1852–1867

    Article  CAS  Google Scholar 

  • Box GE, Cox DR (1964) An analysis of transformations. J R Stat Soc B:211–252

    Google Scholar 

  • Cizdziel JV, Hodge VF (2000) Attics as archives for house infiltrating pollutants: trace elements and pesticides in attic dust and soil from southern Nevada and Utah. Microchem J 64(1):85–92

    Article  CAS  Google Scholar 

  • Cizdziell JV, Hodge VF, Faller SH (1998) Plutonium anomalies in attic dust and soils at locations surrounding the Nevada test site. Chemosphere 37(6):1157–1168

    Article  Google Scholar 

  • Coronas MV, Bavaresco J, Rocha JAV, Geller AM, Caramão EB, Rodrigues MLK, Vargas VMF (2013) Attic dust assessment near a wood treatment plant: past air pollution and potential exposure. Ecotoxicol Environ Saf 95:153–160

    Article  CAS  Google Scholar 

  • Davis JJ, Gulson BL (2005) Ceiling (attic) dust: a “museum” of contamination and potential hazard. Environ Res 99(2):177–194

    Article  CAS  Google Scholar 

  • De Miguel E, Llamas JF, Chacon E, Mazadiego LF (1999) Sources and pathways of trace elements in urban environments: a multi-elemental qualitative approach. Sci Total Environ 235(1):355–357

    Article  Google Scholar 

  • de Smith MJ, Goodchild MF, Longley PA (2009) Geospatial analysis: a comprehensive guide to principles. In: Techniques and software tools. Matador, Leicester, UK

    Google Scholar 

  • Dumurdzanov N, Serafimovski T, Burchfiel BC (2004) Evolution of the Neogene-Pleistocene basins of Macedonia. Geol Soc Am Bull 1:1–20

    Google Scholar 

  • Duruibe JO, Ogwuegbu MOC, Egwurugwu JN (2007) Heavy metal pollution and human biotoxic effects. Int J Phys Sci 2(5):112–118

    Google Scholar 

  • Finlayson-Pitts BJ, Pitts JJN (1999) Chemistry of the upper and lower atmosphere: theory, experiments, and applications. Academic Press, Cambridge, Massachusetts

    Google Scholar 

  • Fordyce FM, Brown SE, Ander EL, Rawlins BG, O’Donnell KE, Lister TR et al (2005) GSUE: urban geochemical mapping in Great Britain. Geochem Explor Environ Anal 5(4):325–336

    Article  CAS  Google Scholar 

  • Goodarzi F (2006) Assessment of elemental content of feed coal, combustion residues, and stack emitted materials for a Canadian pulverized coal fired power plant, and their possible environmental effect. Int J Coal Geol 65:17–25

    Article  CAS  Google Scholar 

  • Gosar M, Teršič T (2012) Environmental geochemistry studies in the area of Idrija mercury mine, Slovenia. Environ Geochem Health 34(1):27–41

    Article  CAS  Google Scholar 

  • Gosar M, Šajn R, Biester H (2006) Binding of mercury in soils and attic dust in the Idrija mercury mine area (Slovenia). Sci Total Environ 369(1):150–162

    Article  CAS  Google Scholar 

  • Hensley AR, Scott A, Rosenfeld PE, Clark JJJ (2007) Attic dust and human blood samples collected near a former wood treatment facility. Environ Res 105(2):194–199

    Article  CAS  Google Scholar 

  • Hoenig M (2001) Preparation steps in environmental trace element analysis-facts and traps. Talanta 54:1021–1038

    Article  CAS  Google Scholar 

  • Ilacqua V, Freeman NC, Fagliano J, Lioy PJ (2003) The historical record of air pollution as defined by attic dust. Atmos Environ 37(17):2379–2389

    Article  CAS  Google Scholar 

  • ISO 14869-1 (2001) Soil quality: dissolution for the determination of total element content - Part 1: Dissolution with hydrofluoric and perchloric acids. International Organization for Standardization, Geneva, Switzerland

    Google Scholar 

  • Jemec Auflič MJ, Šajn R (2007) Geochemical research of soil and attic dust in Litija area. Geologija 50(2):497–505

    Article  Google Scholar 

  • Lazarevski А (1993) Climate in Macedonia. Kultura, Skopje

    Google Scholar 

  • Li Z, Zhu Q, Gold C (2005) Digital terrain modeling – principles and methodology. CRC Press, Florida

    Google Scholar 

  • Lioy PJ, Weisel CP, Millette JR, Eisenreich S, Vallero D, Offenberg J, Buckley B, Turpin B, Zhong M, Cohen MD, Prophete C, Yang I, Stiles R, Chee G, Johnson W, Porcja R, Alimokhtari S, Hale RC, Weschler C, Chen LC (2002) Characterization of the dust/smoke aerosol that settled east of the World Trade Center (WTC) in lower Manhattan after the collapse of the WTC 11 September 2001. Environ Health Perspect 110(7):703–714

    Article  CAS  Google Scholar 

  • Pavilonis BT, Lioy PJ, Guazzetti S, Bostick BC, Donna F, Peli M, Zimmerman NJ, Bertrand P, Lucas E, Smith DR (2015) Manganese concentrations in soil and settled dust in an area with historic ferroalloy production. J Expo Sci Environ Epidemiol 25(4):443–450

    Article  CAS  Google Scholar 

  • Reimann C, Filzmoser P, Fabian K, Hron K, Birke M, Demetriades A, Dinelli E, Ladenberger A. (2012) The concept of compositional data analysis in practice – Total major element concentrations in agricultural and grazing land soils of Europe. Sci Total Environ 426:196–210

    Google Scholar 

  • Šajn R (2000) Influence of lithology and anthropogenic activity on distribution of chemical elements in dwelling dust, Slovenia. Geologija 43:85–101

    Article  Google Scholar 

  • Šajn R (2001) Geochemical research of soil and attic dust in Celje area (Slovenia). Geologija 44:351–362

    Article  Google Scholar 

  • Šajn R (2002) Influence of mining and metallurgy on chemical composition of soil and attic dust in Meža valley, Slovenia. Geologija 45:547–552

    Article  Google Scholar 

  • Šajn R (2003) Distribution of chemical elements in attic dust and soil as reflection of lithology and anthropogenic influence in Slovenia. J Phys 107:1173–1176

    Google Scholar 

  • Šajn R (2005) Using attic dust and soil for the separation of anthropogenic and geogenic elemental distributions in an old metallurgic area (Celje, Slovenia). Geochemistry 5:59–67

    Google Scholar 

  • Šajn R (2006) Factor analysis of soil and attic-dust to separate mining and metallurgy influence, Meza valley, Slovenia. Math Geol 38:735–746

    Article  CAS  Google Scholar 

  • Salminen R, Batista MJ, Bidovec M, Demetriades A, De Vivo B, De Vos W, Duris M, Gilucis A, Gregorauskiene V, Halamic J, Heitzmann P, Heitzmann P, Lima A, Jordan G, Klaver G, Klein P, Lis J, Locutura J, Marsina K, Mazreku A, O’Connor PJ, Olsson SÅ, Ottesen RT, Petersell V, Plant JA, Reeder S, Salpeteur I, Sandström H, Siewers U, Steenfelt A, Tarvainen T (2005) Geochemical atlas of Europe. Part 1 – Background information, methodology and maps. Geological survey of Finland, Espoo, Finland

    Google Scholar 

  • Salomons W (1995) Environmental impact of metals derived from mining activities: processes, predictions, preventions. J Geochem Explor 44:5–23

    Article  Google Scholar 

  • Sengupta М (1993) Environmental impacts of mining: monitoring, restoration and control. Lewis Publishers, Boca Raton

    Google Scholar 

  • Siegel FR (2002) Environmental geochemistry of potentially toxic metals. Springer, Berlin, Heidedelberg

    Book  Google Scholar 

  • Tye AM, Hodgkinson ES, Rawlins BG (2006) Microscopic and chemical studies of metal particulates in tree bark and attic dust: evidence for historical atmospheric smelter emissions, Humberside, UK. J Environ Monit 8(9):904–912

    Article  CAS  Google Scholar 

  • Van het Bolcher M, Van der Gon DH, Groenenberg BJ, Ilyin I, Reinds GJ, Slootweg J, Travnikov O, Visschedijk A, de Vries W (2006) Heavy metal emissions, depositions, critical loads and exceedances in Europe. In: Hettelingh JP, Sliggers J (eds) . National Institute for Public Health and the Environment, Wageningen, The Netherland

    Google Scholar 

  • VanLoon GW, Duffy SJ (2000) Environmental chemistry: a global perspective. Oxford University Press, New York

    Google Scholar 

  • Völgyesi P, Jordan G, Zacháry D, Szabó C, Bartha A, Matschullat J (2014) Attic dust reflects long-term airborne contamination of an industrial area: a case study from Ajka, Hungary. Appl Geochem 46:19–29

    Article  CAS  Google Scholar 

  • Wellmer FW (1998) Statistical evaluations in exploration for mineral deposits. Springer, Berlin Heidelberg

    Book  Google Scholar 

  • Wong CS, Li X, Thornton I (2006) Urban environmental geochemistry of trace metals. Environ Pollut 142(1):1–16

    Article  CAS  Google Scholar 

  • Zeigler BP, Praehofer H, Kim TG (2000) Theory of modelling and simulation, 2nd edn. Academic Press, San Diego

    Google Scholar 

  • Žibret G (2008) Determination of historical emission of heavy metals into the atmosphere: Celje case study. Environ Geol 56:189–196

    Article  CAS  Google Scholar 

  • Žibret G, Šajn R (2008) Modelling of atmospheric dispersion of heavy metals in the Celje area, Slovenia. J Geochem Explor 97(1):29–41

    Article  CAS  Google Scholar 

  • Žibret G, Šajn R (2010) Hunting for geochemical associations of elements: factor analysis and self-organising maps. Math Geosci 42:681–703

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Geological Survey of Slovenia, Ljubljana, Slovenia

    Robert Šajn

  2. Faculty of Agriculture, University “Goce Delčev”, Krste Misirkov bb, Štip, Republic of Macedonia

    Biljana Balabanova

  3. Institute of Chemistry, Faculty of Science, Ss. Cyril and Methodius University, Skopje, Republic of Macedonia

    Trajče Stafilov

  4. INCDO-INOE 2000 Research Institute for Analytical Instrumentation (ICIA), Cluj-Napoca, Romania

    Claudiu Tănăselia

Authors
  1. Robert Šajn
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  2. Biljana Balabanova
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  3. Trajče Stafilov
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  4. Claudiu Tănăselia
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Correspondence to Trajče Stafilov .

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Editors and Affiliations

  1. Faculty of Agriculture, Goce Delčev University, Štip, North Macedonia

    Biljana Balabanova

  2. Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Saints Cyril and Methodius University, Skopje, North Macedonia

    Trajče Stafilov

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Šajn, R., Balabanova, B., Stafilov, T., Tănăselia, C. (2021). Evidence for Atmospheric Depositions Using Attic Dust, Spatial Mapping and Multivariate Stats. In: Balabanova, B., Stafilov, T. (eds) Contaminant Levels and Ecological Effects. Emerging Contaminants and Associated Treatment Technologies. Springer, Cham. https://doi.org/10.1007/978-3-030-66135-9_6

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