Abstract
Silica microparticles synthesized from sodium silicate were characterized and used as an adsorbent for lead and nickel ions (Pb2+ and Ni2+) from their separate solutions. Batch adsorption experimental results showed that an increase in the percentage removals of the Pb2+ and Ni2+ ions from their solutions was favoured by increased contact time, adsorbent dosage, and heavy metal ion concentrations. Optimum adsorptions of 59.40%/64.66%, 61.4%/75.60% and 61.4%/49.58% for Pb2+/Ni2+ ions were obtained at contact time of 40 min, an adsorbent dosage of 2.5 g and heavy metal ion concentration of 50/40 mg/l respectively. The adsorption data were subjected to different kinetic models and pseudo-second-order reaction model had the best fit for both metal ions (R2, 0.985, 0.996). To verify the adsorption performance, the adsorption data were also fitted into the Langmuir and Freundlich isotherms. The Langmuir isotherm had the best fit for both metal ions (R2, 0.918, 0.872). The maximum metal ion capacity calculated from Langmuir isotherm was 22.3 and 25.5 mg g−1 for lead and nickel ions, respectively. This study showed that silica microparticles can bind a substantial amount of lead and nickel ions from aqueous solutions.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Tchounwou PB, Yedjou CG, Patlolla AK, Sutton DJ (2012) Heavy metal toxicity and the environment. Exp Suppl 101:133–164
Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arabian J Chem 4:361–377
Igiri BE, Okoduwa SIR, Idoko GO, Akabuogu EP, Adeyi AO, Ejiogu IK (2018) Toxicity and bioremediation of heavy metals contaminated ecosystem from tannery wastewater: a review. J Toxicol 2018:16
Li J, Zhang C, Lin J, Yin J, Xu J, Chen Y (2018) Evaluating the bioavailability of heavy metals in natural-zeolite-amended aquatic sediments using thin-film diffusive gradients. Aquacultur Fish 3:122–128
Singh R, Gautam N, Mishra A, Gupta R (2011) Heavy metals and living systems: an overview. Indian J Pharmacol 43:246–253
Gleiter H (1995) Nanostructured materials: state of the art and perspectives. Nanostruct Mater 6:3–14
Xu C, Ravi Anusuyadevi P, Aymonier C, Luque R, Marre S (2019) Nanostructured materials for photocatalysis. Chem Soc Rev 48:3868–3902
Khdary NH, Gassim AEH, Howard AG, Sakthivel TS, Seal S (2018) Synthesis and modification of mercapto-submicron scavenger for real-time extraction and preconcentration of As(iii). Anal Methods 10:245–255
A.S. Thouria Benzaoui, Djaafar Djabali, Adsorption of copper (II) ions from aqueous solution using bottom ash of expired drugs incineration, Adsorption Science & Technology, 36 (2017) 114–129
Dąbrowski A (2001) Adsorption—from theory to practice. Adv Coll Interface Sci 93:135–224
Dargahi A, Gholestanifar H, Darvishi P, Karami A, Hasan SH, Poormohammadi A, Behzadnia A (2016) An investigation and comparison of removing heavy metals (Lead and Chromium) from aqueous solutions using magnesium oxide nanoparticles. Pol J Environ Stud 25:557–562
Ahile UJ, Ama SO, Mchihi MM, Oteikwu MO, Nyom PN, Utange PI (2017) Removal Of Pb2+ from aqueous solution using rice husk as an adsorbent. FUW Trends Sci Technol J 2:886–889
Abdus-Salam N, Adekola SK (2018) Adsorption studies of zinc(II) on magnetite, baobab (Adansonia digitata) and magnetite–baobab composite. Appl Water Sci 8:222
Nouh ESA (2020) Manganese oxide-coated wool as adsorbent for U(VI) removal from aqueous waste solutions. Int J Environ Anal Chem 1–14
Freundlich HMF (1906) Uber die adsorption in Losungen. Zeitschrift fur Physikalische Chemie 57:385–470
Lagergren S (1898) About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar 24:1–39
Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–124
Okieimen FE, Okundia EU, Ogbeifun DE (1991) Sorption of cadmium and lead ions on modified groundnut (Arachis hypogea) husks. J Chem Technol Biotechnol 51:97–103
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Ethics declarations
The authors declare that they have no competing interests.
Rights and permissions
Copyright information
© 2021 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Ikhuoria, E.U., Ifijen, I.H., Obiekea, P.G., Maliki, M., Ehigie, A.C. (2021). The Adsorption of Heavy Metals from Aqueous Solutions Using Silica Microparticles Synthesized from Sodium Silicate. In: Anderson, C., et al. Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-65647-8_16
Download citation
DOI: https://doi.org/10.1007/978-3-030-65647-8_16
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-65646-1
Online ISBN: 978-3-030-65647-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)