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Transformation of Reduced Compounds of Carbon and Nitrogen Oxides in the Cramped Aerodynamic Conditions

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Part of the book series: Studies in Systems, Decision and Control ((SSDC,volume 333))

Abstract

The joint transformation of typical urban atmosphere pollutants under cramped aerodynamic conditions is considered. These are the spaces between buildings with their highest concentrations, as a result of which reactions proceed quite intensively, with speeds greater than in unlimited volume. The kinetics of the process is described by a stiff system of differential equations, which is solved by the Rosenbrock method. The effect of the influence of reduced carbon compounds and nitrogen oxides in a wide range of their concentrations on the rate of formation of a highly toxic secondary pollutant is studied. In the course of numerical experiments, the conditions corresponding to its maximum value are determined. In this case, the transfer of substances from the reaction zone does not have time to occur.

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References

  1. DeMore, W.B., Margitan, J.J., Molina, J.J., et al.: Chemical kinetics and photochemical data for use in stratospheric modeling. NASA panel for data evaluation. JPL Publ. 82–57, 1–186 (1982)

    Google Scholar 

  2. Atkinson, R., Lloyd, A.C.: Evaluation of kinetic and mechanistic data for modeling of photochemical smog. J. Phys. Chem. Ref. Data 13(2), 315–444 (1984)

    Article  Google Scholar 

  3. Baulch, D.L., Cox, R.A., Hampson, R.F., et al.: Evaluated kinetic and photochemical data for atmospheric chemistry. J. Phys. Chem. Ref. Data 11(2), 328–496 (1982)

    Article  Google Scholar 

  4. Baulch, D.L., Cox, R.A., Hampson, R.F., et al.: Evaluated kinetic and photochemical data for atmospheric chemistry. J. Phys. Chem. Ref. Data 13(4), 1259–1379 (1984)

    Article  Google Scholar 

  5. Demerjan, K.L., Shere, K.L., Peterson, J.T.: Theoretical estimates of actinic (spherically integrated) flux and photolytic rate constants of atmospheric species in the lower troposphere. Adv. Environ. Sci. Technol. 10, 369–459 (1980)

    Google Scholar 

  6. Anderson, L.C.: Atmospheric chemical kinetic data survey. Rev. Geophys. Space Phys. 10, 369–459 (1976)

    Google Scholar 

  7. Konovalov, I.B., Elanskii, N.F., Belikov, I.B., Zvyagintsev, A.M., Beekmann, M.: Validation of chemistry transport model of the lower atmosphere in the Central European region of Russia using ground-based and satellite measurement data. Russ. Meteorol. Hydrol. 34(4), 236–242 (2009). https://doi.org/10.3103/S1068373909040062

    Article  Google Scholar 

  8. Zaripov, R.B., Kuznetsova, I.N., Konovalov, I.B., Belikov, I.B., Zvyagintsev, A.M.: WRF ARW and CHIMERE models for numerical forecasting of surface ozone concentration. Russ. Meteorol. Hydrol. 36(4), 249–257 (2011). https://doi.org/10.3103/S1068373911040054

    Article  Google Scholar 

  9. Konovalov, I.B., Beekmann, M., Kuznetsova, I.N., Glazkova, A.A., Zaripov, R.B., Vasil’eva, A.V.: Estimation of the influence that natural fires have on air pollution in the region of Moscow megalopolis based on the combined use of chemical transport model and measurement data. Izvestiya. Atmos. Oceanic Phys. 47(4), 457–467 (2011). https://doi.org/10.1134/S0001433811040062

    Article  Google Scholar 

  10. Zaripov, R.B., Konovalov, I.B., Glazkova, A.A.: Modeling the concentration of pollutants using the WRF-ARW atmospheric model and CHIMERE chemistry transport model. Russ. Meteorol. Hydrol. 38(12), 828–839 (2013). https://doi.org/10.3103/S1068373913120042

    Article  Google Scholar 

  11. Zaytsev, V.A.: Chemical transformations vehicle exhaust in cramped aerodynamic conditions of city. Mathematical methods in engineering and technology. MMTT-29: XXIX International Scientific Conference: Proceedings, vol. 10, pp. 24–28 (2016)

    Google Scholar 

  12. Zaytsev, V.A.: Quantitative characteristics of chemical transformations of pollutants in cramped aerodynamic conditions. MMTT-31: XXXI International Scientific Conference: Proceedings, vol. 4, pp. 86–90 (2018)

    Google Scholar 

  13. Zaytsev, V.A.: Some quantitative characteristics of the transformation of pollutant substances in the cramped aerodynamic conditions of the urban atmosphere. Izvestiya Sankt-Peterburgskogo gosudarstvennogo teknologicheskogo instituta (tekhnicheskogo universiteta) 47(73), 128–132 (2018)

    Google Scholar 

  14. Zaytsev, V.A.: Features of the kinetics of gas impurities in cramped aerodynamic conditions of an urban atmosphere. MMTT-32: XXXII International Scientific Conference: Proceedings, vol. 12–3, pp. 57–62 (2019)

    Google Scholar 

  15. Pokusaev, B.G., Zaitsev, A.A., Zaitsev, V.A.: Transfer processes under slug flow conditions in three-phase media. Theor. Found. Chem. Eng. 33(6), 539–549 (1999)

    Google Scholar 

  16. Kotelnikov, S.N., Stepanov, E.V., Ivashkin, V.T.: Ozone concentration in the ground atmosphere and morbidity during extreme heat in the summer of 2010. Doklady Biol. Sci. 473(1), 64–68 (2017). https://doi.org/10.1134/S0012496617020107

    Article  Google Scholar 

  17. Fang, Y., Naik, V., Horowitz, L.W., Mauzerall, D.L.: Air pollution and associated human mortality: the role of air pollutant emissions, climate change and methane concentration increases from the preindustrial period to present. Atmos. Chem. Phys. 13, 1377–1394 (2013)

    Article  Google Scholar 

  18. Bates, D.V.: Ambient ozone and mortality. Epidemiology 16(4), 427–429 (2005)

    Article  MathSciNet  Google Scholar 

  19. Hollingsworth, J.W., Kleeberger, S.R., Foster, W.M.: Ozone and pulmonary innate immunity. Proc. Amer. Thorac. Soc. 4, 240–246 (2007)

    Article  Google Scholar 

  20. Longphre, M., Zhang, L.-Y., Harkema, J.R., Kleeberger, S.R.: Ozone-induced pulmonary inflammation and epithelial proliferation are partially mediated by PAF. J. Appl. Physiol. 86(1), 341–349 (1999)

    Article  Google Scholar 

  21. Gryparis, A., Forsberg, B., Katsouyanni, K., Analitis, A., Touloumi, G., Schwartz, J.: Acute effects of ozone on mortality from the “Air pollution and health: A European project approach”. Amer. J. Respir. Crit. Care Med. 170, 1080–1087 (2004)

    Article  Google Scholar 

  22. Bell, M., Dominici, F.: Analysis of threshold effects for short-term exposure to ozone and increased risk of mortality. Epidemiology 17(6), 223 (2006)

    Article  Google Scholar 

  23. Elansky, N.F.: Russian studies of atmospheric ozone in 2007–2011. Izvestiya. Atmos. Oceanic Phys. 48(3), 281–298 (2012). https://doi.org/10.1134/S0001433812030024

    Article  Google Scholar 

  24. Elansky, N.F.: Russian studies of atmospheric ozone in 2011–2014. Izvestiya. Atmos. Oceanic Phys. 52(2), 132–146 (2016). https://doi.org/10.1134/S0001433816020031

    Article  Google Scholar 

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Acknowledgements

The research was supported by the Russian Foundation for Basic Research (grant 16-08-01252).

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Correspondence to Vadim A. Zaytsev .

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Zaytsev, V.A. (2021). Transformation of Reduced Compounds of Carbon and Nitrogen Oxides in the Cramped Aerodynamic Conditions. In: Kravets, A.G., Bolshakov, A.A., Shcherbakov, M. (eds) Society 5.0: Cyberspace for Advanced Human-Centered Society. Studies in Systems, Decision and Control, vol 333. Springer, Cham. https://doi.org/10.1007/978-3-030-63563-3_13

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  • DOI: https://doi.org/10.1007/978-3-030-63563-3_13

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