Abstract
The joint transformation of typical urban atmosphere pollutants under cramped aerodynamic conditions is considered. These are the spaces between buildings with their highest concentrations, as a result of which reactions proceed quite intensively, with speeds greater than in unlimited volume. The kinetics of the process is described by a stiff system of differential equations, which is solved by the Rosenbrock method. The effect of the influence of reduced carbon compounds and nitrogen oxides in a wide range of their concentrations on the rate of formation of a highly toxic secondary pollutant is studied. In the course of numerical experiments, the conditions corresponding to its maximum value are determined. In this case, the transfer of substances from the reaction zone does not have time to occur.
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The research was supported by the Russian Foundation for Basic Research (grant 16-08-01252).
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Zaytsev, V.A. (2021). Transformation of Reduced Compounds of Carbon and Nitrogen Oxides in the Cramped Aerodynamic Conditions. In: Kravets, A.G., Bolshakov, A.A., Shcherbakov, M. (eds) Society 5.0: Cyberspace for Advanced Human-Centered Society. Studies in Systems, Decision and Control, vol 333. Springer, Cham. https://doi.org/10.1007/978-3-030-63563-3_13
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