Abstract
Nearly three decades of significant academic and commercialization progress, appreciations have to be credited for Li+ ion-based rechargeable secondary batteries, which conquered the entire world. The Li+ ion batteries dictate the consumer battery market and are considered crucial for the practical realization of plug-in hybrid electric vehicles (PHEVs), hybrid electric vehicles (HEVs), and electric vehicles (EVs). Recently, post-lithium–ion batteries, particularly Na, K, Mg, and Zn, and Al–ion batteries have also been intensively explored for various energy storage tenders due to their natural abundance, low cost, and environmental safety of these materials. The utilization of metal oxides in battery application is tremendous and, an example, the first commercial lithium ion batteries by Sony Co. with LiCoO2 as a cathode. Recently, Ni-rich layered oxide-based lithium ion batteries are on an edge of commercialization. The focus on battery research had increased drastically from 2010, and still metal oxide-based cathodes/anodes are researched exclusively due to their significant physicochemical properties. This chapter emphasizes electrochemical properties of various metal oxide-based electrode materials for various secondary rechargeable energy storage applications including sodium ion batteries (SIBs), potassium ion batteries (PIBs), and zinc ion batteries (ZIBs).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Alcántara R, Jaraba M, Lavela P, Tirado JL (2002) NiCo2O4 spinel: first report on a transition metal oxide for the negative electrode of sodium-ion batteries. Chem Mater 14:2847–2848. https://doi.org/10.1021/cm025556v
Alfaruqi MH, Gim J, Kim S, Song J, Jo J, Kim S, Mathew V, Kim J (2015) Enhanced reversible divalent zinc storage in a structurally stable α-MnO2 nanorod electrode. J Power Sources 288:320–327. https://doi.org/10.1016/j.jpowsour.2015.04.140
Amatucci GG, Tarascon JM, Klein LC (1996) CoO2, The end member of the LixCoO2 solid solution. J Electrochem Soc 143:1114–1123. https://doi.org/10.1149/1.1836594
Arai H, Okada S, Ohtsuka H, Ichimura M, Yamaki J (1995) Characterization and cathode performance of Li1 −xNi1 + xO2 prepared with the excess lithium method. Solid State Ionics 80:261–269. https://doi.org/10.1016/0167-2738(95)00144-U
Ariyoshi K, Orikasa Y, Kajikawa K, Yamada Y (2019) Li2Ni0.2Co1.8O4 having a spinel framework as a zero-strain positive electrode material for lithium-ion batteries. J Mater Chem A 7:13641–13649. https://doi.org/10.1039/C9TA03191J
Berthelot R, Carlier D, Delmas C (2011) Electrochemical investigation of the P2–NaxCoO2 phase diagram. Nat Mater 10:74–80. https://doi.org/10.1038/nmat2920
Bhuvaneswari S, Pratheeksha PM, Anandan S, Rangappa D, Gopalan R, Rao TN (2014) Efficient reduced graphene oxide grafted porous Fe3O4 composite as a high performance anode material for Li-ion batteries. Phys Chem Chem Phys 16:5284–5294. https://doi.org/10.1039/C3CP54778G
Bianchini M, Roca-Ayats M, Hartmann P, Brezesinski T, Janek J (2018) There and back again—the journey of liNiO2 as a cathode active material. Angew Chem Int Ed Eng 58:10434–10458. https://doi.org/10.1002/anie.201812472
Billaud J, Singh G, Armstrong AR, Gonzalo E, Roddatis V, Armand M, Rojo T, Bruce PG (2014) Na0.67Mn1−xMgxO2 (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries. Energy Environ Sci 7:1387–1391. https://doi.org/10.1039/C4EE00465E
Boulineau A, Simonin L, Colin JF, Bourbon C, Patoux S (2013) First evidence of manganese–nickel segregation and densification upon cycling in li-rich layered oxides for lithium batteries. Nano Lett 13:3857–3863. https://doi.org/10.1021/nl4019275
Boyd S, Augustyn V (2018) Transition metal oxides for aqueous sodium-ion electrochemical energy storage. Inorg Chem Front 5:999–1015. https://doi.org/10.1039/C8QI00148K
Braconnier JJ, Delmas C, Fouassier C, Hagenmuller P (1980) Comportement electrochimique des phases NaxCoO2. Mater Res Bull 15:1797–1804. https://doi.org/10.1016/0025-5408(80)90199-3
Broconnier JJ, Delmas C, Hagenmuller P (1982) Etude par desintercalation electrochimique des systemes NaxCrO2 et NaxNiO2. Mater Res Bull 17:993–1000. https://doi.org/10.1016/0025-5408(82)90124-6
Caballero A, Hernan L, Morales J, Sanchez L, Santos Pena J, Aranda MAG (2002) Synthesis and characterization of high-temperature hexagonal P2-Na0.6MnO2 and its electrochemical behaviour as cathode in sodium cells. J Mater Chem 12:1142–1147. https://doi.org/10.1039/B108830K
Canepa P, Sai Gautam G, Hannah DC, Malik R, Liu M, Gallagher KG, Persson KA, Ceder G (2017) Odyssey of multivalent cathode materials: open questions and future challenges. Chem Rev 117:4287–4341. https://doi.org/10.1021/acs.chemrev.6b00614
Cao K, Jiao L, Liu Y, Liu H, Wang Y, Yuan H (2015) Ultra-high capacity lithium-ion batteries with hierarchical CoO nanowire clusters as binder free electrodes. Adv Funct Mater 25:1082–1089. https://doi.org/10.1002/adfm.201403111
Cao K, Liu H, Xu X, Wang Y, Jiao L (2016) FeMnO3: a high-performance Li-ion battery anode material. Chem Commun 52:11414–11417. https://doi.org/10.1039/C6CC04891A
Cao K, Jin T, Yang L, Jiao L (2017) Recent progress in conversion reaction metal oxide anodes for Li-ion batteries. Mater Chem Front 1:2213–2242. https://doi.org/10.1039/C7QM00175D
Carlier D, Cheng JH, Berthelot R, Guignard M, Yoncheva M, Stoyanova R, Hwang BJ, Delmas C (2011) The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery. Dalton Trans 40:9306–9312. https://doi.org/10.1039/C1DT10798D
Chen L, Fan X, Hu E, Ji X, Chen J, Hou S, Deng T, Li J, Su D, Yang X, Wang C (2019) Achieving high-energy density through increasing the output voltage: a highly reversible 5.3 V battery. Chem 5:896–912. https://doi.org/10.1016/j.chempr.2019.02.003
Czyżyk MT, Potze R, Sawatzky GA (1992) Band-theory description of high-energy spectroscopy and the electronic structure of LiCoO2. Phys Rev B 46:3729. https://doi.org/10.1103/PhysRevB.46.3729
Dahn JR, Sacken UV, Michal CA (1990) Structure and electrochemistry of Li1±yNiO2 and a new Li2NiO2 phase with the Ni (OH)2 structure. Solid State Ionics 44:87–97. https://doi.org/10.1016/0167-2738(90)90049-W
Daniel C, Mohanty D, Li J, Wood DL (2014) Cathode materials review. AIP Conference Proceedings 1597:26–43. https://doi.org/10.1063/1.4878478
Delmas C, Braconnier JJ, Fouassier C, Hagenmuller P (1981) Electrochemical intercalation of sodium in NaxCoO2 bronzes. Solid State Ionics 3–4:165–169. https://doi.org/10.1016/0167-2738(81)90076-X
Deng L, Niu X, Ma G, Yang Z, Zeng L, Zhu Y, Guo L (2018) Layered potassium vanadate K0.5V2O5 as a cathode material for nonaqueous potassium ion batteries. Adv Fun Mater 28:1800670. https://doi.org/10.1002/adfm.201800670
Du L, Lin H, Ma Z, Wang Q, Li D, Shen Y, Zhang W, Rui K, Zhu J, Huang W (2019) Using and recycling V2O5 as high performance anode materials for sustainable lithium ion battery. J Power Sources 424:158–164. https://doi.org/10.1016/j.jpowsour.2019.03.103
Fang Y, Yu XY, Lou XWD (2017) A practical high-energy cathode for sodium-ion batteries based on uniform P2-Na0.7 CoO2 microspheres. Angew Chem Int Ed 56:5801–5805. https://doi.org/10.1002/anie.201702024
Franger S, Bach S, Pereira-Ramos JP, Baffier N (2000) Chemistry and electrochemistry of low-temperature manganese oxides as lithium intercalation compounds. J Electrochem Soc 147:3226–3230. https://doi.org/10.1149/1.1393887
Godshall NA, Raistrick ID, Huggins RA (1980) Thermodynamic investigations of ternary lithium-transition metal-oxygen cathode materials. Mater Res Bull 15:561–570. https://doi.org/10.1016/0025-5408(80)90135-X
Goodenough JB (2013) Evolution of strategies for modern rechargeable batteries. Acc Chem Res 46:1053–1061. https://doi.org/10.1021/ar2002705
Goodenough JB, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603. https://doi.org/10.1021/cm901452z
Guan B, Sun W, Wang Y (2016) Carbon-coated MnMoO4 nanorod for high-performance lithium-ion batteries. Electrochim Acta 190:354–359. https://doi.org/10.1016/j.electacta.2016.01.008
Gummow RJ, Dekock A, Thackeray MM (1994) Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells. Solid State Ionics 69:59–67. https://doi.org/10.1016/0167-2738(94)90450-2
Guo S, Liu P, Sun Y, Zhu K, Yi J, Chen M, Ishida M, Zhou H (2015) A high-voltage and ultralong-life sodium full cell for stationary energy storage. Angew Chem Int Ed 54:11701–11705. https://doi.org/10.1002/anie.201505215
Gür TM (2018) Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage. Energy Environ Sci 11:2696–2767. https://doi.org/10.1039/C8EE01419A
Hariharan S, Saravanan K, Ramar V, Palani Balaya P (2013) A rationally designed dual role anode material for lithium-ion and sodium-ion batteries: case study of eco-friendly Fe3O4. Phys Chem Chem Phys 15:2945–2953. https://doi.org/10.1039/C2CP44572G
Hsieh CT, Lin CY, Chen YF, Lin JS (2013) Synthesis of ZnO@graphene composites as anode materials for lithium ion batteries. Electrochim Acta 111:359–365. https://doi.org/10.1016/j.electacta.2013.07.197
Hwang JY, Oh SM, Myung ST, Chung KY, Belharouak I, Sun YK (2015) Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries. Nat Commun 6:6865. https://doi.org/10.1038/ncomms7865
Hwang JY, Myung ST, Sun YK (2017) Sodium-ion batteries: present and future. Chem Soc Rev 46:3529–3614. https://doi.org/10.1039/C6CS00776G
Jeong S, Kim J, Mun J (2019) Self-generated coating of LiCoO2 by washing and heat treatment without coating precursors. J Electrochem Soc 166:A5038–A5044. https://doi.org/10.1149/2.0071903jes
Jiang Y, Hu M, Zhang D, Yuan T, Sun W, Xu B, Yan M (2014) Transition metal oxides for high performance sodium ion battery anodes. Nano Energy 5:60–66. https://doi.org/10.1016/j.nanoen.2014.02.002
Jung YH, Christiansen AS, Johnsen RE, Norby P, Kim DK (2015) In situ X-ray diffraction studies on structural changes of a P2 layered material during electrochemical desodiation/sodiation. Adv Funct Mater 25:3227–3237. https://doi.org/10.1002/adfm.201500469
Kaliyappan K, Liu J, Lushington A, Li R, Sun X (2015) Highly stable Na2/3(Mn0.54Ni0.13Co0.13)O2 cathode modified by atomic layer deposition for sodium-ion batteries. ChemSusChem 8:2537–2543. https://doi.org/10.1002/cssc.201500155
Kaliyappan K, Xiao W, Adair KR, Sham TS, Sun X (2018) Designing high-performance nanostructured P2-type cathode based on a template-free modified pechini method for sodium-ion batteries. ACS Omega 3:8309–8316. https://doi.org/10.1021/acsomega.8b00204
Kang D, Liu Q, Si R, Gu J, Zhang W, Zhang D (2016) Crosslinking-derived MnO/carbon hybrid with ultrasmall nanoparticles for increasing lithium storage capacity during cycling. Carbon 99:138–147. https://doi.org/10.1016/j.carbon.2015.11.068
Keller M, Buchholz D, Passerini S (2017) Layered Na-Ion cathodes with outstanding performance resulting from the synergetic effect of mixed P- and O-type phases. Adv Energy Mater 6:1501555. https://doi.org/10.1002/aenm.201702305
Kim D, Lee E, Slater M, Lu W, Rood S, Johnson CS (2012a) Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application. Electrochem Commun 18:66–69. https://doi.org/10.1016/j.elecom.2012.02.020
Kim SW, Seo DH, Ma X, Ceder G, Kang K (2012b) Electrode materials for rechargeable sodium-ion batteries: potential alternatives to current lithium-ion batteries. Adv Energy Mater 2:710–721. https://doi.org/10.1002/aenm.201200026
Kim JH, Pieczonka NPW, Yang L (2014) Challenges and approaches for high-voltage spinel lithium-ion batteries. Chem Phys Chem 15:1940–1954. https://doi.org/10.1002/cphc.201400052
Kim H, Seo DH, Kim JC, Bo SH, Liu L, Shi T, Ceder G (2017a) Investigation of potassium storage in layered P3-Type K0.5MnO2 Cathode. Adv Mater 29: 1702480. https://doi.org/10.1002/adma.201702480
Kim H, Kim JC, Bo SH, Shi T, Kwon DH, Ceder G (2017b) K-ion batteries based on a P2-type K0.6CoO2 cathode. Adv Energy Mater 7:1700098. https://doi.org/10.1002/aenm.201700098
Kim JH, Park KJ, Kim SJ, Yoon CS, Sun YK (2019) A method of increasing the energy density of layered Ni-rich Li[Ni1−2xCoxMnx]O2 cathodes (x = 0.05, 0.1, 0.2). J Mater Chem 7:2694–2701. https://doi.org/10.1039/C8TA10438G
Komaba S, Takei C, Nakayama T, Ogata A, Yabuuchi N (2010) Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2. Electrochem Commun 12:355–358. https://doi.org/10.1016/j.elecom.2009.12.033
Komaba S, Yabuuchi N, Nakayama T, Ogata A, Ishikawa T, Nakai I (2012) Study on the reversible electrode reaction of Na1–xNi0.5Mn0.5O2 for a rechargeable sodium-ion battery. Inorg Chem 51:6211–6220. https://doi.org/10.1021/ic300357d
Kötz R, Carlen M (2000) Principles and applications of electrochemical capacitors. Electrochim Acta 45:2483–2498. https://doi.org/10.1016/S0013-4686(00)00354-6
Kulbota K, Komaba S (2015) Review—practical issues and future perspective for Na-ion batteries. J Electrochem Soc 162:A2538–A2550. https://doi.org/10.1149/2.0151514jes
Lai L, Zhu J, Li Z, Yu DYW, Jiang S, Cai X, Yan Q, Lam YM, Shen Z, Lin J (2014) Co3O4/nitrogen modified graphene electrode as Li-ion battery anode with high reversible capacity and improved initial cycle performance. Nano Energy 3:134–143. https://doi.org/10.1016/j.nanoen.2013.05.014
Larcher D, Tarascon JM (2015) Towards greener and more sustainable batteries for electrical energy storage. Nat Chem 7:19–29. https://doi.org/10.1038/nchem.2085
Li W, Dahn JR, Wainwright DS (1994) Rechargeable lithium batteries with aqueous electrolytes. Science 264:1115–1118. https://doi.org/10.1126/science.264.5162.1115
Li GR, Feng X, Ding Y, Ye SH, Gao XP (2012a) AlF3-coated Li(Li0.17Ni0.25Mn0.58)O2 as cathode material for Li-ion batteries. Electrochim Acta 78:308–315. https://doi.org/10.1016/j.electacta.2012.05.142
Li L, Guo ZP, Du AJ, Liu HK (2012b) Rapid microwave-assisted synthesis of Mn3O4-graphene nanocomposite and its lithium storage properties. J Mater Chem 22:3600–3605. https://doi.org/10.1039/C2JM15075A
Li J, Xiong S, Li X, Qian Y (2013) A facile route to synthesize multiporous MnCo2O4 and CoMn2O4 spinel quasi-hollow spheres with improved lithium storage properties. Nanoscale 5:2045–2054. https://doi.org/10.1039/C2NR33576J
Li X, Wu D, Zhou YN, Liu L, Yang XQ, Ceder G (2014) O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: a quaternary layered cathode compound for rechargeable Na ion batteries. Electrochem Commun 49:51–54. https://doi.org/10.1016/j.elecom.2014.10.003
Li B, Li X, Li W, Wang Y, Uchaker E, Pei Y, Cao X, Li S, Huang B, Cao G (2016) Mesoporous tungsten trioxide polyaniline nanocomposite as an anode material for high-performance lithium-ion batteries. Chem Nano Mat 2:281–289. https://doi.org/10.1002/cnma.201500208
Li H, Zhang N, Li J, Dahn JR (2018a) Updating the structure and electrochemistry of LixNiO2 for 0 ≤ x ≤ 1. J Electrochem Soc 165:A2985–A2993. https://doi.org/10.1149/2.0381813jes
Li L, Zheng Y, Zhang S, Yang J, Shao Z, Guo Z (2018b) Recent progress on sodium ion batteries: potential high-performance anodes. Energy Environ Sci 11:2310–2340. https://doi.org/10.1039/C8EE01023D
Liang L, Sun X, Denis DK, Zhang J, Hou L, Liu Y, Yuan C (2019) Ultralong layered NaCrO2 nanowires: a competitive wide-temperature-operating cathode for extraordinary high-rate sodium-ion batteries. ACS Appl Mater Interfaces 11:4037–4046. https://doi.org/10.1021/acsami.8b20149
Lin M, Ben L, Sun Y, Wang H, Yang Z, Gu L, Yu X, Yang X, Zhao H, Yu R, Armand M, Huang X (2015) Insight into the atomic structure of high-voltage spinel LiNi0.5Mn1.5O4 cathode material in the first cycle. Chem Mater 27:292–303. https://doi.org/10.1021/cm503972a
Liu Y, Zhao Y, Yu Y, Li J, Ahmad M, Sun H (2014) Hierarchical CoNiO2 structures assembled from mesoporous nanosheets with tunable porosity and their application as lithium-ion battery electrodes. New J Chem 38:3084–3091. https://doi.org/10.1039/C4NJ00258J
Liu Z, Yu XY, Paik U (2016) Etching-in-a-box: a novel strategy to synthesize unique yolk-shelled Fe3O4@carbon with an ultralong cycling life for lithium storage. Adv Energy Mater 6:1502318. https://doi.org/10.1002/aenm.201502318
Liu C, Luo S, Huang H, Wang Z, Hao A, Zhai Y, Wang Z (2017) K0.67Ni0.17Co0.17Mn0.66O2: a cathode material for potassium-ion battery. Electrochem Commun 82:150–154. https://doi.org/10.1016/j.elecom.2017.08.008
Liu Q, Wang H, Jiang C, Tang Y (2019) Multi-ion strategies towards emerging rechargeable batteries with high performance. Energy Storage Mater. https://doi.org/10.1016/j.ensm.2019.03.028
Lu Z, Dahn JR (2001) In situ X-ray diffraction study of P2 Na2/3[Ni1/3Mn2/3]O2. J Electrochem Soc 148:A1225–A1229. https://doi.org/10.1149/1.1407247
Lu J, Chen Z, Pan F, Cui Y, Amine K (2018) High-performance anode materials for rechargeable lithium-ion batteries. Electrochem Energy Rev 1:35–53. https://doi.org/10.1007/s41918-018-0001-4
Ma X, Chen H, Ceder G (2011) Electrochemical properties of monoclinic NaMnO2. J Electrochem Soc 158:A1307–A1312. https://doi.org/10.1149/2.035112jes
Ma J, Hu P, Cui G, Chen L (2016) Surface and interface issues in spinel LiNi0.5Mn1.5O4: insights into a potential cathode material for high energy density lithium ion batteries. Chem Mater 28:3578–3606. https://doi.org/10.1021/acs.chemmater.6b00948
Ma C, Alvarado J, Xu J, Clément RJ, Kodur M, Tong W, Grey CP, Meng YS (2017) Exploring oxygen activity in the high energy P2-type Na0.78Ni0.23Mn0.69O2 cathode material for Na-ion batteries. J Am Chem Soc 139:4835–4845. https://doi.org/10.1021/jacs.7b00164
Maggay IVB, Marie Z, De Juan L, Lu JS, Nguyen MT, Yonezawa T, Chan TS, Liu WR (2018) Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries. Sci Rep 8:8839. https://doi.org/10.1038/s41598-018-27083-z
Manalastas W Jr, Kumar S, Verma V, Zhang L, Yuan D, Srinivasan M (2019) Water in rechargeable multivalent-ion batteries: an electrochemical pandora’s box. Chem Sus Chem 12:379–396. https://doi.org/10.1002/cssc.201801523
Mariyappan S, Wang Q, Tarascon JM (2018) Will sodium layered oxides ever be competitive for sodium ion battery applications? J. Electrochem Soc 165:A3714–A3722. https://doi.org/10.1149/2.0201816jes
Masese T, Yoshii K, Yamaguchi Y, Okumura T, Huang ZD, Kato M, Kubota K, Furutani J, Orikasa Y, Senoh H, Sakaebe H, Shikano M (2018) Rechargeable potassium-ion batteries with honeycomb-layered tellurates as high voltage cathodes and fast potassium-ion conductors. Nat Commun 9:3823. https://doi.org/10.1038/s41467-018-06343-6
Masese T, Yoshii K, Kato M, Kubota K, Huang ZD, Senoh H, Shikano M (2019) A high voltage honeycomb layered cathode framework for rechargeable potassium-ion battery: P2-type K2/3Ni1/3Co1/3Te1/3O2. Chem Commun 55:985–988. https://doi.org/10.1039/C8CC07239F
Matsui M, Mizukoshi F, Imanishi N (2015) Improved cycling performance of P2-type layered sodium cobalt oxide by calcium substitution. J Power Sources 280:205–209. https://doi.org/10.1016/j.jpowsour.2015.01.044
Mizushima K, Jones PC, Wiseman PJ, Goodenough JB (1980) LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density. Mater Res Bull 15:783–789. https://doi.org/10.1016/0025-5408(80)90012-4
Newman GH, Klemann LP (1980) Ambient temperature cycling of an Na - TiS2 cell. J Electrochem Soc 127:2097–2099. https://doi.org/10.1149/1.2129353
Ni J, Zhao Y, Li L, Mai L (2015) Ultrathin MoO2 nanosheets for superior lithium storage. Nano Energy 11:129–135. https://doi.org/10.1016/j.nanoen.2014.10.027
Oh SM, Myung ST, Yoon CS, Lu J, Hassoun J, Scrosati B, Amine K, Sun YK (2014a) Advanced Na[Ni0.25Fe0.5Mn0.25]O2/C–Fe3O4 sodium-ion batteries using EMS electrolyte for energy storage. Nano Lett 14:1620–1626. https://doi.org/10.1021/nl500077v
Oh SM, Myung ST, Hwang JY, Scrosati B, Amine K, Sun YK (2014b) High capacity O3-type Na[Li0.05(Ni0.25Fe0.25Mn0.5)0.95]O2 cathode for sodium ion batteries. Chem Mater 26:6165–6171. https://doi.org/10.1021/cm502481b
Ohzuku T, Ueda A (1994) Solid-state redox reactions of LiCoO2 (R3̅m) for 4 volt secondary lithium cells. J Electrochem Soc 141:2972–2977. https://doi.org/10.1149/1.2059267
Ohzuku T, Ueda A, Nagayama M (1993) Electrochemistry and structural chemistry of LiNiO2 (R3̅m) for 4 volt secondary lithium cells. J Electrochem Soc 140:1862–1870. https://doi.org/10.1149/1.2220730
Park GD, Kim JH, Choi YJ, Kang YC (2015) Large-scale production of MoO3-reduced graphene oxide powders with superior lithium storage properties by spray-drying process. Electrochim Acta 173:581–587. https://doi.org/10.1016/j.electacta.2015.05.090
Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499. https://doi.org/10.1038/35035045
Preetham P, Mohapatra S, Nair SV, Santhanagopalan D, Rai AK (2016) Ultrafast pyro-synthesis of NiFe2O4 nanoparticles within a full carbon network as a high-rate and cycle-stable anode material for lithium ion batteries. RSC Adv 6:38064–38070. https://doi.org/10.1039/C6RA03670H
Qian J, Liu L, Yang J, Li S, Wang X, Zhuang HL, Lu Y (2018) Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries. Nat Commun 9:4918. https://doi.org/10.1038/s41467-018-07296-6
Qu QT, Shi Y, Tian S, Chen YH, Wu YP, Holze R (2009) A new cheap asymmetric aqueous supercapacitor: activated carbon//NaMnO2. J Power Sources 194:1222–1225. https://doi.org/10.1016/j.jpowsour.2009.06.068
Qu Q, Fu L, Zhan X, Samuelis D, Maier J, Li L, Tian S, Li Z, Wu Y (2011) Porous LiMn2O4 as cathode material with high power and excellent cycling for aqueous rechargeable lithium batteries. Energy Environ Sci 4:3985–3990. https://doi.org/10.1039/C0EE00673D
Reimers JN, Dahn JR (1992) Electrochemical and in situ X-ray diffraction studies of lithium intercalation in LixCoO2. J Electrochem Soc 139:2091–2097. https://doi.org/10.1149/1.2221184
Rougier A, Gravereau P, Delmas C (1996) Optimization of the composition of the Li1 − zNi1 + z O 2 electrode materials: structural, magnetic, and electrochemical studies. J Electrochem Soc 143:1168–1175. https://doi.org/10.1149/1.1836614
Rozier P, Tarascon JM (2015) Review—Li-rich layered oxide cathodes for next-generation li-ion batteries: chances and challenges. J Electrochem Soc 162:A2450–A2499. https://doi.org/10.1149/2.0111514jes
Sambandam B, Soundharrajan V, Mathew V, Song J, Kim S, Jo J, Tung DP, Kim S, Kim J (2016) Metal–organic framework-combustion: a new, cost-effective and one-pot technique to produce a porous Co3V2O8 microsphere anode for high energy lithium ion batteries. J Mater Chem A 4:14605–14613. https://doi.org/10.1039/C6TA05919H
Sambandam B, Soundharrajan V, Song J, Kim S, Jo J, Pham DT, Kim S, Mathew V, Kim J (2017) Zn3V2O8 porous morphology derived through a facile and green approach as an excellent anode for high-energy lithium ion batteries. Chem Eng J 328:454–4613. https://doi.org/10.1016/j.cej.2017.07.050
Sambandam B, Soundharrajan V, Kim S, Alfaruqi MH, Jo J, Kim S, Mathew V, Sun YK, Kim J (2018) Aqueous rechargeable Zn-ion batteries: an imperishable and high-energy Zn2V2O7 nanowire cathode through intercalation regulation. J Mater Chem A 5:3850–3856. https://doi.org/10.1039/C7TA11237H
Sathiya M, Hemalatha K, Ramesha K, Tarascon JM, Prakash A (2012) Synthesis, structure, and electrochemical properties of the layered sodium insertion cathode material: NaNi1/3Mn1/3Co1/3O2. Chem Mater 24:1846–1853. https://doi.org/10.1021/cm300466b
Sathiya M, Jacquet Q, Doublet ML, Karakulina OM, Hadermann J, Tarascon JM (2018) A chemical approach to raise cell voltage and suppress phase transition in O3 sodium layered oxide electrodes. Adv Energy Mater 8:1702599. https://doi.org/10.1002/aenm.201702599
Sato T, Sato K, Zhao W, Kajiya Y, Yabuuchi N (2018) Metastable and nanosize cation-disordered rocksalt-type oxides: revisit of stoichiometric LiMnO2 and NaMnO2. J Mater Chem A 6:13943–13951. https://doi.org/10.1039/C8TA03667E
Shacklette LW, Jow TR, Townsend L (1988) Rechargeable electrodes from sodium cobalt bronzes. J Electrochem Soc 135:2669–2674. https://doi.org/10.1149/1.2095407
Shan X, Charles DS, Lei Y, Qiao R, Wang G, Yang W, Feygenson M, Su D, Teng X (2016) Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage. Nat Commun 7:13370. https://doi.org/10.1038/ncomms13370
Shi SJ, Tu JP, Tang YY, Liu XY, Zhang YQ, Wang XL, Gu CD (2013) Enhanced cycling stability of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by surface modification of MgO with melting impregnation method. Electrochim Acta 88:671–679. https://doi.org/10.1016/j.electacta.2012.10.111
Singh G, Acebedo B, Cabanas MC, Shanmukaraj D, Armand M, Rojo T (2013) An approach to overcome first cycle irreversible capacity in P2-Na2/3[Fe1/2Mn1/2]O2. Electrochem Commun 37:61–63. https://doi.org/10.1016/j.elecom.2013.10.008
Singh G, Tapia-Ruiz N, Lopez del Amo JM, Maitra U, Somerville JW, Armstrong AR, Martinez de Ilarduya J, Rojo T, Bruce PG (2016) High voltage Mg-doped Na0.67Ni0.3–xMgxMn0.7O2 (x = 0.05, 0.1) Na-ion cathodes with enhanced stability and rate capability. Chem Mater 28:5087–5094. https://doi.org/10.1021/acs.chemmater.6b01935
Soundharrajan V, Sambandam B, Kim S, Alfaruqi MH, Putro DY, Jo J, Kim S, Mathew V, Sun YK, Kim J (2018) Na2V6O16·3H2O barnesite nanorod: an open door to display a stable and high energy for aqueous rechargeable Zn-ion batteries as cathodes. Nano Lett 18:2402–2410. https://doi.org/10.1021/acs.nanolett.7b05403
Sun X, Yan C, Chen Y, Si W, Deng J, Oswald S, Liu L, Schmidt OG (2013) Three-dimensionally “curved” NiO nanomembranes as ultrahigh rate capability anodes for Li-ion batteries with long cycle lifetimes. Adv Energy Mater 4:1300912. https://doi.org/10.1002/aenm.201300912
Suo L, Borodin O, Wang Y, Rong X, Sun W, Fan X, Xu S, Schroeder MA, Cresce AV, Wang F, Yang C, Hu YS, Xu K, Wang C (2017) “Water-in-Salt” electrolyte makes aqueous sodium-ion battery safe, green, and long-lasting. Adv Energy Mater 7:1701189. https://doi.org/10.1002/aenm.201701189
Tabuchi M, Kuriyama N, Takamori K, Imanari Y, Nakane K (2016) Appearance of Lithium-Excess LiNiO2with High Cyclability Synthesized by Thermal Decomposition Route from LiNiO2-Li2NiO3 Solid Solution. J Electrochem Soc 163:A2312–A2317. https://doi.org/10.1149/2.0861610jes
Talaie E, Kim SY, Chen N, Nazar LF (2017) Structural evolution and redox processes involved in the electrochemical cycling of P2–Na0.67[Mn0.66Fe0.20Cu0.14]O2. Chem Mater 29:6684–6697. https://doi.org/10.1021/acs.chemmater.7b01146
Tang W, Liu LL, Tian S, Li L, Yue YB, Wu YP, Guan SY, Zhu K (2010a) Nano-LiCoO2 as cathode material of large capacity and high rate capability for aqueous rechargeable lithium batteries. Electrochem Commun 12:1524–1526. https://doi.org/10.1016/j.elecom.2010.08.024
Tang W, Liu LL, Tian S, Li L, Lia LL, Yue YB, Bai Y, Wu YP, Zhu K, Holzec R (2011a) LiMn2O4 nanorods as a super-fast cathode material for aqueous rechargeable lithium batteries. Electrochem Commun 13:1159–1162. https://doi.org/10.1016/j.elecom.2011.09.008
Tang W, Liu LL, Tian S, Li L, Yue YB, Wu YP, Guan SY, Zhu K (2010b) Nano-LiCoO2 as cathode material of large capacity and high rate capability for aqueous rechargeable lithium batteries. Electrochem Commun 12:1524–1526. https://doi.org/10.1016/j.elecom.2010.08.024
Tang W, Tian S, Liu LL, Li L, Zhang HP, Yue YB, Bai Y, Wu YP, Zhu K (2011b) Nanochain LiMn2O4 as ultra-fast cathode material for aqueous rechargeable lithium batteries. Electrochem Commun 13:205–208. https://doi.org/10.1016/j.elecom.2010.12.015
Thackeray MM, David WIF, Bruce PG, Goodenough JB (1983) Lithium insertion into manganese spinels. Mater Res Bull 18:461–472. https://doi.org/10.1016/0025-5408(83)90138-1
Tong W, Qingxin Chu Q, Meng Y, Wang X, Yang B, Gao J, Zhao X, Liu X (2018) Synthesis of mesoporous orthorhombic LiMnO2 cathode materials via a one-step flux method for high performance lithium-ion batteries. Mater Res Express 5:065511. https://doi.org/10.1088/2053-1591/aac9a2
Tsutomu O, Yoshinari M (2001) Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries. Chem Lett 30:642–643. https://doi.org/10.1246/cl.2001.642
Vaalma C, Giffin GA, Buchholz D, Passerini S (2016) Non-aqueous K-ion battery based on layered K0.3MnO2 and hard carbon/carbon black. J Electrochem Soc 163:A1295–A1299. https://doi.org/10.1149/2.0921607jes
Vassilaras P, Ma X, Li X, Ceder G (2013) Electrochemical properties of monoclinic NaNiO2. J Electrochem Soc 160:A207–A211. https://doi.org/10.1149/2.023302jes
Vassilaras P, Toumar AJ, Ceder G (2014) Electrochemical properties of NaNi1/3Co1/3Fe1/3O2 as a cathode material for Na-ion batteries. Electrochem Commun 38:79–81. https://doi.org/10.1016/j.elecom.2013.11.015
Vinckevičiu̅tė J, Radin MD, Van der Ven A (2016) Stacking-sequence changes and Na ordering in layered intercalation materials. Chem Mater 28:8640–8650. https://doi.org/10.1021/acs.chemmater.6b03609
Wang G, Fu L, Zhao N, Yang L, Wu Y, Wu H (2006) An aqueous rechargeable lithium battery with good cycling performance. Angew Chem Int Ed 46:295–297. https://doi.org/10.1002/anie.200603699
Wang L, Wei Z, Mao M, Wang H, Li Y, Ma J (2019) Metal oxide/graphene composite anode materials for sodium-ion batteries. Energy Storage Mater 16:434–454. https://doi.org/10.1016/j.ensm.2018.06.027
Wang PF, Yao HR, Liu XY, Zhang JN, Gu L, Yu ZQ, Yin YX, Guo YG (2017a) Ti-substituted NaNi0.5Mn0.5-xTixO2 cathodes with reversible O3−P3 phase transition for high-performance sodium-ion batteries. Adv Mater 29: 1700210. https://doi.org/10.1002/adma.201700210
Wang PF, You Y, Yin YX, Guo YG (2016) An O3-type NaNi0.5Mn0.5O2 cathode for sodium-ion batteries with improved rate performance and cycling stability. J Mater Chem A 4:17660–17664. https://doi.org/10.1039/C6TA07589D
Wang X, Liu G, Iwao T, Okubo M, Yamada A (2014) Role of ligand-to-metal charge transfer in O3-type NaFeO2–NaNiO2 solid solution for enhanced electrochemical properties. J Phys Chem C 118:2970–2976. https://doi.org/10.1021/jp411382r
Wang X, Xu X, Niu C, Meng J, Huang M, Liu X, Liu Z, Mai L (2017b) Earth abundant Fe/Mn-based layered oxide interconnected nanowires for advanced K-ion full batteries. Nano Lett 17:544–550. https://doi.org/10.1021/acs.nanolett.6b04611
Wang Y, Mu L, Liu J, Yang Z, Yu X, Gu L, Hu YS, Li H, Yang XQ, Chen L, Huang X (2015) Novel high capacity positive electrode material with tunnel-type structure for aqueous sodium-ion batteries. Adv Energy Mater 5:1501005. https://doi.org/10.1002/aenm.201501005
Whitacre JF, Tevar A, Sharma S (2010) Na4Mn9O18 as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device. Electrochem Commun 12:463–466. https://doi.org/10.1016/j.elecom.2010.01.020
Whittingham MS (1976) Electrical energy storage and intercalation chemistry. Science 192:1126–1127. https://doi.org/10.1126/science.192.4244.1126
Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104:4271–4302. https://doi.org/10.1021/cr020731c
Whittingham MS (2008) Materials challenges facing electrical energy storage. Mater Res Bull 33:411–419. https://doi.org/10.1557/mrs2008.82
Winter M, Brodd RJ (2004) What are batteries, fuel cells, and supercapacitors? Chem Rev 104:4245–4270. https://doi.org/10.1021/cr020730k
Wu M, Yang J, Feng T, Jiang W, Xia D, Gong F, Liao J (2017) Graphene coated Co3V2O8 micro-pencils for enhanced-performance in lithium ion batteries. New J Chem 41:10634–10639. https://doi.org/10.1039/C7NJ02219K
Xu C, Li B, Du H, Kang F (2012) Energetic zinc ion chemistry: the rechargeable zinc ion battery. Angew Chem Int Ed 51:933–935. https://doi.org/10.1002/anie.201106307
Xu J, Lee DH, Clement RJ, Yu X, Leskes M, Pell AJ, Pintacuda G, Yang XQ, Grey CP, Meng YS (2014) Identifying the critical role of Li substitution in P2–Nax[LiyNizMn1–y–z]O2 (0 < x, y, z < 1) intercalation cathode materials for high-energy Na-ion batteries. Chem Mater 26:1260–1269. https://doi.org/10.1021/cm403855t
Xu YS, Duan SY, Sun YG, Bin DS, Tao XS, Zhang D, Liu Y, Cao AM, Wan LJ (2019) Recent developments in electrode materials for potassium-ion batteries. J Mater Chem A 7:4334–4352. https://doi.org/10.1039/C8TA10953B
Yabuuchi N, Hara R, Kubota K, Paulsen J, Kumakura S, Komaba S (2014) A new electrode material for rechargeable sodium batteries: P2-type Na2/3[Mg0.28Mn0.72]O2 with anomalously high reversible capacity. J Mater Chem A 2:16851–16855. https://doi.org/10.1039/C4TA04351K
Yabuuchi N, Kajiyama M, Iwatate J, Mishikawa H, Hitomi S, Okuyama R, Usui R, Yamada Y, Komaba S (2012b) P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries. Nat Mater 11:512–517. https://doi.org/10.1038/nmat3309
Yabuuchi N, Yano M, Yoshida H, Kuze S, Komaba S (2013) Synthesis and electrode performance of O3-type NaFeO2-NaNi1/2Mn1/2O2 solid solution for rechargeable sodium batteries. J Electrochem Soc 160:A3131–A3137. https://doi.org/10.1149/2.018305jes
Yabuuchi N, Yoshida H, Komaba S (2012a) Crystal structures and electrode performance of alpha-NaFeO2 for rechargeable sodium batteries. Electrochemistry 80:716–719. https://doi.org/10.5796/electrochemistry.80.716
Yang C, Chen J, Qing T, Fan X, Sun W, Cresce A, Ding MS, Borodin O, Vatamanu J, Schroeder MA, Eidson N, Wang C, Xu K (2017) 4.0 V aqueous Li-ion batteries. Joule 1:122–132. https://doi.org/10.1016/j.joule.2017.08.009
Yang K, Fan L, Guo J, Qu X (2012) Significant improvement of electrochemical properties of AlF3-coated LiNi0.5Co0.2Mn0.3O2cathode materials. Electrochim Acta 63:363–368. https://doi.org/10.1016/j.electacta.2011.12.121
Yao HR, Wang PF, Gong Y, Zhang J, Yu X, Gu L, OuYang C, Yin YX, Hu E, Yang XQ, Stavitski E, Guo YG, Wan LJ (2017) Designing air-stable O3-type cathode materials by combined structure modulation for Na-Ion batteries. J Am Chem Soc 139:8440–8443. https://doi.org/10.1021/jacs.7b05176
Yoon CS, Jun D, Myung ST, Sun YK (2017) Structural stability of LiNiO2 cycled above 4.2 V. ACS Energy Lett 2:1150–1155. https://doi.org/10.1021/acsenergylett.7b00304
Yoshida H, Yabuuchi N, Komaba S (2013) NaFe0.5Co0.5O2 as high energy and power positive electrode for Na-ion batteries. Electrochem Commun 34:60–63. https://doi.org/10.1016/j.elecom.2013.05.012
Yoshida J, Guerin E, Arnault M, Constantin C, Mortemard de Boisse B, Calier D, Guignard M, Delmas C (2014) New P2 - Na0.70Mn0.60Ni0.30Co0.10O2 layered oxide as electrode material for Na-ion batteries. J Electrochem Soc 161:A1987–A1991. https://doi.org/10.1149/2.0121414jes
You Y, Dolocan A, Li W, Manthiram A (2019) Understanding the air-exposure degradation chemistry at a nanoscale of layered oxide cathodes for sodium-ion batteries. Nano Lett 19:182–188. https://doi.org/10.1021/acs.nanolett.8b03637
Yu F, Zhang S, Fang C, Liu Y, He S, Xia J, Yang J, Zhang N (2017) Electrochemical characterization of P2-type layered Na2/3Ni1/4Mn3/4O2 cathode in aqueous hybrid sodium/lithium ion electrolyte. Ceram Int 43:9960–9967. https://doi.org/10.1016/j.ceramint.2017.05.007
Yuan DD, Wang YX, Cao YL, Ai XP, Yang HX (2015) Improved electrochemical performance of Fe-substituted NaNi0.5Mn0.5O2 cathode materials for sodium-ion batteries. ACS Appl Mater Interfaces 7:8585–8591. https://doi.org/10.1021/acsami.5b00594
Zhang N, Han X, Liu Y, Hu X, Zhao Q, Chen J (2015) 3D porous γ-Fe2O3@C nanocomposite as high-performance anode material of Na-ion batteries. Adv Energy Mater 5:1401123. https://doi.org/10.1002/aenm.201401123
Zhang W, Liu Y, Guo Z (2019b) Approaching high-performance potassium-ion batteries via advanced design strategies and engineering. Sci Adv 5:eaav7412. https://doi.org/10.1126/sciadv.aav7412
Zhang XH, Pang WL, Wan F, Guo JZ, Lü HY, Li JY, Xing YM, Zhang JP, Wu XL (2016) P2–Na2/3Ni1/3Mn5/9Al1/9O2 microparticles as superior cathode material for sodium-ion batteries: enhanced properties and mechanism via graphene connection. ACS Appl Mater Interfaces 8:20650–20659. https://doi.org/10.1021/acsami.6b03944
Zhang Y, Zhang R, Huang Y (2019a) Air-stable NaxTMO2 cathodes for sodium storage. Front Chem 7:335. https://doi.org/10.3389/fchem.2019.00335
Zhou XY, Zhang J, Su QM, Shi JJ, Liu Y, Du GH (2014) Nanoleaf-on-sheet CuO/graphene composites: microwave-assisted assemble and excellent electrochemical performances for lithium ion batteries. Electrochim Acta 125:615–621. https://doi.org/10.1016/j.electacta.2014.01.155
Zhu XJ, Zhu YW, Murali S, Stoller MD, Ruoff RS (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5:3333–3338. https://doi.org/10.1021/nn200493r
Zhu Y, Qi X, Chen X, Zhou X, Zhang X, Wei J, Hu Y, Zhou Z (2016) A P2-Na0.67Co0.5Mn0.5O2 cathode material with excellent rate capability and cycling stability for sodium ion batteries. J Mater Chem 4:11103–11109. https://doi.org/10.1039/C6TA02845D
Zou F, Chen YM, Liu K, Yu Z, Liang W, Bhaway SM, Gao M, Zhu Y (2016) Metal organic frameworks derived hierarchical hollow NiO/Ni/graphene composites for lithium and sodium storage. ACS Nano 10:377–386. https://doi.org/10.1021/acsnano.5b05041
Acknowledgment
The authors dedicated the work to the deceased eminent Professor Dr. P. T. Manoharan, INSA Senior Scientist, Department of Chemistry, Indian Institute of Technology-Madras, for his valuable scientific research contributions. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (2018R1A5A1025224). This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government MSIT (NRF-2020R1A2C3012415).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Sambandam, B., Paul David, S., Sakthivel, T., Sivaramalingam, A., Soosaimanickam, A., Kim, J. (2021). Metal Oxides for Rechargeable Batteries Energy Applications. In: Rajendran, S., Qin, J., Gracia, F., Lichtfouse, E. (eds) Metal and Metal Oxides for Energy and Electronics. Environmental Chemistry for a Sustainable World, vol 55. Springer, Cham. https://doi.org/10.1007/978-3-030-53065-5_1
Download citation
DOI: https://doi.org/10.1007/978-3-030-53065-5_1
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-53064-8
Online ISBN: 978-3-030-53065-5
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)