Abstract
Successful application of selective electron beam melting to a novel CoNi-based superalloy named SB-CoNi-10 is demonstrated. Crack-free as-printed microstructures exhibit excellent ductilities above 30% and ultimate tensile strengths above 1.1 GPa at room temperature in tension. Conventional post-processing consisting of a super-solvus hot isostatic pressing (HIP), a solution heat treatment (SHT), and a low-temperature aging has been applied to remove microstructural inhomogeneities present in the as-printed microstructure. The microstructures of the as-printed and HIP+SHT+Aged alloys have been investigated to determine the effect of post-processing heat treatments on the nanoscale \(\gamma \)/\(\gamma ^{\prime }\) microstructure and the mesoscale grain structure. Tensile tests have been conducted at room temperature and elevated temperatures above 850 \(^{\circ }\)C to investigate mechanical properties in both the as-printed and HIP+SHT+Aged conditions. The high-temperature ductility and strength are strongly affected by the microstructure, with a mostly columnar-grained microstructure in the as-printed condition exhibiting superior ductility to the fully recrystallized microstructure in the HIP+SHT+Aged condition.
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CM 247\(^\circledR \) is a registered trademark of the Cannon-Muskegon Corporation.
References
Körner C (2016) Additive manufacturing of metallic components by selective electron beam melting - a review. Int. Mater. Rev. 61(5):361–377
Babu SS, Raghavan N, Raplee J, Foster SJ, Frederick C, Haines M, Dinwiddie R, Kirka MK, Plotkowski A, Lee Y, Dehoff RR (2018) Additive manufacturing of nickel superalloys: opportunities for innovation and challenges related to qualification. Metall. Mater. Trans. A. 49(9):3764–3780
Kontis P, Chauvet E, Peng Z, He J, Kwiatkowski da Silva A, Raabe D, Tassin C, Blandin J-J, Abed S, Dendievel R, Gault B, Martin G (2019) Atomic-scale grain boundary engineering to overcome hot-cracking in additively-manufactured superalloys. Acta Mater. 177:209–221
Peng H, Shi Y, Gong S, Guo H, Chen B (2018) Microstructure, mechanical properties and cracking behaviour in a \(\gamma ^{\prime }\)-precipitation strengthened nickel-base superalloy fabricated by electron beam melting. Mater. Design 159:155–169
Chauvet E, Kontis P, Jägle EA, Gault B, Raabe D, Tassin C, Blandin J-J, Dandievel R, Vayre B, Abed S, Martin G (2019) Hot cracking mechanism affecting a non-weldable Ni-based superalloy produced by selective electron beam melting. Acta Mater. 142:82–94
Lee CS (1971) Precipitation-hardening characteristics of ternary cobalt-aluminum-X alloys. PhD thesis, Arizona State University.
Sato J, Omori T, Oikawa K, Ohnuma I, Kainuma R, Ishida K (2006) Cobalt-base high-temperature alloys. Science 312:90–91
Suzuki A, Denolf GC, Pollock TM (2007) Flow stress anomalies in \(\gamma \)/\(\gamma ^{\prime }\) two-phase Co-Al-W-base alloys. Scipta Mater. 56:385–388
Titus MS, Suzuki A, Pollock TM (2012) High temperature creep of new L1\(_2\)-containing cobalt-base superalloys. In: Huron ES, Reed RC, Hardy MC, Mills MJ, Montero RE, Portella PD, Telesman J (ed) Superalloys 2012: 12\(^{\rm {th}}\) International Symposium on Superalloys. The Minerals, Metals & Materials Society, Pittsburgh; pp 823–832
Makineni SK, Nithin B, Chattopadhyay K (2015) A new tungsten-free \(\gamma \)-\(\gamma ^{\prime }\) Co-Al-Mo-Nb-based superalloy. Scripta Mater. 98:36–39
Ooshima M, Tanaka K, Okamoto NL, Kishida K, Inui H (2010) Effects of quaternary alloying elements on the \(\gamma ^{\prime }\) solvus temperature of Co-Al-W based alloys with fcc/L1\(_2\) two-phase microstructures. J. Alloy Compd. 508(1):71–78
Yan HY, Vorontsov VA, Dye D (2014) Effect of alloying on the oxidation behaviour of Co-Al-W superalloys. Corros. Sci. 83:382–395
Shinagawa K, Omori T, Sato J, Oikawa K, Ohnuma I, Kainuma R, Ishida K (2008) Phase equilibria and microstructure on \(\gamma ^{\prime }\) phase in Co-Ni-Al-W system. Mater. Trans. 49(6):1474–1479
Stewart CA, Murray SP, Suzuki A, Pollock TM, Levi CG (2020) Accelerated discovery of oxidation resistant CoNi-base \(\gamma \)/\(\gamma ^{\prime }\) alloys with high L1\(_2\) solvus and low density. Mater. Design 189, 108445. https://doi.org/10.1016/j.matdes.2019.108445
Pollock TM, Stewart CA, Murray SP, Levi CG (2020) High temperature oxidation resistant Co-based gamma/gamma prime alloys DMREF-Co. U.S. Patent Application 16/375,687. 7 May 2020
Tsunekane M, Suzuki A, Pollock TM (2011) Single-crystal solidification of new Co-Al-W-base alloys. Intermetallics 19(5):636–643
Lenthe WC, Singh S, De Graef M (2019) A spherical harmonic transform approach to the indexing of electron back-scattered diffraction patterns. Ultramicroscopy 207, 112841. https://doi.org/10.1016/j.ultramic.2019.112841
Goodlet BR, Mills L, Bales B, Charpagne M-A, Murray SP, Lenthe WC, Petzold L, Pollock TM (2018) Elastic properties of novel Co- and CoNi-based superalloys determined through bayesian inference and resonant ultrasound spectroscopy. Metall. Mater. Trans. A 49(6):2324–2339
Tin S (2009) Intelligent alloy design: engineering single crystals superalloys amenable for manufacture. Mater. Sci. Tech. 25(2):136–146
Polonsky AT, Echlin MP, Lenthe WC, Dehoff RR, Kirka MM, Pollock TM (2018) Defects and 3D structural inhomogeneity in electron beam additively manufactured Inconel 718. Mater. Charact. 143:171–181
Chen YQ, Francis E, Robson J, Preuss M, Haigh SJ (2015) Compositional variations for small-scale gamma prime (\(\gamma ^{\prime }\)) precipitates formed at different cooling rates in an advanced Ni-based superalloy. Acta Mater. 85:199–206
Asavavisithchai S, Homkrajai W, Wangyao P (2010) Strain-age cracking after postweld heat treatments in inconel 738 superalloy. High Temp. Mater. Proc. 29(1-2):61–67
Szczotok A, Przeliorz R (2012) Phase transformations in CMSX-4 nickel-base superalloy. IOP Conf. Ser.-Mat. Sc. 35, 012005. https://doi.org/10.1088/1757-899X/35/1/012005
Lass EA, Sauza DJ, Dunand DC, Seidman DN (2018) Multicomponent \(\gamma \)-strengthened Co-based superalloys with increased solvus temperatures and reduced mass densities. Acta Mater. 147:284–295
Volz N, Zenk CH, Cherukuri R, Kalfhaus T, Weiser M, Makineni SK, Betzing C, Lenz M, Gault B, Fries SG, Schreuer J, Vaßen R, Virtanen S, Raabe D, Spiecker E, Neumeier S, Göken M (2018) Thermophysical and mechanical properties of advanced single crystalline Co-base superalloys. Metall. Mater. Trans. A 49(9):4099–4109
Kou S (2015) A criterion for cracking during solidification. Acta Mater. 88:366–374
Park J-W, Vitek JM, Babu SS, David SA (2004) Stray grain formation, thermomechanical stress and solidification cracking in single crystal nickel base superalloy welds. Sci. Technol. Weld. Joi. 9(6):472–482
Lee YS, Kirka MM, Kim S, Sridharan N, Okello A, Dehoff RR, Babu SS (2018) Asymmetric cracking in Mar-M247 alloy builds during electron beam powder bed fusion additive manufacturing. Metall. Mater. Trans. A 49(10):5065–5079
Acknowledgements
Funding for this research was provided by a DoD Vannevar Bush Faculty Fellowship, Grant ONR N00014-18-3031. In addition, tuition and stipend funding was provided to S.P.M. by a DoD National Defense Science and Engineering Graduate Fellowship. This research was sponsored by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office, under contract DE-AC05-00OR22725 with UT-Battelle, LLC, and performed in partiality at the Oak Ridge National Laboratory’s Manufacturing Demonstration Facility, an Office of Energy Efficiency and Renewable Energy user facility. Thanks are due to Dr. Brent Goodlet for technical assistance with the RUS measurements.
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Murray, S.P. et al. (2020). Microstructure and Tensile Properties of a CoNi-Based Superalloy Fabricated by Selective Electron Beam Melting. In: Tin, S., et al. Superalloys 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-51834-9_86
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DOI: https://doi.org/10.1007/978-3-030-51834-9_86
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