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Electrochemical Impedance Spectroscopy and Adsorption Study of Carbon Steel in 1 M HCl Solution Containing 2-(2-Methoxybenzylidene) Hydrazine-1-Carbothioamide

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Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition) (EMCEI 2019)

Part of the book series: Environmental Science and Engineering ((ENVSCIENCE))

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Abstract

In this study, the ability of 2-(2-methoxybenzylidene) hydrazine-1-carbothioamide to inhibit carbon steel corrosion in hydrochloric acid (1 M) was investigated by means of electrochemical impedance spectroscopy. The adsorption parameters of the inhibitor on the metal surface were studied using three isotherm models: Langmuir, Temkin, and Frumkin. The results show that the compound under study exhibits inhibitor properties and may reach an inhibition efficiency of 97.9% at 200 ppm. The adsorption of this compound was found to corroborate with the Langmuir adsorption isotherm, and the obtained value of the free energy (ΔG°ads) suggests a predominant chemisorption of the used Schiff base on the steel surface.

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Author information

Authors and Affiliations

  1. Laboratoire Matériaux et Systèmes Electroniques, University Mohamed El Bachir El Ibrahimi, 34030, Bordj Bou Arreridj, Algeria

    Hana Ferkous, Hamza Behloul & Khaoula Saoud

  2. Laboratoire de Physico-Chimie des Hauts Polymères (LPCHP), University Ferhat Abbas Setif 1, 19000, Setif, Algeria

    Souad Djellali

  3. Laboratoire de Valorisation des Ressources Biologiques Naturelles, University Ferhat Abbas Setif 1, 19000, Setif, Algeria

    Rachid Sahraoui

  4. Department of Chemistry, Faculty of Sciences, Firat University, Elazığ, Turkey

    Alaaddin Çukurovali

Authors
  1. Hana Ferkous
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  2. Souad Djellali
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  3. Rachid Sahraoui
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  4. Hamza Behloul
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  5. Khaoula Saoud
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  6. Alaaddin Çukurovali
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Corresponding author

Correspondence to Hana Ferkous .

Editor information

Editors and Affiliations

  1. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Mohamed Ksibi

  2. Appliquées et Technologies, Institut Supérieur des Sciences, Gabès, Tunisia

    Achraf Ghorbal

  3. University of Calabria, Rende, Cosenza, Italy

    Sudip Chakraborty

  4. School of Engineering (ISEP), Polytechnic of Porto, Porto, Portugal

    Helder I. Chaminé

  5. Università degli Studi di Roma, Roma, Roma, Italy

    Maurizio Barbieri

  6. University of Naples, Naples, Italy

    Giulia Guerriero

  7. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Olfa Hentati

  8. Faculty of Engineering, Water and Water Structure Engineering Department, Zagazig University, Zagazig, Egypt

    Abdelazim Negm

  9. University of Geneva, Genève, Geneve, Switzerland

    Anthony Lehmann

  10. ECT Oekotoxikologie GmbH, Flörsheim am Main, Hessen, Germany

    Jörg Römbke

  11. Centre for Environmental+Marine Studies, University of Aveiro, Aveiro, Portugal

    Armando Costa Duarte

  12. Department of Geography, Justus-Liebig-University Giessen, Gießen, Hessen, Germany

    Elena Xoplaki

  13. Springer Nature, Heidelberg, Baden-Württemberg, Germany

    Nabil Khélifi

  14. Gembloux Agro-Bio Tech, University of Liège, Gembloux, Belgium

    Gilles Colinet

  15. University of Aveiro, Aveiro, Portugal

    João Miguel Dias

  16. Faculty of Medicine of Sfax, University of Sfax, Sfax, Tunisia

    Imed Gargouri

  17. Institut de Physique du Globe de Paris, Université de Paris, Paris, France

    Eric D. Van Hullebusch

  18. FOTOAIR-CIEMAT, Madrid, Madrid, Spain

    Benigno Sánchez Cabrero

  19. Department of Civil Engineering, University of Salerno, Fisciano, Italy

    Settimio Ferlisi

  20. College of Engineering, Swansea University, Swansea, UK

    Chedly Tizaoui

  21. Sfax National School of Engineering, University of Sfax, Sfax, Tunisia

    Amjad Kallel

  22. Swiss Federal Institute of Technology, Lausanne, Switzerland

    Sami Rtimi

  23. Department of Mining Engineering, Suleyman Demirel University, Isparta, Turkey

    Sandeep Panda

  24. Université Clermont Auvergne, Polytech, Aubière, France

    Philippe Michaud

  25. Institute of Chemical Technology, University of Stuttgart, Stuttgart, Baden-Württemberg, Germany

    Jaya Narayana Sahu

  26. High School of Science and Technology, University of Sousse, Sousse, Tunisia

    Mongi Seffen

  27. SEED DICIV, University of Salerno, Fisciano, Italy

    Vincenzo Naddeo

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Ferkous, H., Djellali, S., Sahraoui, R., Behloul, H., Saoud, K., Çukurovali, A. (2021). Electrochemical Impedance Spectroscopy and Adsorption Study of Carbon Steel in 1 M HCl Solution Containing 2-(2-Methoxybenzylidene) Hydrazine-1-Carbothioamide. In: Ksibi, M., et al. Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition). EMCEI 2019. Environmental Science and Engineering(). Springer, Cham. https://doi.org/10.1007/978-3-030-51210-1_9

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