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Enhanced Cyclohexane Oxidation Activity and Selectivity on New Supported Transition Metal Catalysts Based on Co and Ag

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Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition) (EMCEI 2019)

Part of the book series: Environmental Science and Engineering ((ENVSCIENCE))

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Abstract

The oxidation of cyclohexane has been the topic of several investigations over recent years. The aim was to increase the selectivity in K/A oil (cyclohexanone/cyclohexanol). In this work, we proposed to study the cyclohexane oxidation reaction under mild conditions. Supported monometallic catalysts based on cobalt and silver as well as bimetallic catalysts were prepared by a simple method of impregnation on TiO2 and SiO2. These materials have been characterized by XRD, nitrogen adsorption and atomic absorption spectroscopy. The catalysts were tested in the oxidation of cyclohexane reaction with tert-butyl hydroperoxide in mild conditions and the products were analyzed by gas chromatography (GC). A very interesting result was reached: the reaction could be oriented toward the exclusive production of cyclohexanone from the beginning (15 min).

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References

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Author information

Authors and Affiliations

  1. Laboratory of Catalysis and Synthesis in Organic Chemistry, Tlemcen University, 13000, Tlemcen, Algeria

    Ritha Soulimane, Khaira Tafiani, Redouane Bachir & Sumeya Bedrane

  2. Higher School of Electrical and Energy Engineering of Oran, 31000, Oran, Algeria

    Nawel Ameur

Authors
  1. Ritha Soulimane
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  2. Khaira Tafiani
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  3. Nawel Ameur
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  4. Redouane Bachir
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  5. Sumeya Bedrane
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Corresponding author

Correspondence to Ritha Soulimane .

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Editors and Affiliations

  1. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Mohamed Ksibi

  2. Appliquées et Technologies, Institut Supérieur des Sciences, Gabès, Tunisia

    Achraf Ghorbal

  3. University of Calabria, Rende, Cosenza, Italy

    Sudip Chakraborty

  4. School of Engineering (ISEP), Polytechnic of Porto, Porto, Portugal

    Helder I. Chaminé

  5. Università degli Studi di Roma, Roma, Roma, Italy

    Maurizio Barbieri

  6. University of Naples, Naples, Italy

    Giulia Guerriero

  7. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Olfa Hentati

  8. Faculty of Engineering, Water and Water Structure Engineering Department, Zagazig University, Zagazig, Egypt

    Abdelazim Negm

  9. University of Geneva, Genève, Geneve, Switzerland

    Anthony Lehmann

  10. ECT Oekotoxikologie GmbH, Flörsheim am Main, Hessen, Germany

    Jörg Römbke

  11. Centre for Environmental+Marine Studies, University of Aveiro, Aveiro, Portugal

    Armando Costa Duarte

  12. Department of Geography, Justus-Liebig-University Giessen, Gießen, Hessen, Germany

    Elena Xoplaki

  13. Springer Nature, Heidelberg, Baden-Württemberg, Germany

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  14. Gembloux Agro-Bio Tech, University of Liège, Gembloux, Belgium

    Gilles Colinet

  15. University of Aveiro, Aveiro, Portugal

    João Miguel Dias

  16. Faculty of Medicine of Sfax, University of Sfax, Sfax, Tunisia

    Imed Gargouri

  17. Institut de Physique du Globe de Paris, Université de Paris, Paris, France

    Eric D. Van Hullebusch

  18. FOTOAIR-CIEMAT, Madrid, Madrid, Spain

    Benigno Sánchez Cabrero

  19. Department of Civil Engineering, University of Salerno, Fisciano, Italy

    Settimio Ferlisi

  20. College of Engineering, Swansea University, Swansea, UK

    Chedly Tizaoui

  21. Sfax National School of Engineering, University of Sfax, Sfax, Tunisia

    Amjad Kallel

  22. Swiss Federal Institute of Technology, Lausanne, Switzerland

    Sami Rtimi

  23. Department of Mining Engineering, Suleyman Demirel University, Isparta, Turkey

    Sandeep Panda

  24. Université Clermont Auvergne, Polytech, Aubière, France

    Philippe Michaud

  25. Institute of Chemical Technology, University of Stuttgart, Stuttgart, Baden-Württemberg, Germany

    Jaya Narayana Sahu

  26. High School of Science and Technology, University of Sousse, Sousse, Tunisia

    Mongi Seffen

  27. SEED DICIV, University of Salerno, Fisciano, Italy

    Vincenzo Naddeo

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Soulimane, R., Tafiani, K., Ameur, N., Bachir, R., Bedrane, S. (2021). Enhanced Cyclohexane Oxidation Activity and Selectivity on New Supported Transition Metal Catalysts Based on Co and Ag. In: Ksibi, M., et al. Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition). EMCEI 2019. Environmental Science and Engineering(). Springer, Cham. https://doi.org/10.1007/978-3-030-51210-1_67

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