Abstract
The demand for precious and rare earth elements is gradually increasing mainly due to the advancement in their various industrial applications. However, the mining industry is facing challenges of natural resource depletion and it is predicted that in the near future there will be no natural sources of these metals. Therefore, several studies have been conducted to recover precious and rare earth elements from secondary resources such as spent industrial catalysts, jewellery, magnets, automobile parts, and electronic and industrial effluents. For this reason, solvent extraction using ionic liquids has attracted a lot of attention. This is because ionic liquids have improved properties such as non-volatility, non-flammability and low toxicity (when compared with tradition organic solvents used in the recovery of precious metals and rare earth elements). In addition, ionic liquids can be used to separate, extract and recover ionic species without the aid of a ligand, thus rendering them as the best ion-exchange extractants. In this chapter, the application of ionic liquids for the extraction, dissolution and recovery of precious metals and rare earth elements from waste (secondary resources) is reviewed. Special attention is given to solvent extraction which has proven to be one of the most widely used methodologies for metal recovery. This is due to the attractive features such as simplicity, flexibility and rapidity. Application of deep eutectic solvents (known to be greener than traditional ionic liquids) has been discussed to tackle existing challenges of ionic liquids.
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Abbreviations
- Dca−:
-
Dicyanamide
- DES:
-
Deep eutectic solvents
- ILs:
-
Ionic liquids
- IUPAC:
-
International Union of Pure and Applied Chemistry
- NdFeB:
-
Neodymium magnet
- REEs:
-
Rare earth metals
- SCN−:
-
Thiocyanate
- Tf2N−:
-
Bis(trifluoromethylsulphonyl)imide
References
Abbott AP, Boothby D, Capper G, Davies DL, Rasheed RK (2004) Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. J Am Chem Soc 126:9142–9147
Abbott AP, Barron JC, Ryder KS, Wilson D (2007) Eutectic-based ionic liquids with metal-containing anions and cations. Chem Eur J 13:6495–6501
Avdibegović D, RegadÃo M, Binnemans K (2018) Efficient separation of rare earths recovered by a supported ionic liquid from bauxite residue leachate. RSC Adv 8:11886–11893
Bakkar A, Neubert V (2019) Recycling of cupola furnace dust: extraction and electrodeposition of zinc in deep eutectic solvents. J Alloys Compd 771:424–432
Banda R, Forte F, Onghena B, Binnemans K (2019) Yttrium and europium separation by solvent extraction with undiluted thiocyanate ionic liquids. RSC Adv 9:4876–4883
Binnemans K, Jones PT, Blanpain B, Van Gerven T, Yang Y, Walton A, Buchert M (2013) Recycling of rare earths: a critical review. J Clean Prod 51:1–22. https://doi.org/10.1016/j.jclepro.2012.12.037
Boudesocque S, Mohamadou A, Conreux A, Marin B, Dupont L (2019) The recovery and selective extraction of gold and platinum by novel ionic liquids. Sep Purif Technol 210:824–834. https://doi.org/10.1016/j.seppur.2018.09.002
Cardoso CED, Almeida JC, Lopes CB, Trindade T, Vale C, Pereira E (2019) Recovery of rare earth elements by carbon-based. Nanomaterials 9:814
Chen Y-L, Zhang X, You T-T, Xu F (2019) Deep eutectic solvents (DESs) for cellulose dissolution: a mini-review. Cellulose 26:205–213
Cieszynska A, Wieczorek D (2018) Extraction and separation of palladium(II), platinum(IV), gold(III) and rhodium(III) using piperidine-based extractants. Hydrometallurgy 175:359–366. https://doi.org/10.1016/j.hydromet.2017.12.019
Davris P, Balomenos E, Panias D, Paspaliaris I (2016) Selective leaching of rare earth elements from bauxite residue (red mud), using a functionalized hydrophobic ionic liquid. Hydrometallurgy 164:125–135
Davris P, Marinos D, Balomenos E, Alexandri A, Gregou M, Panias D, Paspaliaris I (2018) Leaching of rare earth elements from ‘Rödberg’ ore of fen carbonatite complex deposit, using the ionic liquid HbetTf2N. Hydrometallurgy 175:20–27. https://doi.org/10.1016/j.hydromet.2017.10.031
Devi N, Sukla LB (2019) Studies on liquid-liquid extraction of yttrium and separation from other rare earth elements using bifunctional ionic liquids. Miner Process Extr Metall Rev 40:46–55
Dupont D, Binnemans K (2015) Recycling of rare earths from NdFeB magnets using a combined leaching/extraction system based on the acidity and thermomorphism of the ionic liquid [Hbet][Tf 2 N]. Green Chem 17:2150–2163
Entezari-Zarandi A, Larachi F (2019) Selective dissolution of rare-earth element carbonates in deep eutectic solvents. J Rare Earths 37:528–533. https://doi.org/10.1016/j.jre.2018.07.015
Farzam S, Feyzi F (2019) Response surface methodology applied to extraction optimization of gold(III) by combination of imidazolium-based ionic liquid and 1-octanol from hydrochloric acid. Sep Sci Technol:1–13. https://doi.org/10.1080/01496395.2019.1581217
Geng Y, Xiang Z, Lv C, Wang N, Wang Y, Yang Y (2019) Recovery of gold from hydrochloric medium by deep eutectic solvents based on quaternary ammonium salts. Hydrometallurgy
Gore S, Baskaran S, Koenig B (2011) Efficient synthesis of 3,4-dihydropyrimidin-2-ones in low melting tartaric acid–urea mixtures. Green Chem 13:1009–1013
Jenkin GRT et al (2016) The application of deep eutectic solvent ionic liquids for environmentally-friendly dissolution and recovery of precious metals. Miner Eng 87:18–24. https://doi.org/10.1016/j.mineng.2015.09.026
Jorjani E, Shahbazi M (2016) The production of rare earth elements group via tributyl phosphate extraction and precipitation stripping using oxalic acid. Arab J Chem 9:S1532–S1539. https://doi.org/10.1016/j.arabjc.2012.04.002
Katsuta S, Watanabe Y, Araki Y, Kudo Y (2016) Extraction of gold(III) from hydrochloric acid into various ionic liquids: relationship between extraction efficiency and aqueous solubility of ionic liquids. ACS Sustain Chem Eng 4:564–571. https://doi.org/10.1021/acssuschemeng.5b00976
Kim S-H, Yang S-T, Kim J, Ahn W-S (2011) Sonochemical synthesis of Cu3 (BTC) 2 in a deep eutectic mixture of choline chloride/dimethylurea. Bull Kor Chem Soc 32:2783–2786
Kose Mutlu B, Cantoni B, Turolla A, Antonelli M, Hsu-Kim H, Wiesner MR (2018) Application of nanofiltration for rare earth elements recovery from coal fly ash leachate: performance and cost evaluation. Chem Eng J 349:309–317. https://doi.org/10.1016/j.cej.2018.05.080
Kubota F, Kono R, Yoshida W, Sharaf M, Kolev SD, Goto M (2019) Recovery of gold ions from discarded mobile phone leachate by solvent extraction and polymer inclusion membrane (PIM) based separation using an amic acid extractant. Sep Purif Technol 214:156–161. https://doi.org/10.1016/j.seppur.2018.04.031
Kumar ASK, Sharma S, Reddy RS, Barathi M, Rajesh N (2015) Comprehending the interaction between chitosan and ionic liquid for the adsorption of palladium. Int J Biol Macromol 72:633–639. https://doi.org/10.1016/j.ijbiomac.2014.09.002
Liu B, Zhu N, Li Y, Wu P, Dang Z, Ke Y (2019) Efficient recovery of rare earth elements from discarded NdFeB magnets. Process Saf Environ Prot 124:317–325. https://doi.org/10.1016/j.psep.2019.01.026
Makanyire T, Sanchez-Segado S, Jha A (2016) Separation and recovery of critical metal ions using ionic liquids. Adv Manufact 4:33–46. https://doi.org/10.1007/s40436-015-0132-3
Mamilla JL, Novak U, Grilc M, Likozar B (2019) Natural deep eutectic solvents (DES) for fractionation of waste lignocellulosic biomass and its cascade conversion to value-added bio-based chemicals. Biomass Bioenergy 120:417–425
Marset X, Torregrosa-Crespo J, MartÃnez-Espinosa RM, Guillena G, Ramón DJ (2019) Multicomponent synthesis of sulfonamides from triarylbismuthines, nitro compounds and sodium metabisulfite in deep eutectic solvents green chemistry
Masilela M, Ndlovu S (2019) Extraction of Ag and au from chloride electronic waste leach solutions using ionic liquids. J Environ Chem Eng 7:102810. https://doi.org/10.1016/j.jece.2018.11.054
Nguyen VT, Lee J-c, Jeong J, Kim B-S, Gr C, Chagnes A (2015) Extraction of gold (III) from acidic chloride media using phosphonium-based ionic liquid as an anion exchanger. Ind Eng Chem Res 54:1350–1358
Papaiconomou N, Svecova L, Bonnaud C, Cathelin L, Billard I, Chainet E (2015) Possibilities and limitations in separating Pt (IV) from Pd (II) combining imidazolium and phosphonium ionic liquids. Dalton Trans 44:20131–20138
Pavón S, Fortuny A, Coll MT, Sastre AM (2018) Rare earths separation from fluorescent lamp wastes using ionic liquids as extractant agents. Waste Manag 82:241–248. https://doi.org/10.1016/j.wasman.2018.10.027
Perez JPH, Folens K, Leus K, Vanhaecke F, Van Der Voort P, Du Laing G (2019) Progress in hydrometallurgical technologies to recover critical raw materials and precious metals from low-concentrated streams. Resour Conserv Recycl 142:177–188. https://doi.org/10.1016/j.resconrec.2018.11.029
Riaño S et al (2017) Separation of rare earths and other valuable metals from deep-eutectic solvents: a new alternative for the recycling of used NdFeB magnets. RSC Adv 7:32100–32113
Roda A, Matias AA, Paiva A, Duarte ARC (2019) Polymer science and engineering using deep eutectic solvents. Polymers 11:912
Rodriguez Rodriguez N, Machiels L, Binnemans K (2019) p-Toluenesulfonic acid-based deep-eutectic solvents for solubilizing metal oxides. ACS Sustain Chem Eng 7:3940–3948
Roosen J, Van Roosendael S, Borra CR, Van Gerven T, Mullens S, Binnemans K (2016) Recovery of scandium from leachates of Greek bauxite residue by adsorption on functionalized chitosan–silica hybrid materials. Green Chem 18:2005–2013. https://doi.org/10.1039/c5gc02225h
Rzelewska-Piekut M, Regel-Rosocka M (2019) Separation of Pt(IV), Pd(II), Ru(III) and Rh(III) from model chloride solutions by liquid-liquid extraction with phosphonium ionic liquids. Sep Purif Technol 212:791–801. https://doi.org/10.1016/j.seppur.2018.11.091
Sánchez-Leija R et al (2019) Deep eutectic solvents as active media for the preparation of highly conducting 3D free-standing PANI xerogels and their derived N-doped and N, P-codoped porous carbons. Carbon 146:813–826
Serpe A (2018) 11 - green chemistry for precious metals recovery from WEEE∗∗ This chapter is dedicated to Prof. Paola Deplano on the occasion of her retirement. In: Vegliò F, Birloaga I (eds) Waste electrical and electronic equipment recycling. Woodhead Publishing, Sawston, pp 271–332. https://doi.org/10.1016/B978-0-08-102057-9.00011-1
Shahbaz K, Mjalli FS, Hashim M, Al Nashef IM (2010) Using deep eutectic solvents for the removal of glycerol from palm oil-based biodiesel. J Appl Sci 10:3349–3354
Shahbaz K, Mjalli F, Hashim M, AlNashef I (2011) Using deep eutectic solvents based on methyl triphenyl phosphunium bromide for the removal of glycerol from palm-oil-based biodiesel. Energy Fuel 25:2671–2678
Shahbaz K, Baroutian S, Mjalli F, Hashim M, AlNashef I (2012) Densities of ammonium and phosphonium based deep eutectic solvents: prediction using artificial intelligence and group contribution techniques. Thermochim Acta 527:59–66
Sharma S, Rajesh N (2016) Synergistic influence of graphene oxide and tetraoctylammonium bromide (frozen ionic liquid) for the enhanced adsorption and recovery of palladium from an industrial catalyst. J Environ Chem Eng 4:4287–4298. https://doi.org/10.1016/j.jece.2016.09.028
Singh BS, Lobo HR, Pinjari DV, Jarag KJ, Pandit AB, Shankarling GS (2013) Ultrasound and deep eutectic solvent (DES): a novel blend of techniques for rapid and energy efficient synthesis of oxazoles. Ultrason Sonochem 20:287–293
Su X, Guo X, Zhao Z, Dong Y, Wang Y, Li F, Sun X (2018) An efficient and sustainable [P6,6,6,14]2[BDOAC] ionic liquid based extraction–precipitation strategy for rare earth recovery. Chem Eng Res Des 136:786–794. https://doi.org/10.1016/j.cherd.2018.06.029
Swain N, Mishra S (2019) A review on the recovery and separation of rare earths and transition metals from secondary resources. J Clean Prod 220:884–898. https://doi.org/10.1016/j.jclepro.2019.02.094
Tian GC, Li J, Y-x H (2010) Application of ionic liquids in hydrometallurgy of nonferrous metals. Trans Nonferrous Metals Soc China 20:513–520. https://doi.org/10.1016/S1003-6326(09)60171-0
Tran MK, Rodrigues M-TF, Kato K, Babu G, Ajayan PM (2019) Deep eutectic solvents for cathode recycling of Li-ion batteries. Nat Energy 4:339
Tunsu C, Petranikova M, Ekberg C, Retegan T (2016) A hydrometallurgical process for the recovery of rare earth elements from fluorescent lamp waste fractions. Sep Purif Technol 161:172–186. https://doi.org/10.1016/j.seppur.2016.01.048
Van Roosendael S, RegadÃo M, Roosen J, Binnemans K (2019) Selective recovery of indium from iron-rich solutions using an Aliquat 336 iodide supported ionic liquid phase (SILP). Sep Purif Technol 212:843–853. https://doi.org/10.1016/j.seppur.2018.11.092
Vasilyev DV, Rudnev AV, Broekmann P, Dyson PJ (2019) A general and facile approach for the electrochemical reduction of carbon dioxide inspired by deep eutectic solvents. ChemSusChem 12:1635–1639
Wang K et al (2017a) Recovery of rare earth elements with ionic liquids. Green Chem 19:4469–4493. https://doi.org/10.1039/c7gc02141k
Wang M, Tan Q, Chiang JF, Li J (2017b) Recovery of rare and precious metals from urban mines—a review. Front Environ Sci Eng 11:1. https://doi.org/10.1007/s11783-017-0963-1
Wang N, Wang Q, Lu W, Ru M, Yang Y (2019) Extraction and stripping of platinum (IV) from acidic chloride media using guanidinium ionic liquid. J Mol Liq:111040. https://doi.org/10.1016/j.molliq.2019.111040
Wei W, Cho C-W, Kim S, Song M-H, Bediako JK, Yun Y-S (2016a) Selective recovery of au(III), Pt(IV), and Pd(II) from aqueous solutions by liquid–liquid extraction using ionic liquid Aliquat-336. J Mol Liq 216:18–24. https://doi.org/10.1016/j.molliq.2016.01.016
Wei W, Reddy DHK, Bediako JK, Yun Y-S (2016b) Aliquat-336-impregnated alginate capsule as a green sorbent for selective recovery of gold from metal mixtures. Chem Eng J 289:413–422. https://doi.org/10.1016/j.cej.2015.12.104
Xie F, Zhang TA, Dreisinger D, Doyle F (2014) A critical review on solvent extraction of rare earths from aqueous solutions. Miner Eng 56:10–28. https://doi.org/10.1016/j.mineng.2013.10.021
Xing WD, Lee MS (2019) A process for the separation of noble metals from HCl liquor containing gold (III), palladium (II), platinum (IV), rhodium (III), and iridium (IV) by solvent extraction. PRO 7:243
Xu K, Wang Y, Huang Y, Li N, Wen Q (2015) A green deep eutectic solvent-based aqueous two-phase system for protein extracting. Anal Chim Acta 864:9–20
Yang D, Ma P, Hou Z, Cheng Z, Li C, Lin J (2015) Current advances in lanthanide ion (Ln3+)-based upconversion nanomaterials for drug delivery. Chem Soc Rev 44:1416–1448. https://doi.org/10.1039/c4cs00155a
Zhao C, Ren J, Qu X (2013) G-quadruplexes form ultrastable parallel structures in deep eutectic solvent. Langmuir 29:1183–1191
Zhao H, Xu J, Sheng Q, Zheng J, Cao W, Yue T (2019) NiCo2O4 nanorods decorated MoS2 nanosheets synthesized from deep eutectic solvents and their application for electrochemical sensing of glucose in red wine and honey. J Electrochem Soc 166:H404–H411
Zhou H, Wang Y, Guo X, Dong Y, Su X, Sun X (2018) The recovery of rare earth by a novel extraction and precipitation strategy using functional ionic liquids. J Mol Liq 254:414–420. https://doi.org/10.1016/j.molliq.2018.01.078
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This study was supported by the University of Johannesburg, South Africa (Department of Chemical Sciences), and National Research Foundation (grant nos. 99720; 91230), South Africa.
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Nomngongo, P.N., Biata, N.R., Sihlahla, M., Mpupa, A., Mketo, N. (2020). Recent Advances in the Application of Greener Solvents for Extraction, Recovery and Dissolution of Precious Metals and Rare Earth Elements from Different Matrices. In: Inamuddin, Asiri, A. (eds) Nanotechnology-Based Industrial Applications of Ionic Liquids. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-44995-7_14
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