Modifications on Polymeric Membranes for Isopropanol Dehydration Using Pervaporation: A Review

Jusoh, Wan Zulaisa Amira Wan; Rahman, Sunarti Abdul; Ahmad, Abdul Latif; Mokhtar, Nadzirah Mohd

doi:10.1007/978-3-030-44176-0_5

Part of the book series: Nanotechnology in the Life Sciences ((NALIS))

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Abstract

Isopropanol (IPA) is a product of indirect hydrogenation, which is known as the fermentation of cellulosic material. IPA is widely used in modern semiconductor and microelectronic industries as a solvent and cleaning substance which generates isopropanol waste in the processes. Not only IPA waste is harmful to landfill but also requires a high management and treatment cost. Therefore, recycling IPA is extremely important from both economic and environmental perspectives. Separating IPA using pervaporation (PV) is known for its simplicity, low cost, easy handling and effectiveness. However, the limitations of common PV membranes such as swelling and weak mechanical strength have urged researchers to overcome the issue by using various polymeric materials and modification techniques. The alterations are commonly applied during membrane preparation, modifications on the membrane surface, and even post-modifications. This chapter reviews the development of modified PV membranes specifically to treat the IPA in the previous years and give a future trend in modification techniques.

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Abbreviations

A:: The effective surface area of the membrane (m²)
CB:: Carbon black
EDA:: Ethylenediamine
F:: Mass fraction of the species at the feed
GA:: Glutaraldehyde
GFT:: Gesellschaft für trenntechnik
GOTMS:: 3-Glycidyloxypropyltrimethoxysilane
GTMAC:: Glycidyl trimethyl ammonium chloride
HDA:: 1,6-Hexanediamine
HEC-g-AAm:: Hydroxyethyl cellulose grafting with acrylamide
HPEI:: Hyperbranched polyethyleneimine
HTPB:: Hydroxyl-terminated polybutadiene
IP:: Interfacial polymerization
IPA:: Isopropanol
IPAC:: Isopropyl acetone
J:: The flux of the mass transfer
mPAN:: Polyacrylonitrile
MPD:: M-Phenylenediamine
MPDA:: M-Phenylenediamine
MPDASA:: 1,3-Phenylenediamine-4-sulfonic acid
NaAlg:: Sodium alginate
NaSS:: Sodium 4-styrenesulfonate
P:: Mass fraction of the species at the permeate
P84:: Co-polyimide
PAI:: Polyamide-imide
PAN:: Polyacrylonitrile
PDA:: 1,3-Propanediamine
PDMS:: Polydimethylsiloxane
PE:: Polyethylene
PEBA:: Polyether-block-polyamide
PEI:: Polyetherimide
PIP:: Piperazine
PP:: Polypropylene
PS:: Polysulfone
PTFE:: Polytetrafluoroethylene
PU:: Polyurethane urea
PV:: Pervaporation
PVA:: Poly(vinyl alcohol)
PVDF:: Poly(vinylidene fluoride)
PVME:: Poly(vinyl methyl ether)
SA:: Sodium alginate
SPVA:: Sulfonated-poly(vinyl alcohol)
t:: The experiment time (h)
TETA:: Triethylenetetramine
TFC:: Thin-film composite
TMC:: Trimesoyl chloride
W:: Mass of the permeate (kg)
α:: Selectivity

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Acknowledgements

The authors would like to thank the sponsor for the financial support for this research through grants, RDU1803113 (UMP Grant).

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Authors and Affiliations

Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, Kuantan, Pahang, Malaysia
Wan Zulaisa Amira Wan Jusoh & Sunarti Abdul Rahman
Pusat Pengajian Kejuruteraan Kimia, Kampus Kejuruteraan, Universiti Sains Malaysia, Universiti Sains Malaysia Pulau Pinang, Gelugor, Pulau Pinang, Malaysia
Abdul Latif Ahmad
Faculty of Engineering Technology, Universiti Malaysia Pahang, Kuantan, Pahang, Malaysia
Nadzirah Mohd Mokhtar

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Wan Zulaisa Amira Wan Jusoh
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Sunarti Abdul Rahman
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Abdul Latif Ahmad
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Nadzirah Mohd Mokhtar
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Correspondence to Sunarti Abdul Rahman .

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Editors and Affiliations

Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia, Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India
Inamuddin
Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia
Abdullah M. Asiri

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Jusoh, W.Z.A.W., Rahman, S.A., Ahmad, A.L., Mokhtar, N.M. (2020). Modifications on Polymeric Membranes for Isopropanol Dehydration Using Pervaporation: A Review. In: Inamuddin, Asiri, A. (eds) Applications of Nanotechnology for Green Synthesis. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-44176-0_5

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DOI: https://doi.org/10.1007/978-3-030-44176-0_5
Published: 03 July 2020
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-44175-3
Online ISBN: 978-3-030-44176-0
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