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Characterization of Wood Chemical Changes Caused by Pyrolysis During Flaming Combustion Using X-Ray Photoelectron Spectroscopy

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Abstract

As heat is applied to wood, thermal degradation, called pyrolysis, occurs. A majority of what is known about the pyrolysis of wood has been obtained using either extracted component polymers or wood pyrolyzed in an inert atmosphere. However, the physical and chemical reactions that occur during pyrolysis of wood are affected by the interaction of the polymers in whole wood as well as the oxygen present in the atmosphere. X-ray photoelectron spectroscopy (XPS) is a surface measurement technique that yields information on both the chemical composition of the sample and the chemical bonds among the elements and compounds that comprise it. Here, XPS was used as a tool to examine the number and type of carbon bonds in Douglas fir exposed to flaming combustion.

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References

  1. White RH (2016) Analytical methods for determining fire resistance of timber members. In: SFPE handbook of fire protection engineering. Springer, pp 1979–2011

    Google Scholar 

  2. Schmid J, Just A, Klippel M, Fragiacomo M (2015) The reduced cross-section method for evaluation of the fire resistance of timber members: discussion and determination of the zero-strength layer. Fire Technol 51:1285–1309

    Article  Google Scholar 

  3. Zelinka SL, Hasburgh LE, Bourne KJ, Tucholski DR, Ouellette JP, Kochkin V, Hudson E, Ross RJ, Martinson KL, Lebow ST (2018) Compartment fire testing of a two-story mass timber building. Energy Technol 5:1179–1185

    Google Scholar 

  4. Hill CA (2007) Thermal modification of wood. In: Hill CA (ed) Wood modification: chemical, thermal and other processes. Wiley, West Sussex, UK, pp 99–126

    Google Scholar 

  5. Shafizadeh F, Chin PP (1977) Thermal deterioration of wood. Wood Technol: Chem Aspects 43:57–81

    Google Scholar 

  6. Nzokou P, Pascal Kamdem D (2005) X-ray photoelectron spectroscopy study of red oak-(Quercus rubra), black cherry-(Prunus serotina) and red pine-(Pinus resinosa) extracted wood surfaces. Surf Interf Anal 37:689–694

    Article  Google Scholar 

  7. Inari GN, Petrissans M, Lambert J, Ehrhardt J, Gérardin P (2006) XPS characterization of wood chemical composition after heat-treatment. Surf Interf Anal 38:1336–1342

    Article  Google Scholar 

  8. Bañuls-Ciscar J, Abel M-L, Watts JF (2016) Characterisation of cellulose and hardwood organosolv lignin reference materials by XPS. Surf Sci Spectra 23:1–8

    Article  Google Scholar 

  9. Hua X, Kaliaguine S, Kokta B, Adnot A (1993) Surface analysis of explosion pulps by ESCA Part 2. Oxygen (1s) and sulfur (2p) spectra. Wood Sci Technol 28:449–459

    Article  Google Scholar 

  10. Plaza N (2019) Automated Peak Fitting Routine for XPS Data from Wood (Version from March 2019). http://doi.org/10.2019/xps.wood

  11. Newville M, Stensitzki T, Allen DB, Rawlik M, Ingargiola A, Nelson A (2016) LMFIT: Non-linear least-square minimization and curve-fitting for Python. Astrophysics Source Code Library

    Google Scholar 

  12. Herrera-Gomez A (2011) The peak-Shirley background. Internal Report. Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN)

    Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge use of facilities and instrumentation supported by NSF through the University of Wisconsin Materials Research Science and Engineering Center (DMR-1720415).

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Correspondence to Laura E. Hasburgh .

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Hasburgh, L.E., Stone, D.S., Zelinka, S.L., Plaza, N.Z. (2020). Characterization of Wood Chemical Changes Caused by Pyrolysis During Flaming Combustion Using X-Ray Photoelectron Spectroscopy. In: Makovicka Osvaldova, L., Markert, F., Zelinka, S. (eds) Wood & Fire Safety. WFS 2020. Springer, Cham. https://doi.org/10.1007/978-3-030-41235-7_4

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  • DOI: https://doi.org/10.1007/978-3-030-41235-7_4

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-41234-0

  • Online ISBN: 978-3-030-41235-7

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