Skip to main content

Indian Coal Ash: A Potential Alternative Resource for Rare Earth Metals (REMs)

  • Conference paper
  • First Online:
Rare Metal Technology 2020

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

  • 1681 Accesses

Abstract

Huge scarcity of rare earth metals (REMs) globally, lack of good natural resources, and generation of tremendous coal ash containing REMs of power plant attracted the researchers to work in this area. The analysis of geologically distributed heterogeneous coal samples at CSIR-NML, India reports the presence of 0.5–1.5 kg/Ton REMs in particular seam of coal at Indian eastern part. In this regard, systematic leaching studies were made to recover REMs from Indian coal ash using hydrometallurgical technique. Maximum dissolution of REMs from coal ash take place using HCl of concentration ranging between 2 and 6 M at elevated temperature. From the obtained leach liquor, more than 90% REMs were recovered using oxalate precipitation . The process developed has tremendous potential to be commercialized after feasibility studies.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (Canada)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (Canada)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (Canada)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (Canada)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Kim JS, Lee CH, Han SH, Suh MY (1997) Studies on complexation and solvent extraction of lanthanide in the presence of diaza-18-crown-6-di-isopropionicacid. Talanta 45:437–444. https://doi.org/10.1016/s0039-9140(97)00151-3

    Article  CAS  Google Scholar 

  2. Blissett RS, Smalley N, Rowson NA (2014) An investigation into six coal fly ashes from the united kingdom and Poland to evaluate rare earth elements content. Fuel 119:236–239. https://doi.org/10.1016/j.fuel.2013.11.053

    Article  CAS  Google Scholar 

  3. Franus W, Wiatros-Motyka MM, Wdowin M (2015) Coal fly ash as a resource for rare earth elements. Environ Sci Pollut Res 22:9464–9474. https://doi.org/10.1007/s11356-015-4111-9

    Article  CAS  Google Scholar 

  4. Thompson RL, Bank T, Montross S, Roth E, Howard B, Verba C, Granite E, (2018) Analysis of rare earth elements in coal fly ash using laser ablation inductively coupled plasma mass spectrometry and scanning electron microscopy. Spectrochim Acta B 143:1–11. https://doi.org/10.1016/j.sab.2018.02.009

    Article  CAS  Google Scholar 

  5. Kolker A, Scott C, Hower JC, Vazquez JA, Lopano CL, Shifeng D, (2017) Distribution of rare earth elements in coal combustion fly ash, determined by SHRIMP-RG ion microprobe. Int J Coal Geol 184:1–10. https://doi.org/10.1016/j.coal.2017

  6. Phuoc TX, Wang P, McIntyre D (2016) Detection of rare earth elements in powder river basin sub-bituminous coal ash using laser-induced breakdown spectroscopy (LIBS). Fuel 163:129–132. https://doi.org/10.1016/j.fuel.2015.09.034

    Article  CAS  Google Scholar 

  7. Banerjee A, Mishra PR, Mohanty A, Chakravarty K, Biswas RD, Sahu R, Chakravarty S (2016) Distribution of mineral species in different coal seams of Talcher coalfield and its transformation behavior at varying temperatures. Int J Coal Sci Technol 3(2):97–103. https://doi.org/10.1007/s40789-016-0127-0

    Article  CAS  Google Scholar 

  8. Mishra V, Sharma M, Chakravarty S, Banerjee A (2016) Changes in organic structure and mineral phases transformation of coal during heat treatment on laboratory scale. Int J Coal Sci Technol 3(4):418–428. https://doi.org/10.1007/s40789-016-0153-y

    Article  CAS  Google Scholar 

  9. Seredin V, Finkelman RB (2008) Metalliferous coals: a review of the main genetic and geochemical types. Int J Coal Geol 76:253–289. https://doi.org/10.1016/j.coal.2008.07.016

    Article  CAS  Google Scholar 

  10. Vassilev SV, Vassileva CG (1997) Geochemistry of coals, coal ashes and combustion wastes from coal fired power stations. Fuel Process Technol 51(1–2):19–45. https://doi.org/10.1016/s0378-3820(96)01082-x

    Article  CAS  Google Scholar 

  11. Wang Y, Tang Y, Liu S, Wang Y, Finkelman RB, Wang B, Guo X (2018) Behavior of trace elements and mineral transformations in the super-high organic sulfur Ganhe coal during gasification. Fuel Process Technol 177:140–151. https://doi.org/10.1016/j.fuproc.2018.04.01

  12. Lin R, Howard BH, Roth EA, Bank TL, Granite EJ, Soong Y (2017) Enrichment of rare earth elements from coal and coal by-products by physical separation. Fuel 200:506–520. https://doi.org/10.1016/j.fuel.2017.03.096

    Article  CAS  Google Scholar 

  13. Peterson R, Heinrichs M, Glier J, Lane A, Taha R (2017) Recovery of rare earth elements from coal ash with a recycling acid leach process. In: Proceedings of the World of Coal Ash Conference, Lexington

    Google Scholar 

  14. Taggart R (2015) Recovering rare earth metals from coal fly ash. In: Proceedings of the World of Coal Ash Conference, Lexington

    Google Scholar 

  15. Kumari A, Parween R, Chakravarty S, Parmar K, Pathak DD, Lee JC, Jha MK (2019) Novel approach to recover rare earth metals (REMs) from Indian coal bottom ash. Hydrometallurgy 187:1–7. https://doi.org/10.1016/j.hydromet.2019.04.024

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Present paper is based on the research work related to REMs extraction from Indian coal ash carried out at CSIR-National Metallurgical Laboratory (CSIR-NML), Jamshedpur, India. Authors are thankful to the Director, CSIR-NML for the permission to publish this paper. One of the authors, Ms. Archana Kumari would like to extend her sincere gratitude to CSIR, New Delhi (Grant: 31/10(60)/2015-EMR-I) for providing Senior Research Fellowship to carry out this research work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Manis Kumar Jha .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Kumari, A., Jha, M.K., Chakravarty, S., Pathak, D.D. (2020). Indian Coal Ash: A Potential Alternative Resource for Rare Earth Metals (REMs). In: Azimi, G., Forsberg, K., Ouchi, T., Kim, H., Alam, S., Baba, A. (eds) Rare Metal Technology 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36758-9_25

Download citation

Publish with us

Policies and ethics