Abstract
Huge scarcity of rare earth metals (REMs) globally, lack of good natural resources, and generation of tremendous coal ash containing REMs of power plant attracted the researchers to work in this area. The analysis of geologically distributed heterogeneous coal samples at CSIR-NML, India reports the presence of 0.5–1.5 kg/Ton REMs in particular seam of coal at Indian eastern part. In this regard, systematic leaching studies were made to recover REMs from Indian coal ash using hydrometallurgical technique. Maximum dissolution of REMs from coal ash take place using HCl of concentration ranging between 2 and 6 M at elevated temperature. From the obtained leach liquor, more than 90% REMs were recovered using oxalate precipitation . The process developed has tremendous potential to be commercialized after feasibility studies.
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References
Kim JS, Lee CH, Han SH, Suh MY (1997) Studies on complexation and solvent extraction of lanthanide in the presence of diaza-18-crown-6-di-isopropionicacid. Talanta 45:437–444. https://doi.org/10.1016/s0039-9140(97)00151-3
Blissett RS, Smalley N, Rowson NA (2014) An investigation into six coal fly ashes from the united kingdom and Poland to evaluate rare earth elements content. Fuel 119:236–239. https://doi.org/10.1016/j.fuel.2013.11.053
Franus W, Wiatros-Motyka MM, Wdowin M (2015) Coal fly ash as a resource for rare earth elements. Environ Sci Pollut Res 22:9464–9474. https://doi.org/10.1007/s11356-015-4111-9
Thompson RL, Bank T, Montross S, Roth E, Howard B, Verba C, Granite E, (2018) Analysis of rare earth elements in coal fly ash using laser ablation inductively coupled plasma mass spectrometry and scanning electron microscopy. Spectrochim Acta B 143:1–11. https://doi.org/10.1016/j.sab.2018.02.009
Kolker A, Scott C, Hower JC, Vazquez JA, Lopano CL, Shifeng D, (2017) Distribution of rare earth elements in coal combustion fly ash, determined by SHRIMP-RG ion microprobe. Int J Coal Geol 184:1–10. https://doi.org/10.1016/j.coal.2017
Phuoc TX, Wang P, McIntyre D (2016) Detection of rare earth elements in powder river basin sub-bituminous coal ash using laser-induced breakdown spectroscopy (LIBS). Fuel 163:129–132. https://doi.org/10.1016/j.fuel.2015.09.034
Banerjee A, Mishra PR, Mohanty A, Chakravarty K, Biswas RD, Sahu R, Chakravarty S (2016) Distribution of mineral species in different coal seams of Talcher coalfield and its transformation behavior at varying temperatures. Int J Coal Sci Technol 3(2):97–103. https://doi.org/10.1007/s40789-016-0127-0
Mishra V, Sharma M, Chakravarty S, Banerjee A (2016) Changes in organic structure and mineral phases transformation of coal during heat treatment on laboratory scale. Int J Coal Sci Technol 3(4):418–428. https://doi.org/10.1007/s40789-016-0153-y
Seredin V, Finkelman RB (2008) Metalliferous coals: a review of the main genetic and geochemical types. Int J Coal Geol 76:253–289. https://doi.org/10.1016/j.coal.2008.07.016
Vassilev SV, Vassileva CG (1997) Geochemistry of coals, coal ashes and combustion wastes from coal fired power stations. Fuel Process Technol 51(1–2):19–45. https://doi.org/10.1016/s0378-3820(96)01082-x
Wang Y, Tang Y, Liu S, Wang Y, Finkelman RB, Wang B, Guo X (2018) Behavior of trace elements and mineral transformations in the super-high organic sulfur Ganhe coal during gasification. Fuel Process Technol 177:140–151. https://doi.org/10.1016/j.fuproc.2018.04.01
Lin R, Howard BH, Roth EA, Bank TL, Granite EJ, Soong Y (2017) Enrichment of rare earth elements from coal and coal by-products by physical separation. Fuel 200:506–520. https://doi.org/10.1016/j.fuel.2017.03.096
Peterson R, Heinrichs M, Glier J, Lane A, Taha R (2017) Recovery of rare earth elements from coal ash with a recycling acid leach process. In: Proceedings of the World of Coal Ash Conference, Lexington
Taggart R (2015) Recovering rare earth metals from coal fly ash. In: Proceedings of the World of Coal Ash Conference, Lexington
Kumari A, Parween R, Chakravarty S, Parmar K, Pathak DD, Lee JC, Jha MK (2019) Novel approach to recover rare earth metals (REMs) from Indian coal bottom ash. Hydrometallurgy 187:1–7. https://doi.org/10.1016/j.hydromet.2019.04.024
Acknowledgements
Present paper is based on the research work related to REMs extraction from Indian coal ash carried out at CSIR-National Metallurgical Laboratory (CSIR-NML), Jamshedpur, India. Authors are thankful to the Director, CSIR-NML for the permission to publish this paper. One of the authors, Ms. Archana Kumari would like to extend her sincere gratitude to CSIR, New Delhi (Grant: 31/10(60)/2015-EMR-I) for providing Senior Research Fellowship to carry out this research work.
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Kumari, A., Jha, M.K., Chakravarty, S., Pathak, D.D. (2020). Indian Coal Ash: A Potential Alternative Resource for Rare Earth Metals (REMs). In: Azimi, G., Forsberg, K., Ouchi, T., Kim, H., Alam, S., Baba, A. (eds) Rare Metal Technology 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36758-9_25
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