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History of Inventions and Innovations for Aluminum Production

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TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

Industrial production of aluminum started in 1856 with the chemical method developed by Sainte-Claire Deville. In 1886, Charles Hall and Paul Héroult invented the electrolytic reduction of alumina with carbon, which quickly became the only industrial method used to produce aluminum until today. Even though the Hall-Héroult process remained the same, the production technology changed tremendously since the beginning, to reduce the production cost and specific energy consumption, increase productivity, and improve environment. In this paper, the most notable inventions and innovations for improvement of the Hall-Héroult process in the last 100 years will be described as well as efforts to break away from this process, which all have been unsuccessful so far. These include direct reduction of alumina with carbon and the aluminum chloride process. Within the electrolysis process, until now unsuccessful research to use non-consumable anodes and wettable cathodes for large-scale production will also be described.

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References

  1. Deville HS-C (1859) De l’aluminium. Ses propriétés, sa fabrication et ses applications (About aluminium. Its properties, its production and its applications). Mallet-Brachelier, Paris

    Google Scholar 

  2. Drozdov A (2007) 13 Al thirteenth element Encyclopedia. The RUSAL Library, Moscow

    Google Scholar 

  3. https://www.aluminiumleader.com/history/industry_history/. Retrieved on 24 Sept 2019

  4. Héroult PL-T (1886) French patent 175,711, filed on 23 Apr 1886 and granted on 1 Sept 1886 (quotation taken from reference [3])

    Google Scholar 

  5. Hall CM (1889) Process of reducing aluminum by electrolysis. US patent 400766, filed on 9 July 1886, granted on Apr 1889

    Google Scholar 

  6. Bayer KJ (1888), Process of obtaining alumina. US patent 382505, filed on 18 Aug 1887, granted on 8 May 1888

    Google Scholar 

  7. Söderberg KW (1919) Electrode for electric furnaces and process for manufacturing the same. US patent 1440724, filed on 8 Sept 1919

    Google Scholar 

  8. Barber M, Tabereaux AT (2014) The evolution of Søderberg Aluminum Cell Technology in North and South America. JOM 66(2):223–234

    Article  CAS  Google Scholar 

  9. Mann V et al (2019) Environmental aspects of UC RUSAL’s aluminum smelters sustainable development. In: Proceedings of 36th international ICSOBA conference, Belem, Brazil, 29 Oct–1 Nov 2019, Paper AL14, Travaux 47, pp 745–755

    Google Scholar 

  10. McMahon TK, Dirth GP (1966) Computer control of aluminum reduction cells. JOM 18(3):317–319

    Google Scholar 

  11. Reverdy M, Alzarooni A (2018) Emirates global aluminium state-of-the-art advanced pot control system—simple and flexible. Int Aluminium J 1–2:32, 34

    Google Scholar 

  12. Lowe RL (1972) Alumina feeder. US patent 3681229, filed on 17 July 1970, granted on 1 Aug 1972

    Google Scholar 

  13. Bonny P et al (1984) Process and apparatus for accurately controlling the rate of introduction and the content of alumina in an igneous electrolysis tank in the production of aluminum. US patent 4431491, filed on 20 July 1981, granted on 14 Feb 1984

    Google Scholar 

  14. Tarcy GP, Kvande H, Tabereaux A (2011) Advancing the industrial aluminum process: 20th century breakthrough inventions and developments. JOM 63(8):101–108

    Article  Google Scholar 

  15. Tabereaux A (2007) Principles of point feeders and alumina control. TMS course before TMS annual meeting, 25–27 Feb 2007, Orlando, Florida

    Google Scholar 

  16. Vanvoren C, Homsi P, Fève B, Molinier B, di Giovanni Y (2001) AP35: the latest high performance industrially available new cell technology. In: Light metals, pp 207–212

    Google Scholar 

  17. Potocnik V (1986) A-275 MHD design. In: Light metals, pp 203–208

    Google Scholar 

  18. Vanvoren C, Homsi P, Basquin JL, Beheregaray T (2001) AP50: the Pechiney 500 kA cell. In: Light metals, pp 221–226

    Google Scholar 

  19. Akmetov SI et al (2007) Rapid development & implementation of high amperage technology. In: 9th Australasian smelter technology conference and workshop, Terrigal, Australia, 4–9 Nov 2007

    Google Scholar 

  20. Mann V et al (2018) RA-550 cell technology: UC RUSAL’s new stage of technology development. In: Light metals, pp 715–719

    Google Scholar 

  21. Zarouni A et al (2013) Mathematical model validation of aluminium electrolysis cells at DUBAL. In: Light metals, pp 597–602

    Google Scholar 

  22. Reverdy M et al (2016) The successful implementation of DUBAL DX+ Technology at EMAL. In: Light metals, pp 307–311

    Google Scholar 

  23. Habib A, Riverin J-F (2019) Commissioning and start-up of Alba Line 6 project using EGA DX+ Ultra Technology. In: Proceedings of 37th international ICSOBA conference and XXV conference «Aluminium of Siberia», Krasnoyarsk, Russia, 16–20 Sept 2019, Paper AL12, Travaux 48, pp 831–841

    Google Scholar 

  24. Ban Y et al (2018) Development and industrial application of NEUI600 high efficiency aluminum reduction cell. In: Light metals, pp 705–713

    Google Scholar 

  25. Dufour O, Richard P, Vanvoren C (2018) Towards 4.0: the smelter of the future. Aluminium Int Today 11–16

    Google Scholar 

  26. Solheim A (2018) Inert anodes—the blind alley to environmental friendliness? In: Light metals, pp 1253–1260

    Google Scholar 

  27. https://www.elysis.com/en/rio-tinto-and-alcoa-announce-worlds-first-carbon-free-aluminium-smelting-process. Retrieved on 26 Sept 2019

  28. Mann V et al (2018) Environmental aspects of UC RUSAL’s aluminum smelters sustainable development. In: Proceedings of the 36th international ICSOBA conference, Belem, Brazil, 29 Oct–1 Nov 2018, Travaux 47, pp 745–755

    Google Scholar 

  29. Pawlek RP (2010) Wettable cathodes: an update. In: Light metals, pp 377–382

    Google Scholar 

  30. Grunert E, Mercier J (1961) Reduction of alumina. US patent 2,974,032, filed on 28 Feb 1960, granted on 7 Mar 1961

    Google Scholar 

  31. Bruno MJ (2003) Aluminum carbothermic technology comparison to Hall-Héroult process. In: Light metals, pp 395–400

    Google Scholar 

  32. Johansen K, Aune JA, Bruno M, Schei A (2003) Aluminum carbothermic technology Alcoa-Elkem advanced reactor process. In: Light metals, pp 401–406

    Google Scholar 

  33. Bruno MJ (2004) Aluminum carbothermic technology, final technical progress report for the period 2000 July through 2004 Dec, submitted to: U.S. Department of Energy, 31 Dec 2004. https://digital.library.unt.edu/ark:/67531/metadc787817/m2/1/high_res_d/838679.pdf. Accessed 1 Oct 2019

  34. White CV, Mikkelsen Ø, Roha D (2012) Status of the Alcoa carbothermic aluminum project. In: International smelting technology symposium (incorporating the 6th advances in sulfide smelting symposium). TMS (The Minerals, Metals and Materials Society), San Antonio, TX, pp 81–88

    Google Scholar 

  35. Kvande H, Drabløs PA (2014) The aluminum smelting process and innovative alternative technologies. JOEM 56(5S):S23–S32

    Google Scholar 

  36. Ikram-ul-Haq M, Khanna R, Mukherjee PS, Sahajwalla V (2018) 2. Recent developments in lower temperature carbothermic reduction of alumina as alternative routes for aluminium production. Recent Res Dev Mat Sci 11:25–42

    Google Scholar 

  37. Kannan CN, Desikan PS (1985) A critical appraisal and review of aluminium chloride electrolysis for the production of aluminium. Bull Electrochem 1(5):483–488

    Google Scholar 

  38. Russel AS (1981) Pitfalls and pleasures in new aluminum process development. Metall Trans B 12B:203–215

    Article  Google Scholar 

  39. Page 545 of Minerals yearbook 1985 vol II, Area reports domestic, United States Department of Interior, 1985, US Government Printing Office 1987

    Google Scholar 

  40. Øye B. Could the chloride process replace the Hall-Héroult process in aluminium production? SINTEF Blog. https://blog.sintef.com/sintefenergy/energy-efficiency/could-the-chloride-process-replace-the-hall-heroult-process-in-aluminium-production/

  41. Haupin WE (1973) Light metal production. US patent 3,755,099, filed 8 Sept 1971, granted 28 Aug 1973

    Google Scholar 

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Correspondence to Michel Reverdy .

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Reverdy, M., Potocnik, V. (2020). History of Inventions and Innovations for Aluminum Production. In: TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36296-6_175

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