Abstract
Chapter 4 deals with the thermodynamics of polymer solutions, i.e. a polymer dissolved in a low molar mass solvent, a low molar mass substance swelling a solid polymer and polymer blends. A starting point is the regular solution model, which is used as a vehicle to explain a number of fundamental concepts: phase separation, binodal points, spinodal decomposition, critical points (UCST and LCST), chemical potential issues, etc. The Flory-Huggins model (being a polymer version of the regular solution model) including its limitations is comprehensively discussed. The solubility parameter concept originating from the work of Hildebrand and Scatchard and also the more recent Hansen parameter model, the scaling law models according to des Cloiseaux and de Gennes, and the equation-of-state models are covered. The morphology of polymer blends based on both thermodynamics and the kinetics is discussed in the final section.
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Gedde, U.W., Hedenqvist, M.S. (2019). Polymer Solutions. In: Fundamental Polymer Science. Graduate Texts in Physics. Springer, Cham. https://doi.org/10.1007/978-3-030-29794-7_4
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