Abstract
The photochemical water splitting to produce O2 and H2 is considered as the most promising, sustainable, renewable and cost-effective energy technology for the future. In photochemical water splitting process, the efficiency of H2 and O2 production rates depends on the properties of the selected semiconductor material. However, most of the semiconductors face various limitations which confines their water splitting efficiency. Different strategies could be implemented to improve the water splitting efficiency of semiconductors. Among them, loading of catalyst onto the water splitting material is known to be one of the effective strategy to enhance the H2 and O2 production rates. Given this, several catalytic materials have been explored and successfully utilized in efficient O2 and H2 production systems. In this chapter, we summarize some of the effective O2 and H2 production catalysts derived from noble metal, noble metal oxides, earth-abundant metals and oxides, metal phosphides and metal chalcogenides. The surface deposited catalysts were known to reduce the surface trap states, which decreases the charge recombination and acts as protective layer to minimize photo-corrosion of the light absorbing semiconductors. Conclusively, to explore the efficient catalysts for photochemical water splitting require more research contribution towards the understanding of the core reaction mechanism of catalytic process with the use of sustainable and stable materials.
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References
Abe R (2011) Development of a new system for photocatalytic water splitting into H2 and O2 under visible light irradiation. BCSJ 84:1000–1030. https://doi.org/10.1246/bcsj.20110132
Agegnehu AK, Pan C-J, Rick J, Lee J-F, Su W-N, Hwang B-J (2012) Enhanced hydrogen generation by cocatalytic Ni and NiO nanoparticles loaded on graphene oxide sheets. J Mater Chem 22:13849–13854. https://doi.org/10.1039/C2JM30474K
Badwal SPS, Giddey S, Munnings C (2013) Hydrogen production via solid electrolytic routes. Wiley Interdisc Rev Energy Environ 2:473–487. https://doi.org/10.1002/wene.50
Balat M (2008) Potential importance of hydrogen as a future solution to environmental and transportation problems. Int J Hydrogen Energy 33:4013–4029. https://doi.org/10.1016/j.ijhydene.2008.05.047
Bard AJ (1979) Photoelectrochemistry and heterogeneous photo-catalysis at semiconductors. J Photochem 10:59–75. https://doi.org/10.1016/0047-2670(79)80037-4
Birol F (2006) World energy prospects and challenges. Aust Econ Rev 39:190–195. https://doi.org/10.1111/j.1467-8462.2006.00411.x
Bolton JR, Strickler SJ, Connolly JS (1985) Limiting and realizable efficiencies of solar photolysis of water. Nature 316:495. https://doi.org/10.1038/316495a0
Cao S, Chen Y, Wang C-J, He P, Fu W-F (2014) Highly efficient photocatalytic hydrogen evolution by nickel phosphide nanoparticles from aqueous solution. Chem Commun 50:10427–10429. https://doi.org/10.1039/C4CC05026F
Cao S, Chen Y, Wang C-J, Lv X-J, Fu W-F (2015) Spectacular photocatalytic hydrogen evolution using metal-phosphide/CdS hybrid catalysts under sunlight irradiation. Chem Commun 51:8708–8711. https://doi.org/10.1039/C5CC01799H
Cao S, Wang C-J, Fu W-F, Chen Y (2017) Metal phosphides as Co-catalysts for photocatalytic and photoelectrocatalytic water splitting. Chemsuschem 10:4306–4323. https://doi.org/10.1002/cssc.201701450
Cao S, Wang C-J, Lv X-J, Chen Y, Fu W-F (2015) A highly efficient photocatalytic H2 evolution system using colloidal CdS nanorods and nickel nanoparticles in water under visible light irradiation. Appl Catal B 162:381–391. https://doi.org/10.1016/j.apcatb.2014.07.014
Carroll GM, Gamelin DR (2016) Kinetic analysis of photoelectrochemical water oxidation by mesostructured Co-Pi/α-Fe2O3 photoanodes. J Mater Chem A 4:2986–2994. https://doi.org/10.1039/C5TA06978E
Chemelewski WD, Lee H-C, Lin J-F, Bard AJ, Mullins CB (2014) Amorphous FeOOH oxygen evolution reaction catalyst for photoelectrochemical water splitting. J Am Chem Soc 136:2843–2850. https://doi.org/10.1021/ja411835a
Chen S, Takata T, Domen K (2017) Particulate photocatalysts for overall water splitting. Nat Rev Mater 2:17050. https://doi.org/10.1038/natrevmats.2017.50
Chen X, Zhang Z, Chi L, Nair AK, Shangguan W, Jiang Z (2016) Recent advances in visible-light-driven photoelectrochemical water splitting: catalyst nanostructures and reaction systems. Nano-Micro Lett 8:1–12. https://doi.org/10.1007/s40820-015-0063-3
Cheng H, Lv X-J, Cao S, Zhao Z-Y, Chen Y, Fu W-F (2016) Robustly photogenerating H2 in water using FeP/CdS catalyst under solar irradiation. Sci Rep 6:19846. https://doi.org/10.1038/srep19846
Choi J, Ryu SY, Balcerski W, Lee TK, Hoffmann MR (2008) Photocatalytic production of hydrogen on Ni/NiO/KNbO3/CdS nanocomposites using visible light. J Mater Chem 18:2371–2378. https://doi.org/10.1039/B718535A
Clarke RE, Giddey S, Badwal SPS (2010) Stand-alone PEM water electrolysis system for fail safe operation with a renewable energy source. Int J Hydrogen Energy 35:928–935. https://doi.org/10.1016/j.ijhydene.2009.11.100
Dinh C-T, Pham M-H, Kleitz F, Do T-O (2013) Design of water-soluble CdS–titanate–nickel nanocomposites for photocatalytic hydrogen production under sunlight. J Mater Chem A 1:13308–13313. https://doi.org/10.1039/C3TA12914D
Eftekhari A, Fang B (2017) Electrochemical hydrogen storage: opportunities for fuel storage, batteries, fuel cells, and supercapacitors. Int J Hydrogen Energy 42:25143–25165. https://doi.org/10.1016/j.ijhydene.2017.08.103
Fang Y-H, Liu Z-P (2010) Mechanism and tafel lines of electro-oxidation of water to oxygen on RuO2(110). J Am Chem Soc 132:18214–18222. https://doi.org/10.1021/ja1069272
Le Formal F, Pendlebury SR, Cornuz M, Tilley SD, Grätzel M, Durrant JR (2014) Back electron-hole recombination in hematite photoanodes for water splitting. J Am Chem Soc 136:2564–2574. https://doi.org/10.1021/ja412058x
Frame FA, Townsend TK, Chamousis RL, Sabio EM, Dittrich Th, Browning ND, Osterloh FE (2011) Photocatalytic water oxidation with nonsensitized IrO2 nanocrystals under visible and UV light. J Am Chem Soc 133:7264–7267. https://doi.org/10.1021/ja200144w
Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38. https://doi.org/10.1038/238037a0
Gupta B, Melvin AA, Matthews T, Dash S, Tyagi AK (2014) Facile gamma radiolytic synthesis of synergistic Co3O4-rGO nanocomposite: direct use in photocatalytic water splitting. Mater Res Express 1:045507. https://doi.org/10.1088/2053-1591/1/4/045507
Gurudayal Bassi PS, Sritharan T, Wong LH (2018) Recent progress in iron oxide based photoanodes for solar water splitting. J Phys D Appl Phys 51:473002. https://doi.org/10.1088/1361-6463/aae138
Han B, Hu YH (2016) MoS2 as a co-catalyst for photocatalytic hydrogen production from water. Energy Sci Eng 4:285–304. https://doi.org/10.1002/ese3.128
Hara M, Kondo T, Komoda M, Ikeda S, Kondo JN, Domen K, Hara M, Shinohara K, Tanaka A (1998) Cu2O as a photocatalyst for overall water splitting under visible light irradiation. Chem Commun 3:357–358. https://doi.org/10.1039/A707440I
Hara M, Nunoshige J, Takata T, Kondo JN, Domen K (2003) Unusual enhancement of H2 evolution by Ru on TaON photocatalyst under visible light irradiation. Chem Commun 24:3000–3001. https://doi.org/10.1039/B309935K
Holladay JD, Hu J, King DL, Wang Y (2009) An overview of hydrogen production technologies. Catal Today 139:244–260. https://doi.org/10.1016/j.cattod.2008.08.039
Hong J, Wang Y, Wang Y, Zhang W, Xu R (2013) Noble-metal-free NiS/C3N4 for efficient photocatalytic hydrogen evolution from water. Chemsuschem 6:2263–2268. https://doi.org/10.1002/cssc.201300647
Hu S, Lewis NS, Ager JW, Yang J, McKone JR, Strandwitz NC (2015) Thin-film materials for the protection of semiconducting photoelectrodes in solar-fuel generators. J Phys Chem C 119:24201–24228. https://doi.org/10.1021/acs.jpcc.5b05976
Hu Z, Yu JC (2013) Pt3Co-loaded CdS and TiO2 for photocatalytic hydrogen evolution from water. J Mater Chem A 1:12221–12228. https://doi.org/10.1039/C3TA12407J
Huang Y, Liu Z, Gao G, Xiao G, Du A, Bottle S, Sarina S, Zhu H (2017) Stable copper nanoparticle photocatalysts for selective epoxidation of alkenes with visible light. ACS Catal 7:4975–4985. https://doi.org/10.1021/acscatal.7b01180
Iwase A, Yoshino S, Takayama T, Ng YH, Amal R, Kudo A (2016) Water splitting and CO2 reduction under visible light irradiation using Z-scheme systems consisting of metal sulfides, CoOx-Loaded BiVO4, and a reduced graphene oxide electron mediator. J Am Chem Soc 138:10260–10264. https://doi.org/10.1021/jacs.6b05304
Jacobsson TJ, Fjällström V, Edoff M, Edvinsson T (2014) Sustainable solar hydrogen production: from photoelectrochemical cells to PV-electrolyzers and back again. Energy Environ Sci 7:2056–2070. https://doi.org/10.1039/C4EE00754A
Jakob M, Levanon H, Prashant VK (2003) Charge Distribution between UV-Irradiated TiO2 and Gold Nanoparticles: Determination of Shift in the Fermi Level. Nano Letters 3:353–358. https://doi.org/10.1021/nl0340071
Janáky C, Chanmanee W, Rajeshwar K (2013) On the substantially improved photoelectrochemical properties of nanoporous WO3 through surface decoration with RuO2. Electrocatalysis 4:382–389. https://doi.org/10.1007/s12678-013-0177-7
Jian J, Jiang G, van de Krol R, Wei B, Wang H (2018) Recent advances in rational engineering of multinary semiconductors for photoelectrochemical hydrogen generation. Nano Energy 51:457–480. https://doi.org/10.1016/j.nanoen.2018.06.074
Kalanoor BS, Seo H, Kalanur SS (2018) Recent developments in photoelectrochemical water-splitting using WO3/BiVO4 heterojunction photoanode: a review. Mater Sci Energy Technol 1:49–62. https://doi.org/10.1016/j.mset.2018.03.004
Kalanur SS, Duy LT, Seo H (2018) Recent progress in photoelectrochemical water splitting activity of WO3 photoanodes. Top Catal 61:1–34. https://doi.org/10.1007/s11244-018-0950-1
Kalanur SS, Hwang YJ, Chae SY, Joo OS (2013) Facile growth of aligned WO3 nanorods on FTO substrate for enhanced photoanodic water oxidation activity. J Mater Chem A 1:3479–3488. https://doi.org/10.1039/C3TA01175E
Kalanur SS, Hwang YJ, Joo O-S (2013) Construction of efficient CdS–TiO2 heterojunction for enhanced photocurrent, photostability, and photoelectron lifetimes. J Colloid Interface Sci 402:94–99. https://doi.org/10.1016/j.jcis.2013.03.049
Kalanur SS, Hwang J-Y, Seo H (2017) Facile fabrication of bitter-gourd-shaped copper (II) tungstate thin films for improved photocatalytic water splitting. J Catal 350:197–202. https://doi.org/10.1016/j.jcat.2017.04.008
Kalanur SS, Lee SH, Hwang YJ, Joo O-S (2013) Enhanced photoanode properties of CdS nanoparticle sensitized TiO2 nanotube arrays by solvothermal synthesis. J Photochem Photobiol, A 259:1–9. https://doi.org/10.1016/j.jphotochem.2013.02.018
Kalanur SS, Seo H (2019) Intercalation of barium into monoclinic tungsten oxide nanoplates for enhanced photoelectrochemical water splitting. Chem Eng J 355:784–796. https://doi.org/10.1016/j.cej.2018.08.210
Kalanur SS, Seo H (2019) Facile growth of compositionally tuned copper vanadate nanostructured thin films for efficient photoelectrochemical water splitting. Appl Catal B 249:235–245. https://doi.org/10.1016/j.apcatb.2019.02.069
Kanan MW, Surendranath Y, Nocera DG (2008) Cobalt–phosphate oxygen-evolving compound. Chem Soc Rev 38:109–114. https://doi.org/10.1039/B802885K
Kegel J, Povey IM, Pemble ME (2018) Zinc oxide for solar water splitting: a brief review of the material’s challenges and associated opportunities. Nano Energy 54:409–428. https://doi.org/10.1016/j.nanoen.2018.10.043
Kenney MJ, Gong M, Li Y, Wu JZ, Feng J, Lanza M, Dai H (2013) High-performance silicon photoanodes passivated with ultrathin nickel films for water oxidation. Science 342:836–840. https://doi.org/10.1126/science.1241327
Khaselev O, Turner JA (1998) A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting. Science 280:425–427. https://doi.org/10.1126/science.280.5362.425
Klahr B, Gimenez S, Fabregat-Santiago F, Bisquert J, Hamann TW (2012) Photoelectrochemical and impedance spectroscopic investigation of water oxidation with “Co–Pi”-coated hematite electrodes. J Am Chem Soc 134:16693–16700. https://doi.org/10.1021/ja306427f
Korzhak AV, Ermokhina NI, Stroyuk AL, Bukhtiyarov VK, Raevskaya AE, Litvin VI, Kuchmiy SY, Ilyin VG, Manorik PA (2008) Photocatalytic hydrogen evolution over mesoporous TiO2/metal nanocomposites. J Photochem Photobiol, A 198:126–134. https://doi.org/10.1016/j.jphotochem.2008.02.026
Kudo A, Miseki Y (2008) Heterogeneous photocatalyst materials for water splitting. Chem Soc Rev 38:253–278. https://doi.org/10.1039/B800489G
Lewis NS, Nocera DG (2006) Powering the planet: chemical challenges in solar energy utilization. PNAS 103:15729–15735. https://doi.org/10.1073/pnas.0603395103
Li Q, Guo B, Yu J, Ran J, Zhang B, Yan H, Gong JR (2011) Highly efficient visible-light-driven photocatalytic hydrogen production of Cds-cluster-decorated graphene nanosheets. J Am Chem Soc 133:10878–10884. https://doi.org/10.1021/ja2025454
Li J, Wu N (2015) Semiconductor-based photocatalysts and photoelectrochemical cells for solar fuel generation: a review. Catal Sci Technol 5:1360–1384. https://doi.org/10.1039/C4CY00974F
Li X, Yu J, Low J, Fang Y, Xiao J, Chen X (2015) Engineering heterogeneous semiconductors for solar water splitting. J Mater Chem A 3:2485–2534. https://doi.org/10.1039/C4TA04461D
Li Y, Yu Z, Meng J, Li Y (2013) Enhancing the activity of a SiC–TiO2 composite catalyst for photo-stimulated catalytic water splitting. Int J Hydrogen Energy 38:3898–3904. https://doi.org/10.1016/j.ijhydene.2013.01.077
Licht S, Wang B, Mukerji S, Soga T, Umeno M, Tributsch H (2000) Efficient solar water splitting, exemplified by RuO2-Catalyzed AlGaAs/Si photoelectrolysis. J Phys Chem B 104:8920–8924. https://doi.org/10.1021/jp002083b
Lin Z, Li J, Li L, Yu L, Li W, Yang G (2017) Manipulating the hydrogen evolution pathway on composition-tunable CuNi nanoalloys. J Mater Chem A 5:773–781. https://doi.org/10.1039/C6TA09169E
Lin H-Y, Yang H-C, Wang W-L (2011) Synthesis of mesoporous Nb2O5 photocatalysts with Pt, Au, Cu and NiO cocatalyst for water splitting. Catal Today 174:106–113. https://doi.org/10.1016/j.cattod.2011.01.052
Lingampalli SR, Gautam UK, Rao CNR (2013) Highly efficient photocatalytic hydrogen generation by solution-processed ZnO/Pt/CdS, ZnO/Pt/Cd1−xZnxS and ZnO/Pt/CdS1−xSex hybrid nanostructures. Energy Environ Sci 6:3589–3594. https://doi.org/10.1039/C3EE42623H
Linic S, Christopher P, Ingram DB (2011) Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy. Nat Mater 10:911–921. https://doi.org/10.1038/nmat3151
Maeda K, Domen K (2007) New non-oxide photocatalysts designed for overall water splitting under visible light. J Phys Chem C 111:7851–7861. https://doi.org/10.1021/jp070911w
Mangrulkar PA, Joshi MM, Tijare SN, Polshettiwar V, Labhsetwar NK, Rayalu SS (2012) Nano cobalt oxides for photocatalytic hydrogen production. Int J Hydrogen Energy 37:10462–10466. https://doi.org/10.1016/j.ijhydene.2012.01.112
Marimuthu A, Zhang J, Linic S (2013) Tuning selectivity in propylene epoxidation by plasmon mediated photo-switching of Cu oxidation state. Science 339:1590–1593. https://doi.org/10.1126/science.1231631
May MM, Lewerenz H-J, Lackner D, Dimroth F, Hannappel T (2015) Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure. Nat Commun 6:8286. https://doi.org/10.1038/ncomms9286
Mei Z, Li Y, Yang X, Ren W, Tong S, Zhang N, Zhao W, Lin Y, Pan F (2018) Tuning nanosheet Fe2O3 photoanodes with C3N4 and p-type CoOx decoration for efficient and stable water splitting. Catal Sci Technol 8:3144–3150. https://doi.org/10.1039/C8CY00729B
Melchionna M, Beltram A, Stopin A, Montini T, Lodge RW, Khlobystov AN, Bonifazi D, Prato M, Fornasiero P (2018) Magnetic shepherding of nanocatalysts through hierarchically-assembled Fe-filled CNTs hybrids. Appl Catal B 227:356–365. https://doi.org/10.1016/j.apcatb.2018.01.049
Miyoshi A, Nishioka S, Maeda K (2018) Water splitting on rutile TiO2-based photocatalysts. Chem Eur J 24:18204–18219. https://doi.org/10.1002/chem.201800799
Moore GF, Brudvig GW (2011) Energy conversion in photosynthesis: a paradigm for solar fuel production. Annu Rev Condens Matter Phys 2:303–327. https://doi.org/10.1146/annurev-conmatphys-062910-140503
Murdoch M, Waterhouse GIN, Nadeem MA, Metson JB, Keane MA, Howe RF, Llorca J, Idriss H (2011) The effect of gold loading and particle size on photocatalytic hydrogen production from ethanol over Au/TiO2 nanoparticles. Nat Chem 3:489–492. https://doi.org/10.1038/nchem.1048
Nishiyama H, Kobayashi H, Inoue Y (2011) Effects of distortion of metal-oxygen octahedra on photocatalytic water-splitting performance of RuO2-loaded niobium and tantalum phosphate bronzes. Chemsuschem 4:208–215. https://doi.org/10.1002/cssc.201000294
Onsuratoom S, Puangpetch T, Chavadej S (2011) Comparative investigation of hydrogen production over Ag-, Ni-, and Cu-loaded mesoporous-assembled TiO2–ZrO2 mixed oxide nanocrystal photocatalysts. Chem Eng J 173:667–675. https://doi.org/10.1016/j.cej.2011.08.016
Osterloh FE (2013) Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting. Chem Soc Rev 42:2294–2320. https://doi.org/10.1039/C2CS35266D
Pan L, Kim JH, Mayer MT, Son M-K, Ummadisingu A, Lee JS, Hagfeldt A, Luo J, Grätzel M (2018) Boosting the performance of Cu2O photocathodes for unassisted solar water splitting devices. Nat Catal 1:412. https://doi.org/10.1038/s41929-018-0077-6
Pan Z, Zheng Y, Guo F, Niu P, Wang X (2017) Decorating CoP and Pt nanoparticles on graphitic carbon nitride nanosheets to promote overall water splitting by conjugated polymers. Chemsuschem 10:87–90. https://doi.org/10.1002/cssc.201600850
Pastoriza-Santos I, Sánchez-Iglesias A, Rodríguez-González B, Liz-Marzán LM (2009) Aerobic synthesis of Cu nanoplates with intense plasmon resonances. Small 5:440–443. https://doi.org/10.1002/smll.200801088
Popczun EJ, McKone JR, Read CG, Biacchi AJ, Wiltrout AM, Lewis NS, Schaak RE (2013) Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction. J Am Chem Soc 135:9267–9270. https://doi.org/10.1021/ja403440e
Porosoff MD, Yan B, Chen JG (2016) Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities. Energy Environ Sci 9:62–73. https://doi.org/10.1039/C5EE02657A
Potje-Kamloth K (2008) Semiconductor junction gas sensors. Chem Rev 108:367–399. https://doi.org/10.1021/cr0681086
Ran J, Zhang J, Yu J, Jaroniec M, Qiao SZ (2014) Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting. Chem Soc Rev 43:7787–7812. https://doi.org/10.1039/C3CS60425J
Reddy DA, Choi J, Lee S, Kim Y, Hong S, Kumar DP, Kim TK (2016) Hierarchical dandelion-flower-like cobalt-phosphide modified CdS/reduced graphene oxide-MoS2 nanocomposites as a noble-metal-free catalyst for efficient hydrogen evolution from water. Catal Sci Technol 6:6197–6206. https://doi.org/10.1039/C6CY00768F
Reddy VR, Hwang DW, Lee JS (2003) Photocatalytic water splitting over ZrO2 prepared by precipitation method. Korean J Chem Eng 20:1026–1029. https://doi.org/10.1007/BF02706932
Saadetnejad D, Yıldırım R (2018) Photocatalytic hydrogen production by water splitting over Au/Al-SrTiO3. Int J Hydrogen Energy 43:1116–1122. https://doi.org/10.1016/j.ijhydene.2017.10.154
Sasaki Y, Iwase A, Kato H, Kudo A (2008) The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation. J Catal 259:133–137. https://doi.org/10.1016/j.jcat.2008.07.017
Sayama K, Yase K, Arakawa H, Asakura K, Tanaka A, Domen K, Onishi T (1998) Photocatalytic activity and reaction mechanism of Pt-intercalated K4Nb6O17 catalyst on the water splitting in carbonate salt aqueous solution. J Photochem Photobiol, A 114:125–135. https://doi.org/10.1016/S1010-6030(98)00202-0
Sayed FN, Jayakumar OD, Sasikala R, Kadam RM, Bharadwaj SR, Kienle L, Schürmann U, Kaps S, Adelung R, Mittal JP, Tyagi AK (2012) Photochemical hydrogen generation using nitrogen-doped TiO2–Pd nanoparticles: facile synthesis and effect of Ti3+ incorporation. J Phys Chem C 116:12462–12467. https://doi.org/10.1021/jp3029962
Seger B, Laursen AB, Vesborg PCK, Pedersen T, Hansen O, Dahl S, Chorkendorff I (2012) Hydrogen production using a molybdenum sulfide catalyst on a titanium-protected n+p-silicon photocathode. Angew Chem Int Ed 51:9128–9131. https://doi.org/10.1002/anie.201203585
Seo SW, Park S, Jeong H-Y, Kim SH, Sim U, Lee CW, Nam KT, Hong KS (2012) Enhanced performance of NaTaO3 using molecular co-catalyst [Mo3S4]4+ for water splitting into H2 and O2. Chem Commun 48:10452–10454. https://doi.org/10.1039/C2CC36216C
Shi J, Guo L (2012) ABO3-based photocatalysts for water splitting. Progr Nat Sci Mater Int 22:592–615. https://doi.org/10.1016/j.pnsc.2012.12.002
Simon T, Bouchonville N, Berr MJ, Vaneski A, Adrović A, Volbers D, Wyrwich R, Döblinger M, Susha AS, Rogach AL, Jäckel F, Stolarczyk JK, Feldmann J (2014) Redox shuttle mechanism enhances photocatalytic H2 generation on Ni-decorated CdS nanorods. Nat Mater 13:1013–1018. https://doi.org/10.1038/nmat4049
Sinigaglia T, Lewiski F, Santos Martins ME, Mairesse Siluk JC (2017) Production, storage, fuel stations of hydrogen and its utilization in automotive applications-a review. Int J Hydrogen Energy 42:24597–24611. https://doi.org/10.1016/j.ijhydene.2017.08.063
Sreethawong T, Suzuki Y, Yoshikawa S (2005) Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol–gel process with surfactant template. Int J Hydrogen Energy 30:1053–1062. https://doi.org/10.1016/j.ijhydene.2004.09.007
Stern PC, Sovacool BK, Dietz T (2016) Towards a science of climate and energy choices. Nature Climate Change 6:547–555. https://doi.org/10.1038/nclimate3027
Sun Z, Chen H, Huang Q, Du P (2015) Enhanced photocatalytic hydrogen production in water under visible light using noble metal-free ferrous phosphide as an active cocatalyst. Catal Sci Technol 5:4964–4967. https://doi.org/10.1039/C5CY01293G
Sun Z, Lv B, Li J, Xiao M, Wang X, Du P (2016) Core–shell amorphous cobalt phosphide/cadmium sulfide semiconductor nanorods for exceptional photocatalytic hydrogen production under visible light. J Mater Chem A 4:1598–1602. https://doi.org/10.1039/C5TA07561K
Sun Z, Yue Q, Li J, Xu J, Zheng H, Du P (2015) Copper phosphide modified cadmium sulfide nanorods as a novel p–n heterojunction for highly efficient visible-light-driven hydrogen production in water. J Mater Chem A 3:10243–10247. https://doi.org/10.1039/C5TA02105G
Sun Z, Zheng H, Li J, Du P (2015) Extraordinarily efficient photocatalytic hydrogen evolution in water using semiconductor nanorods integrated with crystalline Ni2P cocatalysts. Energy Environ Sci 8:2668–2676. https://doi.org/10.1039/C5EE01310K
Tachibana Y, Vayssieres L, Durrant JR (2012) Artificial photosynthesis for solar water-splitting. Nat Photonics 6:511–518. https://doi.org/10.1038/nphoton.2012.175
Takata T, Domen K (2019) Particulate photocatalysts for water splitting: recent advances and future prospects. ACS Energy Lett 4:542–549. https://doi.org/10.1021/acsenergylett.8b02209
Takata T, Pan C, Nakabayashi M, Shibata N, Domen K (2015) Fabrication of a core–shell-type photocatalyst via photodeposition of group IV and V transition metal oxyhydroxides: an effective surface modification method for overall water splitting. J Am Chem Soc 137:9627–9634. https://doi.org/10.1021/jacs.5b04107
Tang ML, Grauer DC, Lassalle-Kaiser B, Yachandra VK, Amirav L, Long JR, Yano J, Alivisatos AP (2011) Structural and electronic study of an amorphous MoS3 hydrogen-generation catalyst on a quantum-controlled photosensitizer. Angew Chem Int Ed 50:10203–10207. https://doi.org/10.1002/anie.201104412
Tian H, Zhang XL, Scott J, Ng C, Amal R (2014) TiO2-supported copper nanoparticles prepared via ion exchange for photocatalytic hydrogen production. J Mater Chem A 2:6432–6438. https://doi.org/10.1039/C3TA15254E
Tran PD, Xi L, Batabyal SK, Wong LH, Barber J, Loo JSC (2012) Enhancing the photocatalytic efficiency of TiO2 nanopowders for H2 production by using non-noble transition metal co-catalysts. Phys Chem Chem Phys 14:11596–11599. https://doi.org/10.1039/C2CP41450C
Trześniewski BJ, Smith WA (2016) Photocharged BiVO4 photoanodes for improved solar water splitting. J Mater Chem A 4:2919–2926. https://doi.org/10.1039/C5TA04716A
Wan S, Ou M, Zhong Q, Zhang S, Song F (2017) Construction of Z-scheme photocatalytic systems using ZnIn2S4, CoOx-loaded Bi2MoO6 and reduced graphene oxide electron mediator and its efficient nonsacrificial water splitting under visible light. Chem Eng J 325:690–699. https://doi.org/10.1016/j.cej.2017.05.047
Wang C, Cao S, Fu W-F (2013) A stable dual-functional system of visible-light-driven Ni(II) reduction to a nickel nanoparticle catalyst and robust in situ hydrogen production. Chem Commun 49:11251–11253. https://doi.org/10.1039/C3CC46623J
Wang J, Li B, Chen J, Li N, Zheng J, Zhao J, Zhu Z (2012) Enhanced photocatalytic H2-production activity of CdxZn1−xS nanocrystals by surface loading MS (M = Ni Co, Cu) species. Appl Surf Sci 259:118–123. https://doi.org/10.1016/j.apsusc.2012.07.003
Wang X, Liu G, Wang L, Chen Z-G, Lu GQ, Cheng H-M (2012) ZnO–CdS@Cd heterostructure for effective photocatalytic hydrogen generation. Adv Energy Mater 2:42–46. https://doi.org/10.1002/aenm.201100528
Wang Z, Wang J, Li L, Zheng J, Jia S, Chen J, Liu B, Zhu Z (2017) Fabricating efficient CdSe–CdS photocatalyst systems by spatially resetting water splitting sites. J Mater Chem A 5:20131–20135. https://doi.org/10.1039/C7TA06085H
Wang Y, Zhu D, Xu X (2016) Zr-doped mesoporous Ta3N5 microspheres for efficient photocatalytic water oxidation. ACS Appl Mater Interfaces 8:35407–35418. https://doi.org/10.1021/acsami.6b14230
Wu W, Yue X, Wu X-Y, Lu C-Z (2016) Efficient visible-light-induced hydrogen evolution from water splitting using a nanocrystalline nickel phosphide catalyst. RSC Adv 6:24361–24365. https://doi.org/10.1039/C5RA25286E
Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 Nanoparticles. J Am Chem Soc 134:6575–6578. https://doi.org/10.1021/ja302846n
Xu X-T, Pan L, Zhang X, Wang L, Zou J-J (2019) Rational Design and construction of cocatalysts for semiconductor-based photo-electrochemical oxygen evolution: a comprehensive review. Adv Sci 6:1801505. https://doi.org/10.1002/advs.201801505
Xu Y, Wu R, Zhang J, Shi Y, Zhang B (2013) Anion-exchange synthesis of nanoporous FeP nanosheets as electrocatalysts for hydrogen evolution reaction. Chem Commun 49:6656–6658. https://doi.org/10.1039/C3CC43107J
Yan H, Yang J, Ma G, Wu G, Zong X, Lei Z, Shi J, Li C (2009) Visible-light-driven hydrogen production with extremely high quantum efficiency on Pt–PdS/CdS photocatalyst. J Catal 266:165–168. https://doi.org/10.1016/j.jcat.2009.06.024
Yang T, Bao Y, Xiao W, Zhou J, Ding J, Feng YP, Loh KP, Yang M, Wang SJ (2018) Hydrogen evolution catalyzed by a molybdenum sulfide two-dimensional structure with active basal planes. ACS Appl Mater Interfaces 10:22042–22049. https://doi.org/10.1021/acsami.8b03977
Yang J, Wang D, Han H, Li C (2013) Roles of cocatalysts in photocatalysis and photoelectrocatalysis. Acc Chem Res 46:1900–1909. https://doi.org/10.1021/ar300227e
Yi S-S, Zhang X-B, Wulan B-R, Yan J-M, Jiang Q (2018) Non-noble metals applied to solar water splitting. Energy Environ Sci 11:3128–3156. https://doi.org/10.1039/C8EE02096E
Yoshida M, Takanabe K, Maeda K, Ishikawa A, Kubota J, Sakata Y, Ikezawa Y, Domen K (2009) Role and function of noble-metal/Cr-layer core/shell structure cocatalysts for photocatalytic overall water splitting studied by model electrodes. J Phys Chem C 113:10151–10157. https://doi.org/10.1021/jp901418u
Yu S-H, Chiu C-W, Wu Y-T, Liao C-H, Nguyen V-H, Wu JCS (2016) Photocatalytic water splitting and hydrogenation of CO2 in a novel twin photoreactor with IO3−/I− shuttle redox mediator. Appl Catal A 518:158–166. https://doi.org/10.1016/j.apcata.2015.08.027
Yuan Y-P, Cao S-W, Yin L-S, Xu L, Xue C (2013) NiS2 Co-catalyst decoration on CdLa2S4 nanocrystals for efficient photocatalytic hydrogen generation under visible light irradiation. Int J Hydrogen Energy 38:7218–7223. https://doi.org/10.1016/j.ijhydene.2013.03.169
Zeng C, Hu T, Hou N, Liu S, Gao W, Cong R, Yang T (2015) Photocatalytic pure water splitting activities for ZnGa2O4 synthesized by various methods. Mater Res Bull 61:481–485. https://doi.org/10.1016/j.materresbull.2014.10.041
Zhang L, Jiang T, Li S, Lu Y, Wang L, Zhang X, Wang D, Xie T (2013) Enhancement of photocatalytic H2 evolution on Zn0.8Cd0.2S loaded with CuS as cocatalyst and its photogenerated charge transfer properties. Dalton Trans 42:12998–13003. https://doi.org/10.1039/C3DT51256H
Zhang L, Tian B, Chen F, Zhang J (2012) Nickel sulfide as co-catalyst on nanostructured TiO2 for photocatalytic hydrogen evolution. Int J Hydrogen Energy 37:17060–17067. https://doi.org/10.1016/j.ijhydene.2012.08.120
Zhang Z, Yates JT (2012) Band bending in semiconductors: chemical and physical consequences at surfaces and interfaces. Chem Rev 112:5520–5551. https://doi.org/10.1021/cr3000626
Zhou X, Liu R, Sun K, Friedrich D, McDowell MT, Yang F, Omelchenko ST, Saadi FH, Nielander AC, Yalamanchili S, Papadantonakis KM, Brunschwig BS, Lewis NS (2015) Interface engineering of the photoelectrochemical performance of Ni-oxide-coated n-Si photoanodes by atomic-layer deposition of ultrathin films of cobalt oxide. Energy Environ Sci 8:2644–2649. https://doi.org/10.1039/C5EE01687H
Zhu Y, Marianov A, Xu H, Lang C, Jiang Y (2018) Bimetallic Ag–Cu supported on graphitic carbon nitride nanotubes for improved visible-light photocatalytic hydrogen production. ACS Appl Mater Interfaces 10:9468–9477. https://doi.org/10.1021/acsami.8b00393
Zong X, Han J, Ma G, Yan H, Wu G, Li C (2011) Photocatalytic H2 evolution on CdS loaded with WS2 as cocatalyst under visible light irradiation. J Phys Chem C 115:12202–12208. https://doi.org/10.1021/jp2006777
Zong X, Yan H, Wu G, Ma G, Wen F, Wang L, Li C (2008) Enhancement of photocatalytic H2 evolution on CdS by loading MoS2 as cocatalyst under visible light irradiation. J Am Chem Soc 130:7176–7177. https://doi.org/10.1021/ja8007825
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Kalanur, S.S., Seo, H. (2020). Electrocatalysts for Photochemical Water-Splitting. In: Inamuddin, Boddula, R., Asiri, A. (eds) Methods for Electrocatalysis. Springer, Cham. https://doi.org/10.1007/978-3-030-27161-9_7
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