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Super-Crystals in Composite Ferroelectrics

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Electro-optic Photonic Circuits

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Abstract

In this chapter, in Sect. 7.1, we report the discovery of spontaneous polarization “Super-crystals” in microstructured disordered ferroelectric samples, published in the article ’Super-crystals in composite ferroelectrics’, Nature Communications 7, 10674 (2016).

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References

  1. Agranat A, Hofmeister R, Yariv A (1992) Characterization of a new photorefractive material: K 1- ylyt 1- xnx. Opt Lett 17(10):713–715

    Article  ADS  Google Scholar 

  2. Agranat AJ, Kaner R, Perpelitsa G, Garcia Y (2007) Stable electro-optic striation grating produced by programed periodic modulation of the growth temperature. Appl Phys Lett 90(19):192902

    Article  ADS  Google Scholar 

  3. Agranat AJ, de Oliveira CEM, Orr G (2007) Dielectric electrooptic gratings in potassium lithium tantalate niobate. J Non-Cryst Solids 353(47):4405–4410

    Article  ADS  Google Scholar 

  4. Ayoub M, Imbrock J, Denz C (2011) Second harmonic generation in multi-domain \(\chi \) 2 media: from disorder to order. Opt Express 19(12):11340–11354

    ADS  Google Scholar 

  5. Baledent V, Chattopadhyay S, Fertey P, Lepetit MB, Greenblatt M, Wanklyn B, Saouma FO, Jang JI, Foury-Leylekian P (2015) Evidence for room temperature electric polarization in r m n 2 o 5 multiferroics. Phys Rev Lett 114(11):117601

    Article  ADS  Google Scholar 

  6. Biancoli A, Fancher CM, Jones JL, Damjanovic D (2015) Breaking of macroscopic centric symmetry in paraelectric phases of ferroelectric materials and implications for flexoelectricity. Nat Mater 14(2):224–229

    Article  ADS  Google Scholar 

  7. Bitman A, Sapiens N, Secundo L, Agranat AJ, Bartal G, Segev M (2006) Electroholographic tunable volume grating in the g 44 configuration. Opt Lett 31(19):2849–2851

    Article  ADS  Google Scholar 

  8. Bousquet E, Dawber M, Stucki N, Lichtensteiger C, Hermet P, Gariglio S, Triscone J-M, Ghosez P (2008) Improper ferroelectricity in perovskite oxide artificial superlattices. Nature 452(7188):732–736

    Article  ADS  Google Scholar 

  9. Callori SJ, Gabel J, Dong S, Sinsheimer J, Fernandez-Serra MV, Dawber M (2012) Ferroelectric pbtio 3/srruo 3 superlattices with broken inversion symmetry. Phys Rev Lett 109(6):067601

    Article  ADS  Google Scholar 

  10. Catalan G, Janssens A, Gijsbert Rispens S, Csiszar OS, Rijnders G, Blank DHA, Noheda B (2006) Polar domains in lead titanate films under tensile strain. Phys Rev Lett 96(12):127602

    Article  ADS  Google Scholar 

  11. Gustau Catalan A, Lubk AHGV, Snoeck E, Magen C, Janssens A, Rispens G, Rijnders G, Blank DHA, Noheda B (2011) Flexoelectric rotation of polarization in ferroelectric thin films. Nat Mater 10(12):963–967

    Article  ADS  Google Scholar 

  12. Chang Y-C, Wang C, Yin S, Hoffman RC, Mott AG (2013) Giant electro-optic effect in nanodisordered ktn crystals. Opt Lett 38(22):4574–4577

    Article  ADS  Google Scholar 

  13. Chao J-H, Zhu W, Chen C-J, Campbell AL, Henry MG, Yin S, Hoffman RC (2017) High speed non-mechanical two-dimensional ktn beam deflector enabled by space charge and temperature gradient deflection. Opt Express 25(13):15481–15492

    Article  ADS  Google Scholar 

  14. Chen L-Q (2008) Phase-field method of phase transitions/domain structures in ferroelectric thin films: a review. J Am Ceram Soc 91(6):1835–1844

    Article  Google Scholar 

  15. Choi KJ, Biegalski M, Li YL, Sharan A, Schubert J, Uecker R, Reiche P, Chen YB, Pan XQ, Gopalan V et al (2004) Enhancement of ferroelectricity in strained batio3 thin films. Science 306(5698):1005–1009

    Article  ADS  Google Scholar 

  16. Chu P, Chen DP, Wang YL, Xie YL, Yan ZB, Wan JG, Liu J-M, Li JY (2014) Kinetics of 90 domain wall motions and high frequency mesoscopic dielectric response in strained ferroelectrics: a phase-field simulation. Sci Rep 4:5007

    Article  ADS  Google Scholar 

  17. Dawber M, Rabe KM, Scott JF (2005) Physics of thin-film ferroelectric oxides. Rev Mod Phys 77(4):1083

    Article  ADS  Google Scholar 

  18. De Oliveira CEM, Orr G, Axelrold N, Agranat AJ (2004) Controlled composition modulation in potassium lithium tantalate niobate crystals grown by off-centered tssg method. J Cryst Growth 273(1):203–206

    Article  ADS  Google Scholar 

  19. DelRe E, Spinozzi E, Agranat AJ, Conti C (2011) Scale-free optics and diffractionless waves in nanodisordered ferroelectrics. Nat Photonics 5(1):39–42

    Article  ADS  Google Scholar 

  20. DelRe E, Di Mei F, Parravicini J, Parravicini G, Agranat AJ, Conti C (2015) Subwavelength anti-diffracting beams propagating over more than 1,000 rayleigh lengths. Nat Photonics

    Google Scholar 

  21. Di Mei F, Pierangeli D, Parravicini J, Claudio Conti AJ, Agranat EDR (2015) Observation of diffraction cancellation for nonparaxial beams in the scale-free-optics regime. Phys Rev A 92(1):013835

    Article  ADS  Google Scholar 

  22. Di Mei F, Caramazza P, Pierangeli D, Di Domenico G, Ilan H, Agranat AJ, Di Porto P, DelRe E (2016) Intrinsic negative mass from nonlinearity. Phys Rev Lett 116(15):153902

    Article  ADS  Google Scholar 

  23. Garcia V, Fusil S, Bouzehouane K, Enouz-Vedrenne S, Mathur ND, Barthelemy A, Bibes M (2009) Giant tunnel electroresistance for non-destructive readout of ferroelectric states. Nature 460(7251):81–84

    Article  ADS  Google Scholar 

  24. Glinchuk MD, Eliseev EA, Morozovska AN (2008) Superparaelectric phase in the ensemble of noninteracting ferroelectric nanoparticles. Phys Rev B 78(13):134107

    Article  ADS  Google Scholar 

  25. Gumennik A, Kurzweil-Segev Y, Agranat AJ (2011) Electrooptical effects in glass forming liquids of dipolar nano-clusters embedded in a paraelectric environment. Opt Mater Express 1(3):332–343

    Article  ADS  Google Scholar 

  26. Imai T, Miyazu J, Kobayashi J (2014) Measurement of charge density distributions in kta 1–x nb x o 3 optical beam deflectors. Opt Mater Express 4(5):976–981

    Article  ADS  Google Scholar 

  27. Jeong I-K, Darling TW, Lee J-K, Proffen T, Heffner RH, Park JS, Hong KS, Dmowski W, Egami T (2005) Direct observation of the formation of polar nanoregions in pb (mg 1/3 nb 2/3) o 3 using neutron pair distribution function analysis. Phys Rev Lett 94(14):147602

    Google Scholar 

  28. Khomeriki R, Chotorlishvili L, Tralle I, Berakdar J (2016) Positive-negative birefringence in multiferroic layered metasurfaces. Nano Lett 16(11):7290–7294

    Article  ADS  Google Scholar 

  29. Kim W-H, Son JY, Shin Y-H, Jang HM (2014) Imprint control of nonvolatile shape memory with asymmetric ferroelectric multilayers. Chem Mat 26(24):6911–6914

    Article  Google Scholar 

  30. Kleemann W, Schäfer FJ, Rytz D (1985) Diffuse ferroelectric phase transition and long-range order of dilute k ta 1–x nb x o 3. Phys Rev Lett 54(18):2038

    Article  ADS  Google Scholar 

  31. Kogelnik H (1969) Coupled wave theory for thick hologram gratings. Bell Labs Tech J 48(9):2909–2947

    Article  Google Scholar 

  32. Kounga AB, Granzow T, Aulbach E, Hinterstein M, Rödel J (2008) High-temperature poling of ferroelectrics. J Appl Phys 104(2):024116

    Article  ADS  Google Scholar 

  33. Kutnjak Z, Petzelt J, Blinc R (2006) The giant electromechanical response in ferroelectric relaxors as a critical phenomenon. Nature 441(7096):956–959

    Article  ADS  Google Scholar 

  34. Lawes G, Brooks Harris A, Tsuyoshi Kimura N, Rogado RJ, Cava AA, Entin-Wohlman O, Yildirim T, Michel Kenzelmann C, Broholm, et al (2005) Magnetically driven ferroelectric order in ni 3 v 2 o 8. Phys Rev Lett 95(8):087205

    Google Scholar 

  35. Lee HN, Christen HM, Chisholm MF, Rouleau CM, Lowndes DH (2005) Strong polarization enhancement in asymmetric three-component ferroelectric superlattices. Nature 433(7024):395–399

    Article  ADS  Google Scholar 

  36. Li BL, Liu XP, Fang F, Zhu JL, Liu J-M (2006) Monte carlo simulation of ferroelectric domain growth. Phys Rev B 73(1):014107

    Article  ADS  Google Scholar 

  37. Li H, Tian H, Gong D, Meng Q, Zhou Z (2013) High dielectric tunability of kta0. 60nb0. 40o3 single crystal. J Appl Phys 114(5):054103

    Article  ADS  Google Scholar 

  38. Li P-F, Tang Y-Y, Wang Z-X, Ye H-Y, You Y-M, Xiong R-G (2016) Anomalously rotary polarization discovered in homochiral organic ferroelectrics. Nat Commun 7:13635

    Article  ADS  Google Scholar 

  39. Li Q, Cao Y, Yu P, Vasudevan RK, Laanait N, Tselev A, Xue F, Chen LQ, Maksymovych P, Kalinin SV et al (2015) Giant elastic tunability in strained bifeo3 near an electrically induced phase transition. Nat Commun 6

    Google Scholar 

  40. Li YL, Hu SY, Liu ZK, Chen LQ (2001) Phase-field model of domain structures in ferroelectric thin films. Appl Phys Lett 78(24):3878–3880

    Article  ADS  Google Scholar 

  41. Lines ME, Glass AM (1977) Principles and applications of ferroelectrics and related materials. Oxford University Press, Oxford

    Google Scholar 

  42. Qieni L, Li B, Li Z, Ge B (2017) Field-induced lifetime enhancement of photorefractive gratings in a mn: Fe: Ktn crystal. Opt Lett 42(13):2407–2410

    Article  Google Scholar 

  43. Lummen TTA, Yijia G, Wang J, Lei S, Xue F, Kumar A, Barnes AT, Barnes E, Denev S, Belianinov A et al (2014) Thermotropic phase boundaries in classic ferroelectrics. Nat Commun 5:2014

    Article  Google Scholar 

  44. Manley ME, Lynn JW, Abernathy DL, Specht ED, Delaire O, Bishop AR, Sahul R, Budai JD (2014) Phonon localization drives polar nanoregions in a relaxor ferroelectric. Nat Commun 5

    Google Scholar 

  45. Meng X, Tian H, Tan P, Huang F, Zhang R, Zhou Z (2017) Strong electromechanical coupling in paraelectric kta1-xnbxo3 crystals. J Am Ceram Soc

    Google Scholar 

  46. Menzel C, Helgert C, Rockstuhl C, Kley E-B, Tünnermann A, Pertsch T, Lederer F (2010) Asymmetric transmission of linearly polarized light at optical metamaterials. Phys Rev Lett 104(25):253902

    Article  ADS  Google Scholar 

  47. Balthasar Mueller JP, Rubin NA, Devlin RC, Groever B, Capasso F (2017) Metasurface polarization optics: Independent phase control of arbitrary orthogonal states of polarization. Phys Rev Lett 118(11):113901

    Article  ADS  Google Scholar 

  48. Parravicini J, Martínez Lorente R, Di Mei F, Pierangeli D, Agranat AJ, DelRe E (2015) Volume integrated phase modulator based on funnel waveguides for reconfigurable miniaturized optical circuits. Opt Lett 40(7):1386–1389

    Article  ADS  Google Scholar 

  49. Parravicini J, DelRe E, Agranat AJ, Parravicini G (2016) Macroscopic response and directional disorder dynamics in chemically substituted ferroelectrics. Phys Rev B 93(9):094203

    Article  ADS  Google Scholar 

  50. Parravicini J, DelRe E, Agranat AJ, Parravicini G (2017) Liquid-solid directional composites and anisotropic dipolar phases of polar nanoregions in disordered perovskite. Nanoscale

    Google Scholar 

  51. Phelan D, Stock C, Rodriguez-Rivera JA, Chi S, Leão J, Long X, Xie Y, Bokov AA, Ye Z-G, Ganesh P et al (2014) Role of random electric fields in relaxors. Proc Natl Acad Sci 111(5):1754–1759

    Article  ADS  Google Scholar 

  52. Pierangeli D, Di Mei F, Parravicini J, Parravicini GB, Agranat AJ, Conti C, DelRe E (2014) Observation of an intrinsic nonlinearity in the electro-optic response of freezing relaxors ferroelectrics. Opt Mater Express 4(8):1487–1493

    Article  ADS  Google Scholar 

  53. Pierangeli D, Di Mei F, Conti C, Agranat AJ, DelRe E (2015) Spatial rogue waves in photorefractive ferroelectrics. Phys Rev Lett 115(9):093901

    Google Scholar 

  54. Pierangeli D, Flammini M, Di Mei F, Parravicini J, de Oliveira CEM, Agranat AJ, DelRe E (2015) Continuous solitons in a lattice nonlinearity. Phys Rev Lett 114(20):203901

    Article  ADS  MathSciNet  Google Scholar 

  55. Pierangeli D, Di Mei F, Di Domenico G, Agranat AJ, Conti C, DelRe E (2016a) Turbulent transitions in optical wave propagation. Phys Rev Lett 117(18):183902

    Article  ADS  Google Scholar 

  56. Pierangeli D, Ferraro M, Di Mei F, Di Domenico G, de Oliveira CEM, Agranat AJ, DelRe E (2016) Spontaneous photonic super-crystals in composite ferroelectrics. In: 2016 conference on lasers and electro-optics (CLEO). IEEE, pp 1–2

    Google Scholar 

  57. Pirc R, Kutnjak Z (2014) Electric-field dependent freezing in relaxor ferroelectrics. Phys Rev B 89(18):184110

    Article  ADS  Google Scholar 

  58. Pirc R, Blinc R (2007) Vogel-fulcher freezing in relaxor ferroelectrics. Phys Rev B 76(2):020101

    Article  ADS  Google Scholar 

  59. Plum E, Liu X-X, Fedotov VA, Chen Y, Tsai DP, Zheludev NI (2009) Metamaterials: optical activity without chirality. Phys Rev Lett 102(11):113902

    Article  ADS  Google Scholar 

  60. Potter BG Jr, Tikare V, Tuttle BA (2000) Monte carlo simulation of ferroelectric domain structure and applied field response in two dimensions. J Appl Phys 87(9):4415–4424

    Article  ADS  Google Scholar 

  61. Prosandeev S, Dawei Wang AR, Akbarzadeh BD, Bellaiche L (2013) Field-induced percolation of polar nanoregions in relaxor ferroelectrics. Phys Rev Lett 110(20):207601

    Article  ADS  Google Scholar 

  62. Pugachev AM, Kovalevskii VI, Surovtsev NV, Kojima S, Prosandeev SA, Raevski IP, Raevskaya SI (2012) Broken local symmetry in paraelectric batio 3 proved by second harmonic generation. Phys Rev Lett 108(24):247601

    Article  ADS  Google Scholar 

  63. Rabe KM, Ahn CH, Triscone J-M (2007) Physics of ferroelectrics: a modern perspective, vol 105. Springer Science & Business Media, Berlin

    Google Scholar 

  64. Ramachandran GN (1964) Advanced methods of crystallography. Academic Press Inc, New York

    Google Scholar 

  65. Ren M-X, Wei W, Cai W, Pi B, Zhang X-Z, Jing-Jun X (2017) Reconfigurable metasurfaces that enable light polarization control by light. Light Sci Appl 6(6)

    Article  Google Scholar 

  66. Roppo V, Wang W, Kalinowski K, Kong Y, Cojocaru C, Trull J, Vilaseca R, Scalora M, Krolikowski W, Kivshar Y (2010) The role of ferroelectric domain structure in second harmonic generation in random quadratic media. Opt Express 18(5):4012–4022

    Article  ADS  Google Scholar 

  67. Sakamoto T, Sasaura M, Yagi S, Fujiura K, Cho Y (2008) In-plane distribution of phase transition temperature of kta1-xnbxo3 measured with single temperature sweep. Appl Phys Express 1(10):101601

    Article  ADS  Google Scholar 

  68. Shevchenko A, Roussey M, Friberg AT, Setälä T (2017) Polarization time of unpolarized light. Optica 4(1):64–70

    Google Scholar 

  69. Shvartsman VV, Lupascu DC (2012) Lead-free relaxor ferroelectrics. J Am Ceram Soc 95(1):1–26

    Article  Google Scholar 

  70. Takagi M, Ishidate T (2000) Anomalous birefringence of cubic batio 3. Solid State Commun 113(7):423–426

    Article  ADS  Google Scholar 

  71. Tan P, Tian H, Chengpeng H, Meng X, Mao C, Huang F, Shi G, Zhou Z (2016) Temperature field driven polar nanoregions in kta1- x nb x o3. Appl Phys Lett 109(25):252904

    Article  ADS  Google Scholar 

  72. Tan P, Tian H, Mao C, Chengpeng H, Meng X, Li L, Shi G, Zhou Z (2017) Field-driven electro-optic dynamics of polar nanoregions in nanodisordered kta1- x nb x o3 crystal. Appl Phys Lett 111(1):012903

    Article  ADS  Google Scholar 

  73. Tian H, Yao B, Hu C, Meng X, Zhou Z (2014) Impact of polar nanoregions on the quadratic electro-optic effect in k0. 95na0. 05ta1- xnbxo3 crystals near the curie temperature. Appl Phys Express 7(6):062601

    Article  ADS  Google Scholar 

  74. Tian H, Tan P, Meng X, Chengpeng H, Yao B, Shi G, Zhou Z (2015) Variable gradient refractive index engineering: design, growth and electro-deflective application of kta 1–x nb x o 3. J Mater Chem C 3(42):10968–10973

    Article  Google Scholar 

  75. Tian H, Yao B, Tan P, Zhou Z, Shi G, Gong D, Zhang R (2015) Double-loop hysteresis in tetragonal kta0. 58nb0. 42o3 correlated to recoverable reorientations of the asymmetric polar domains. Appl Phys Lett 106(10):102903

    Article  ADS  Google Scholar 

  76. Tian H, Yao B, Wang L, Tan P, Meng X, Shi G, Zhou Z (2015) Dynamic response of polar nanoregions under an electric field in a paraelectric kta0. 61nb0. 39o3 single crystal near the para-ferroelectric phase boundary. Sci Rep 5:13751

    Google Scholar 

  77. Toulouse J, DiAntonio P, Vugmeister BE, Wang XM, Knauss LA (1992) Precursor effects and ferroelectric macroregions in kta 1–x nb x o 3 and k 1- y li y tao 3. Phys Rev Lett 68(2):232

    Article  ADS  Google Scholar 

  78. Trull J, Cojocaru C, Fischer R, Saltiel SM, Staliunas K, Herrero R, Vilaseca R, Neshev DN, Krolikowski W, Kivshar YS (2007) Second-harmonic parametric scattering in ferroelectric crystals with disordered nonlinear domain structures. Opt Express 15(24):15868–15877

    Article  ADS  Google Scholar 

  79. Wang L, Tian H, Meng X, Chen H, Zhou Z, Shen Y (2014) Field-induced enhancement of voltage-controlled diffractive properties in paraelectric iron and manganese co-doped potassium-tantalate-niobate crystal. Appl Phys Express 7(11):112601

    Article  ADS  Google Scholar 

  80. Weber MF, Stover CA, Gilbert LR, Nevitt TJ, Ouderkirk AJ (2000) Giant birefringent optics in multilayer polymer mirrors. Science 287(5462):2451–2456

    Article  ADS  Google Scholar 

  81. Wemple SH, DiDomenico M Jr (1969) Oxygen-octahedra ferroelectrics. ii. Electro-optical and nonlinear-optical device applications. J Appl Phys 40(2):735–752

    Article  ADS  Google Scholar 

  82. Westphal V, Kleemann W, Glinchuk MD (1992) Diffuse phase transitions and random-field-induced domain states of the “relaxor” ferroelectric pbmg 1/3 nb 2/3 o 3. Phys Rev Lett 68(6):847

    Article  ADS  Google Scholar 

  83. Guangyong X, Zhong Z, Bing Y, Ye Z-G, Shirane G (2006) Electric-field-induced redistribution of polar nano-regions in a relaxor ferroelectric. Nat Mater 5(2):134–140

    Article  ADS  Google Scholar 

  84. Yariv A, Yeh P (1984) Optical waves in crystals, vol 10. Wiley, New York

    Google Scholar 

  85. Zhu W, Chao J-H, Chen C-J, Yin S, Hoffman RC (2016) Three order increase in scanning speed of space charge-controlled KTN deflector by eliminating electric field induced phase transition in nanodisordered KTN. Sci Rep 6

    Google Scholar 

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Di Domenico, G. (2019). Super-Crystals in Composite Ferroelectrics. In: Electro-optic Photonic Circuits. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-030-23189-7_7

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