Abstract
Symmetries and symmetry transformations in quantum systems are considered. Rotation operators, Rotation Matrices and general rotations expressed in terms of the Euler angles are analyzed. Tensor operators are introduced and the Wigner-Eckart theorem is established. Spatial and temporal translations are considered. Spatial Reflection (Parity) and Time-Reversal are studied as examples of Discrete Transformations. Dynamical Symmetries are discussed and the example of the Runge-Lenz vector in the Hydrogen atom is analyzed.
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Notes
- 1.
An antilinear operator is defined by the property \(\mathcal{{Q}}c\,=\,c^*\mathcal{{Q}}\) for any complex number c. This is in contrast to linear operators which commute with complex numbers.
- 2.
Since \(\mathcal{{R}}\) is orthogonal, the Jacobian of the transformation is unity (\(\det \mathcal{{R}}=1\)) and \(d^3r'=d^3r\).
- 3.
Note that
$$\mathcal{{R}}\,\approx \,1\,+\,\left( \begin{array}{ccc} 0\,&{}\,-\alpha \,&{}\,0\\ \alpha \,&{}\,0\,&{}\,0\\ 0\,&{}\,0\,&{}\,0 \end{array}\right) \,\,\Longrightarrow \,\,\,\mathcal{{R}}_{ij}\,=\,\delta _{ij}-\alpha _k\,\epsilon _{ijk}\,+\,O(\alpha ^2) .$$ - 4.
Nevertheless \(\left( \hat{R}(2\pi )\right) ^2=\hat{R}(4\pi )=\mathbf{{ I}}\), meaning that the rotation by \(4\pi \) must be the unit operator.
- 5.
See any of the standard Mathematical Methods textbooks, e.g., Mathews and Walker [3].
- 6.
Nevertheless, rotations around the same axis are commutative.
- 7.
The relation of the rotation operator to the rotation matrix was introduced through \(\langle \mathcal{{R}}_1\left\{ \mathbf{{ r}}\right\} |\hat{R}_1|\psi \rangle \,=\,\langle \mathbf{{ r}}_1|\psi _1\rangle \,=\,\langle \mathbf{{ r}}|\psi \rangle \). Obviously, we have \(\langle \mathcal{{R}}_2\mathcal{{R}}_1\left\{ \mathbf{{ r}}\right\} |\hat{R}_2\hat{R}_1|\psi \rangle \,=\,\langle \mathbf{{ r}}|\psi \rangle \). Thus, the product \(\hat{R}_2\hat{R}_1\) will be the rotation operator corresponding to the rotation matrix \(\mathcal{{R}}_2\mathcal{{R}}_1\). The product operator is unitary, since \(\hat{R}_2\hat{R}_1\left( \hat{R}_2\hat{R}_1\right) ^{\dagger }\,=\,\hat{R}_2\hat{R}_1\hat{R}_1^{\dagger }\hat{R}_2^{\dagger }\,=\,\mathbf{{I}}\).
- 8.
Note that \(d^{(j)}(-\mathbf{{ a}})=\left( d^{(j)}(\mathbf{{ a}})\right) ^{\dagger }\).
- 9.
For an antilinear operator, we have \(\hat{C}i\,=\,-i\hat{C}\).
- 10.
Compare this to Hermitian conjugation for a linear operator \(\langle \psi _1|\hat{L}^{\dagger }|\psi _2\rangle \,=\,\langle \psi _2|\hat{L}|\psi _1\rangle ^*\).
- 11.
\(e^{-\frac{i}{\hbar }\pi \hat{S}_y}\,=\,e^{-i\pi \sigma _2/2}\,=\,\cos (\pi /2)-i\sigma _2\sin (\pi /2)=-i\sigma _2\).
References
G. Baym, Lectures in Quantum Mechanics. Lecture Notes and Supplements in Physics (ABP, 1969)
W. Greiner, B. Müller, Quantum Mechanics Symmetries, 2nd edn. (Springer, Berlin, 1992)
J. Mathews, R. Walker, Mathematical Methods of Physics, 2nd edn. (Pearson, London, 1970)
E. Merzbacher, Quantum Mechanics, 3rd edn. (Wiley, Hoboken, 1998)
A. Messiah, Quantum Mechanics (Dover publications, Mineola, 1958). Single-volume reprint of the Wiley, New York, two-volume 1958 edn
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Problems and Exercises
Problems and Exercises
19.1
If \(\psi (\mathbf{{ r}},t)\) is the wave function of a particle, show that the wave function \(\psi ^*(\mathbf{{r}}, -t)\) describes a particle having the opposite momentum.
19.2
A particle of spin \(s=1\) is described by the Hamiltonian
with \(a,\,b\) real parameters. Is the energy invariant under time reversal? How do the energy eigenstates change under a time reversal?
19.3
Consider the three-dimensional isotropic harmonic oscillator. Prove that the angular momentum \(\mathbf{{ L}}\) and the tensor operators \(\hat{Q}_{ij}\,=\,m\omega \left( x_ix_j-\frac{1}{3}\delta _{ij}r^2\right) \,+\,\frac{1}{m\omega }\left( \hat{p}_i\hat{p}_j-\frac{1}{3}\delta _{ij}\hat{p}^2\right) \) satisfy the relation
19.4
Show that, if the Hamiltonian of a system is time reversal invariant, we can always choose the wave function to be real. How is this compatible with the fact that at some particular time the wave function of a free particle can be a plane wave \(e^{i\mathbf{{ k}}\cdot \mathbf{{ r}}}\)?
19.5
A system consists of two particles of the same mass interacting through a potential \(V(|\mathbf{{ r}}_1-\mathbf{{ r}}_2|)\). Discuss the rotational properties of the system and the associated conserved quantities.
19.6
Let \(\alpha ,\,\beta ,\,\gamma \) be the Euler angles. If \(U\,=\,e^{-i\alpha X_1}\,e^{-i\beta X_2}\,e^{-i\gamma X_3}\) is to represent a rotation, find the commutation relations that have to be satisfied by the \(X_1,\,X_2,\,X_3\). Relate them to angular momentum.
19.7
Consider the Galilean Transformations \(\hat{G}\,=\,e^{\frac{i}{\hbar }{} \mathbf{{V}}\cdot \mathbf{{ K}}}\), where their generator is \(\mathbf{{ K}}=m\mathbf{{ r}}-t\mathbf{{ p}}\). Show that \(\mathbf{{ K}}\) is a vector operator.
19.8
Consider a sequence of Euler rotations represented by
Show that this is equivalent to a single rotation around an axis by an angle \(\theta \). Find \(\theta \).
19.9
Consider the simple harmonic oscillator. Show that spatial reflection (parity) can be represented by the operator \(-ie^{i\frac{\pi \hat{H}}{\hbar \omega }}\), where \(\hat{H}\) is the Hamiltonian.
19.10
For the parity operator \(\hat{P}_{\hat{n}}\,=\,\hat{P}\,e^{-\frac{i}{\hbar }\pi \hat{n}\cdot \mathbf{{ J}}}\) prove the following:
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Tamvakis, K. (2019). Symmetries. In: Basic Quantum Mechanics. Undergraduate Texts in Physics. Springer, Cham. https://doi.org/10.1007/978-3-030-22777-7_19
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DOI: https://doi.org/10.1007/978-3-030-22777-7_19
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