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Electron Structure and Optical Properties of Conjugated Systems in Solutions

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Modern Problems of the Physics of Liquid Systems (PLMMP 2018)

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 223))

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Abstract

The review deals with the special type of the organic molecules which contain the collective system of π-electrons; the mobility of the electrons that determines both the electron structure and spectral properties of considered conjugated molecules. The classification of the linear conjugated systems is proposed: polymethine dyes, polyenes, donor-acceptor compounds and the differences between them. It is shown that the high mobility of the collective π-electron shell depends on the type of the conjugated system, chain length, symmetry, molecular constitution of the terminal groups, as well as the electron shell (neutral or charge system). Experimentally, the features of the electron structure of conjugated molecules are observed by spectral methods, especially, in various solvents. It is established that different molecular types show the different sensitivity to the solvent polarity. The work reviews principal results that were obtained by the quantum-chemical and spectral study of the linear conjugated systems.

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Acknowledgements

Figures 9.2, 9.4 and 9.3, Table 9.1 are reprinted from: [8, 81]; Table 9.6 is reprinted from A.D. Kachkovsky, N.V. Pilipchuk, V.V. Kurdyukov, A.I. Tolmachev, Yu.L. Slominskii, V.Ya. Gayvoronsky, E.V. Shepelyavyy, S.V. Yakunin, M.S. Brodyn, Spectral and non-linear optical properties of cyanine bases’ derivatives of benzo[c, d]indole, Dyes Pigments 74, 195–201 (2007) https://doi.org/10.1016/j.dyepig.2006.01.048, respectively with permission from Elsevier.

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Authors and Affiliations

  1. Faculty of Physics, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    O. L. Pavlenko, O. P. Dmytrenko, M. P. Kulish, V. A. Sendiuk & Leonid A. Bulavin

  2. Department of Bioorganic and Biological Chemistry, Bogomolets National Medical University, Kyiv, Ukraine

    N. V. Obernikhina

  3. Institute of Bioorganic Chemistry and Petrochemistry, NAS of Ukraine, Kyiv, Ukraine

    Ya. O. Prostota & O. D. Kachkovsky

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  1. O. L. Pavlenko
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  2. O. P. Dmytrenko
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  8. Leonid A. Bulavin
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Correspondence to O. L. Pavlenko .

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  1. National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid A. Bulavin

  2. International Center for Quantum Materials and School of Physics, Peking University, Beijing, China

    Limei Xu

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Pavlenko, O.L. et al. (2019). Electron Structure and Optical Properties of Conjugated Systems in Solutions. In: Bulavin, L., Xu, L. (eds) Modern Problems of the Physics of Liquid Systems. PLMMP 2018. Springer Proceedings in Physics, vol 223. Springer, Cham. https://doi.org/10.1007/978-3-030-21755-6_9

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