Skip to main content

Photocatalytic Degradation of Tetracycline Using C/TiO2 Composites Synthesized via Different Hydrothermal Methods

  • Conference paper
  • First Online:
  • 458 Accesses

Abstract

Composite materials consisting of pine cone-derived-carbon and TiO2 were prepared by three different hydrothermal methods [microwave (CT-MW), autoclave (CT-AC), and reflux (CT-R)] and by physical mixing (CT-PM). The purpose of preparing these materials was to evaluate their photocatalytic performance in tetracycline hydrochloride degradation under visible-LED light. The photocatalytic performance of the materials based on their apparent rate constant (Kapp) was in a decreasing order of CT-MW > CT-AC > CT-R > CT-PM. The Kapp of the materials was observed to be inversely proportional to their electron-hole recombination rate. The composite material prepared by microwave method (CT-MW) apart from its photocatalytic performance, is also more economical, based on the time and simplicity of its preparation.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. Hassani A, Khataee A, Karaca S (2015) Photocatalytic degradation of ciprofloxacin by synthesized TiO2 nanoparticles on montmorillonite: effect of operation parameters and artificial neural network modeling. J Mol Catal A Chem 409:149–161

    Article  CAS  Google Scholar 

  2. Santos LHMLM, Araújo AN, Fachini A, Pena A, Delerue-Matos C, Montenegro MCBSM (2010) Ecotoxicological aspects related to the presence of pharmaceuticals in the aquatic environment. J Hazard Mater 175:45–95

    Article  CAS  PubMed  Google Scholar 

  3. Ekpeghere KI, Lee JW, Kim HY, Shin SK, Oh JE (2017) Determination and characterization of pharmaceuticals in sludge from municipal and livestock wastewater treatment plants. Chemosphere 168:1211–1221

    Article  CAS  PubMed  Google Scholar 

  4. Ye Z, Weinberg HS, Meyer MT (2007) Trace analysis of trimethoprim and sulfonamide, macrolide, quinolone, and tetracycline antibiotics in chlorinated drinking water using liquid chromatography electrospray tandem mass spectrometry. Anal Chem 79:1135–1144

    Article  CAS  PubMed  Google Scholar 

  5. Fathinia M, Khataee K, Naseri A, Aber S (2015) Monitoring simultaneous photocatalytic-ozonation of mixture of pharmaceuticals in the presence of immobilized TiO2 nanoparticles using MCR-ALS: identification of intermediates and multi-response optimization approach. Spectrochim Acta A Mol Biomol Spectrosc 136:1275–1290

    Article  CAS  PubMed  Google Scholar 

  6. Liang R, Luo S, Jing F, Shen L, Qin N, Wu L (2015) A simple strategy for fabrication of Pd@MIL-100(Fe) nanocomposite as a visible-light-driven photocatalyst for the treatment of pharmaceuticals and personal care products (PPCPs). Appl Catal B176–177:240–248

    Article  Google Scholar 

  7. Martín J, Santos JL, Aparicio I, Alonso E (2015) Pharmaceutically active compounds in sludge stabilization treatments: anaerobic and aerobic digestion, wastewater stabilization ponds and composting. Sci Total Environ 503–504:97–104

    Article  PubMed  Google Scholar 

  8. Xu Y, Guo C, Luo Y, Lv J, Zhang Y, Lin H, Wang L, Xu J (2016) Occurrence and distribution of antibiotics, antibiotic resistance genes in the urban rivers in Beijing, China. Environ Pollut 213:833–840

    Article  CAS  PubMed  Google Scholar 

  9. Zhou Y, Yang Q, Zhang D, Gan N, Li Q, Cuan J (2018) Detection and removal of antibiotic tetracycline in water with a highly stable luminescent MOF. Sens Actuators B Chem 262:137–143

    Article  CAS  Google Scholar 

  10. Fujishima A, Zhang X, Tryk DA (2008) TiO2 photocatalysis and related surface phenomena. Surf Sci Rep 63:515–582

    Article  CAS  Google Scholar 

  11. Daghrir R, Drogui P, Robert D (2013) Modified TiO2 for environmental photocatalytic applications: a review. Ind Eng Chem Res 52:3581–3599

    Article  CAS  Google Scholar 

  12. Oseghe EO, Ndungu PG, Jonnalagadda SB (2015) Synthesis of mesoporous Mn/TiO2 nanocomposites and investigating the photocatalytic properties in aqueous systems. Environ Sci Pollut Res 22:211–222

    Article  CAS  Google Scholar 

  13. Huang WC, Ting JM (2017) Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response. Ceram Int 43:9992–9997

    Article  CAS  Google Scholar 

  14. Bello A, Manyala N, Barzegar F, Khaleed AA, Momodu DY, Dangbegnon JK (2016) Renewable pine cone biomass derived carbon materials for supercapacitor application. RSC Adv 6:1800–1809

    Article  CAS  Google Scholar 

  15. Rangel-Mendez JR, Matos J, Cházaro-Ruiz LF, González-Castillo AC, Barrios-Yáñez G (2018) Microwave-assisted synthesis of C-doped TiO2 and ZnO hybrid nanostructured materials as quantum-dots sensitized solar cells. Appl Surf Sci 434:744–755

    Article  CAS  Google Scholar 

  16. Saud PS, Pant B, Alam AM, Ghouri ZK, Park M, Kim HY (2015) Carbon quantum dots anchored TiO2 nanofibers: Effective photocatalyst for waste water treatment. Ceram Int 41:11953–11959

    Article  CAS  Google Scholar 

  17. Mu S, Long Y, Kang SZ, Mu J (2010) Surface modification of TiO2 nanoparticles with a C60 derivative and enhanced photocatalytic activity for the reduction of aqueous Cr(VI) ions. Catal Commun 11:741–744

    Article  CAS  Google Scholar 

  18. Cheng G, Xu F, Xiong J, Tian F, Ding J, Stadler FJ, Chen R (2016) Enhanced adsorption and photocatalysis capability of generally synthesized TiO2-carbon materials hybrids. Adv Powder Technol 27:1949–1962

    Article  CAS  Google Scholar 

  19. Spurr RA, Myers H (1957) Quantitative analysis of anatase-rutile mixtures with an X-ray diffractometer. Anal Chem 29:760–762

    Article  CAS  Google Scholar 

  20. Fagan R, McCormack DE, Hinder S, Pillai SC (2016) Improved high temperature stability of anatase TiO2 photocatalysts by N, F, P co-doping. Mater Des 96:44–53

    Article  CAS  Google Scholar 

  21. Zhang J, Zhang X, Dong S, Zhou X, Dong S (2016) N-doped carbon quantum dots/TiO2 hybrid composites with enhanced visible light driven photocatalytic activity toward dye wastewater degradation and mechanism insight. J Photochem Photobiol A 325:104–110

    Article  CAS  Google Scholar 

  22. Akhavan O, Ghaderi E (2009) Photocatalytic reduction of graphene oxide nanosheets on TiO2 thin film for photoinactivation of bacteria in solar light irradiation. J Phys Chem C 113:20214–20220

    Article  CAS  Google Scholar 

  23. Cong Y, Li X, Qin Y, Dong Z, Yuan G, Cui Z, Lai X (2011) Carbon-doped TiO2 coating on multiwalled carbon nanotubes with higher visible light photocatalytic activity. Appl Catal B 107:128–134

    Article  CAS  Google Scholar 

  24. Li S, Cai J, Wu X, Zheng F, Lin X, Liang W, Chen J, Zheng J, Lai Z, Chen T et al (2014) Fabrication of positively and negatively charged, double-shelled, nanostructured hollow spheres for photodegradation of cationic and anionic aromatic pollutants under sunlight irradiation. Appl Catal B160:279–285

    Article  Google Scholar 

  25. Teng F, Zhang G, Wang Y, Gao C, Chen L, Zhang P, Zhang Z, Xie E (2014) The role of carbon in the photocatalytic reaction of carbon/TiO2 photocatalysts. Appl Surf Sci 320:703–709

    Article  CAS  Google Scholar 

  26. Haroune L, Salaun M, Ménard A, Legault CY, Bellenger JP (2014) Photocatalytic degradation of carbamazepine and three derivatives using TiO2 and ZnO: effect of pH, ionic strength, and natural organic matter. Sci Total Environ 475:16–22

    Article  CAS  PubMed  Google Scholar 

  27. Parayil SK, Kibombo HS, Wu CM, Peng R, Baltrusaitis J, Koodali RT (2012) Enhanced photocatalytic water splitting activity of carbon-modified TiO2 composite materials synthesized by a green synthetic approach. Int J Hydrogen Energy 37:8257–8267

    Article  CAS  Google Scholar 

  28. Parayil SK, Kibombo HS, Koodali RT (2013) Naphthalene derivatized TiO2–carbon hybrid materials for efficient photocatalytic splitting of water. Catal Today 199:8–14

    Article  CAS  Google Scholar 

  29. Shao P, Tian J, Zhao Z, Shi W, Gao S, Cui F (2015) Amorphous TiO2 doped with carbon for visible light photodegradation of rhodamine B and 4-chlorophenol. Appl Surf Sci 324:35–43

    Article  CAS  Google Scholar 

  30. Zhao C, Li W, Liang Y, Tian Y, Zhang Q (2016) Synthesis of BiOBr/carbon quantum dots microspheres with enhanced photoactivity and photostability under visible light irradiation. Appl Catal A 527:127–136

    Article  CAS  Google Scholar 

  31. Tripathi AK, Singh MK, Mathpal MC, Mishra SK, Agarwal A (2013) Study of structural transformation in TiO2 nanoparticles and its optical properties. J Alloys Compd 549:114–120

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors thank the Department of Chemistry, Research Directorate of Vaal University of Technology, and the Nanotechnology and Water Sustainability (NanoWS) research unit of University of South Africa for the support provided.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ekemena O. Oseghe .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Oseghe, E.O., Msagati, T.A.M., Ofomaja, A.E. (2019). Photocatalytic Degradation of Tetracycline Using C/TiO2 Composites Synthesized via Different Hydrothermal Methods. In: Ramasami, P., Gupta Bhowon, M., Jhaumeer Laulloo, S., Li Kam Wah, H. (eds) Chemistry for a Clean and Healthy Planet. ICPAC 2018. Springer, Cham. https://doi.org/10.1007/978-3-030-20283-5_28

Download citation

Publish with us

Policies and ethics