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2D Metal Carbides and Nitrides (MXenes) pp 349–365Cite as

MXenes for Supercapacitor Application

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Abstract

Being one of the key applications of MXenes, MXene-based supercapacitors attracted huge attention for their superior electrochemical performance. In this section, an overview of MXenes as supercapacitor electrodes in various electrolytes is discussed as well as strategies for improving their performance. In aqueous electrolytes, MXenes exhibit capacitive behavior in neutral and alkaline electrolytes, while a pseudocapacitive behavior was observed in acidic electrolytes, resulting in ultrahigh capacitance values up to 370 F g−1 (1500 F cm−3). Studies were extended to nonaqueous electrolytes to achieve large voltage windows (up to 3 V), but were limited by low capacitance values. The effects of surface chemistry on energy storage in MXenes are also discussed. In addition, composite MXene electrodes have been developed to increase the electrical conductivity, the mechanical robustness, or surface accessibility of MXenes. Lastly, MXene-based supercapacitor devices including hybrid, all-solid-state, and micro-supercapacitors are introduced.

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Notes

  1. 1.

    Ethyl-methyl-imidazole, tri-fluoro-sulfonyl-imide

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Authors and Affiliations

  1. College of Materials Science and Engineering, Sichuan University, Chengdu, China

    Zifeng Lin

  2. CIRIMAT, Université de Toulouse, CNRS, INPT, UPS, Toulouse, France

    Patrice Simon

  3. Reseau sur le Stockage Electrochimique de l’Energie (RS2E), FR CNRS 3459, Amiens, France

    Patrice Simon

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  1. Zifeng Lin
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Correspondence to Zifeng Lin or Patrice Simon .

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Editors and Affiliations

  1. Department of Mechanical and Energy Engineering, Purdue School of Engineering and Technology, Indiana University-Purdue University, Indianapolis (IUPUI), Indianapolis, IN, USA

    Babak Anasori

  2. Department of Materials Science and Engineering and A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, PA, USA

    Yury Gogotsi

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Lin, Z., Simon, P. (2019). MXenes for Supercapacitor Application. In: Anasori, B., Gogotsi, Y. (eds) 2D Metal Carbides and Nitrides (MXenes). Springer, Cham. https://doi.org/10.1007/978-3-030-19026-2_18

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