Abstract
In the past decade, two-dimensional (2D) materials have had a significant impact on the physics and optics research community as they are observed to interact with light in a large variety of unique ways. MXenes have been added to this class of 2D in 2011. Ever since their discovery, they have been explored by a growing number of different fields of research, including optics and nanophotonics. In relation to optics, in the past few years, researchers have demonstrated a number of widely useful and interesting features of the MXenes, for example, optical transparency, plasmonic behavior, optical nonlinearity, efficient photothermal conversion, tunability of optical response, etc. These have led to application of the MXenes in functional metamaterial devices, mode-locked lasers, surface-enhanced Raman spectroscopy (SERS), photothermal therapy (PTT), and so on. In this chapter, we start by reviewing the theoretical and experimental approaches in studying the optical properties of the MXenes and then discuss the impactful optical device demonstrations.
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References
Novoselov, K. S., Jiang, D., Schedin, F., Booth, T. J., Khotkevich, V. V., Morozov, S. V., & Geim, A. K. (2005). Two-dimensional atomic crystals. Proceedings of the National Academy of Sciences of the United States of America, 102(30), 10451–10453.
Manzeli, S., Ovchinnikov, D., Pasquier, D., Yazyev, O. V., & Kis, A. (2017). 2D transition metal dichalcogenides. Nature Reviews Materials, 2(8), 17033.
Xia, F., Wang, H., & Jia, Y. (2014). Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. Nature Communications, 5, 4458.
Koppens, F. H. L., Chang, D. E., & GarcÃa de Abajo, F. J. (2011). Graphene plasmonics: A platform for strong light-matter interactions. Nano Letters, 11(8), 3370–3377.
Fiori, G., Bonaccorso, F., Iannaccone, G., Palacios, T., Neumaier, D., Seabaugh, A., Banerjee, S. K., & Colombo, L. (2014). Electronics based on two-dimensional materials. Nature Nanotechnology, 9(10), 768–779.
Xia, F., Wang, H., Xiao, D., Dubey, M., & Ramasubramaniam, A. (2014). Two-dimensional material nanophotonics. Nature Photonics, 8(12), 899–907.
Geim, A. K., & Novoselov, K. S. (2007). The rise of graphene. Nature Materials, 6(3), 183–191.
Wallace, P. R. (1947). The band theory of graphite. Physics Review, 71(9), 622–634.
Fei, Z., Rodin, A. S., Andreev, G. O., Bao, W., McLeod, A. S., Wagner, M., Zhang, L. M., Zhao, Z., Thiemens, M., Dominguez, G., et al. (2012). Gate-tuning of graphene plasmons revealed by infrared nano-imaging. Nature, 487(7405), 82–85.
Pirruccio, G., MartÃn Moreno, L., Lozano, G., & Gómez Rivas, J. (2013). Coherent and broadband enhanced optical absorption in graphene. ACS Nano, 7(6), 4810–4817.
Sun, Z., Hasan, T., Torrisi, F., Popa, D., Privitera, G., Wang, F., Bonaccorso, F., Basko, D. M., & Ferrari, A. C. (2010). Graphene mode-locked ultrafast laser. ACS Nano, 4(2), 803–810.
Kim, Y. D., Kim, H., Cho, Y., Ryoo, J. H., Park, C.-H., Kim, P., Kim, Y. S., Lee, S., Li, Y., Park, S.-N., et al. (2015). Bright visible light emission from graphene. Nature Nanotechnology, 10(8), 676–681.
Lui, C. H., Mak, K. F., Shan, J., & Heinz, T. F. (2010). Ultrafast photoluminescence from graphene. Physical Review Letters, 105(12), 127404.
Nair, R. R., Blake, P., Grigorenko, A. N., Novoselov, K. S., Booth, T. J., Stauber, T., Peres, N. M. R., & Geim, A. K. (2008). Fine structure constant defines visual transparency of graphene. Science, 320(5881), 1308–1308.
Blake, P., Hill, E. W., Castro Neto, A. H., Novoselov, K. S., Jiang, D., Yang, R., Booth, T. J., & Geim, A. K. (2007). Making graphene visible. Applied Physics Letters, 91(6), 63124.
Xiao, D., Liu, G.-B., Feng, W., Xu, X., & Yao, W. (2012). Coupled spin and valley physics in monolayers of MoS2 and other group-VI dichalcogenides. Physical Review Letters, 108(19), 196802.
Yu, H., Liu, G.-B., Gong, P., Xu, X., & Yao, W. (2014). Dirac cones and Dirac saddle points of bright excitons in monolayer transition metal dichalcogenides. Nature Communications, 5(May), 3876.
Berkelbach, T. C., Hybertsen, M. S., & Reichman, D. R. (2013). Theory of neutral and charged excitons in monolayer transition metal dichalcogenides. Physical Review B, 88(4), 45318.
Rodin, A. S., Carvalho, A., & Castro Neto, A. H. (2014). Excitons in anisotropic two-dimensional semiconducting crystals. Physical Review B, 90(7), 1–7.
Mak, K. F., He, K., Shan, J., & Heinz, T. F. (2012). Control of valley polarization in monolayer MoS2 by optical helicity. Nature Nanotechnology, 7(8), 494–498.
Clark, D. J., Senthilkumar, V., Le, C. T., Weerawarne, D. L., Shim, B., Jang, J. I., Shim, J. H., Cho, J., Sim, Y., Seong, M.-J., et al. (2014). Strong optical nonlinearity of CVD-grown MoS2 monolayer as probed by wavelength-dependent second-harmonic generation. Physical Review B, 90(12), 121409.
Wang, R., Chien, H. C., Kumar, J., Kumar, N., Chiu, H. Y., & Zhao, H. (2014). Third-harmonic generation in ultrathin films of MoS2. ACS Applied Materials & Interfaces, 6, 314–318.
Zhang, H., Lu, S. B., Zheng, J., Du, J., Wen, S. C., Tang, D. Y., & Loh, K. P. (2014). Molybdenum disulfide (MoS2) as a broadband saturable absorber for ultra-fast photonics. Optics Express, 22(6), 7249.
Lagoudakis, K. G., Wouters, M., Richard, M., Baas, A., Carusotto, I., André, R., Dang, L. S., & Deveaud-Plédran, B. (2008). Quantized vortices in an exciton–polariton condensate. Nature Physics, 4(9), 706–710.
Ye, Y., Wong, Z. J., Lu, X., Ni, X., Zhu, H., Chen, X., Wang, Y., & Zhang, X. (2015). Monolayer excitonic laser. Nature Photonics, 9(11), 733–737.
Ye, Y., Dou, X., Ding, K., Chen, Y., Jiang, D., Yang, F., & Sun, B. (2017). Single photon emission from deep-level defects in monolayer WSe2. Physical Review B, 95(24), 245313.
Ling, X., Wang, H., Huang, S., Xia, F., & Dresselhaus, M. S. (2015). The renaissance of black phosphorus. Proceedings of the National Academy of Sciences, 112(15), 201416581.
Low, T., Rodin, A. S., Carvalho, A., Jiang, Y., Wang, H., Xia, F., & Neto, A. H. C. (2014). Tunable optical properties of multilayers black phosphorus. arXiv, 75434, 1–5.
Tran, V., Soklaski, R., Liang, Y., & Yang, L. (2014). Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Physical Review B, 89(23), 1–6.
Qiao, J., Kong, X., Hu, Z.-X., Yang, F., & Ji, W. (2014). High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus. Nature Communications, 5, 4475.
Mao, N., Tang, J., Xie, L., Wu, J., Han, B., Lin, J., Deng, S., Ji, W., Xu, H., Liu, K., et al. (2016). Optical anisotropy of black phosphorus in the visible regime. Journal of the American Chemical Society, 138(1), 300–305.
Luo, Z., Maassen, J., Deng, Y., Du, Y., Garrelts, R. P., Lundstrom, M. S., Ye, P. D., & Xu, X. (2015). Anisotropic in-plane thermal conductivity observed in few-layer black phosphorus. Nature Communications, 6(1), 1–32.
Low, T., Rold, R., Wang, H., Xia, F., Avouris, P., & Mart, L. (2014). Plasmons and screening in monolayer and multilayer black phosphorus. Physical Review Letters, 67(12), 3–7.
Chen, Y., Jiang, G., Chen, S., Guo, Z., Yu, X., Zhao, C., Zhang, H., Bao, Q., Wen, S., Tang, D., et al. (2015). Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation. Optics Express, 23(10), 12823.
Li, L., Wang, Y., & Wang, X. (2017). Ultrafast pulse generation with black phosphorus solution saturable absorber. Laser Physics, 27(8), 85104.
Sotor, J., Sobon, G., Macherzynski, W., Paletko, P., & Abramski, K. M. (2015). Black phosphorus saturable absorber for ultrashort pulse generation. Applied Physics Letters, 107(5), 51108.
Naguib, M. (2017). Chapter 4: Two-dimensional transition metal carbides and carbonitrides. In Y. Gogotsi (Ed.), Nanomaterials handbook (pp. 83–102). Boca Raton: Taylor & Francis, CRC Press.
Naguib, M., & Gogotsi, Y. (2015). Synthesis of two-dimensional materials by selective extraction. Accounts of Chemical Research, 48(1), 128–135.
Alhabeb, M., Maleski, K., Anasori, B., Lelyukh, P., Clark, L., Sin, S., & Gogotsi, Y. (2017). Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chemistry of Materials, 29(18), 7633–7644.
Halim, J., Lukatskaya, M. R., Cook, K. M., Lu, J., Smith, C. R., Näslund, L.-Å., May, S. J., Hultman, L., Gogotsi, Y., Eklund, P., et al. (2014). Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chemistry of Materials, 26(7), 2374–2381.
Kajiyama, S., Szabova, L., Sodeyama, K., Iinuma, H., Morita, R., Gotoh, K., Tateyama, Y., Okubo, M., & Yamada, A. (2016). Sodium-ion intercalation mechanism in MXene nanosheets. ACS Nano, 10(3), 3334–3341.
Lukatskaya, M. R., Kota, S., Lin, Z., Zhao, M.-Q., Shpigel, N., Levi, M. D., Halim, J., Taberna, P.-L., Barsoum, M. W., Simon, P., et al. (2017). Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nature Energy, 2(8), 17105.
Tian, Y., Yang, C., Que, W., Liu, X., Yin, X., & Kong, L. B. (2017). Flexible and free-standing 2D titanium carbide film decorated with manganese oxide nanoparticles as a high volumetric capacity electrode for supercapacitor. Journal of Power Sources, 359, 332–339.
Yang, C., Que, W., Yin, X., Tian, Y., Yang, Y., & Que, M. (2017). Improved capacitance of nitrogen-doped delaminated two-dimensional titanium carbide by urea-assisted synthesis. Electrochimica Acta, 225, 416–424.
Shahzad, F., Alhabeb, M., Hatter, C. B., Anasori, B., Man Hong, S., Koo, C. M., & Gogotsi, Y. (2016). Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science, 353(6304), 1137–1140.
Geunchang, C., Faisal, S., Young-Mi, B., Min, J. Y., Hyunchul, P., Mohamed, A., Babak, A., Dai-Sik, K., Min, K. C., Yury, G., et al. (2018). Enhanced terahertz shielding of MXenes with nano-metamaterials. Advanced Optical Materials, 6(5), 1701076.
Li, R., Zhang, L., Shi, L., & Wang, P. (2017). MXene Ti3C2 : An effective 2D light-to-heat conversion material. ACS Nano, 11(4), 3752–3759.
Jhon, Y. M. I., Koo, J., Anasori, B., Seo, M., Lee, J. H., Gogotsi, Y., & Jhon, Y. M. I. (2017). Metallic MXene saturable absorber for femtosecond mode-locked lasers. Advanced Materials, 29(40), 1702496.
Satheeshkumar, E., Makaryan, T., Melikyan, A., Minassian, H., Gogotsi, Y., & Yoshimura, M. (2016). One-step solution processing of Ag, Au and Pd@MXene hybrids for SERS. Scientific Reports, 6(1), 32049.
Sarycheva, A., Makaryan, T., Maleski, K., Satheeshkumar, E., Melikyan, A., Minassian, H., Yoshimura, M., & Gogotsi, Y. (2017). Two-dimensional titanium carbide (MXene) as surface-enhanced Raman scattering substrate. Journal of Physical Chemistry C, 121(36), 19983–19988.
Chaudhuri, K., Alhabeb, M., Wang, Z., Shalaev, V. M., Gogotsi, Y., & Boltasseva, A. (2018). Highly broadband absorber using plasmonic titanium carbide (MXene). ACS Photonics, 5(3), 1115–1122.
Dong, Y., Chertopalov, S., Maleski, K., Anasori, B., Hu, L., Bhattacharya, S., Rao, A. M., Gogotsi, Y., Mochalin, V. N., & Podila, R. (2018). Saturable absorption in 2D Ti3C2 MXene thin films for passive photonic diodes. Advanced Materials, 30(10), 1705714.
Khazaei, M., Ranjbar, A., Arai, M., Sasaki, T., & Yunoki, S. (2017). Electronic properties and applications of MXenes: A theoretical review. Journal of Materials Chemistry C, 5(10), 2488–2503.
Lashgari, H., Abolhassani, M. R., Boochani, A., Elahi, S. M., & Khodadadi, J. (2014). Electronic and optical properties of 2D graphene-like compounds titanium carbides and nitrides: DFT calculations. Solid State Communications, 195, 61–69.
Ambrosch-Draxl, C., & Sofo, J. O. (2006). Linear optical properties of solids within the full-potential linearized augmented planewave method. Computer Physics Communications, 175(1), 1–14.
Ren, X., Rinke, P., Joas, C., & Scheffler, M. (2012). Random-phase approximation and its applications in computational chemistry and materials science. Journal of Materials Science, 47(21), 7447–7471.
Fox, M. (2001). Optical properties of solids. Oxford: Oxford University Press.
Wooten, F. (1972). Optical properties of solids. New York/London: Academic Press.
Naguib, M., Mashtalir, O., Carle, J., Presser, V., Lu, J., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2012). Two-dimensional transition metal carbides. ACS Nano, 6(2), 1322–1331.
Zhang, X., Ma, Z., Zhao, X., Tang, Q., & Zhou, Z. (2015). Computational studies on structural and electronic properties of functionalized MXene monolayers and nanotubes. Journal of Materials Chemistry A, 3(9), 4960–4966.
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011). Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Advanced Materials, 23(37), 4248–4253.
Berdiyorov, G. R. (2016). Optical properties of functionalized Ti3C2Tx (T = F, O, OH) MXene: First-principles calculations. AIP Advances, 6(5), 55105.
Harrison, W. A. (1970). Solid state theory. New York: McGrawHill.
Dillon, A. D., Ghidiu, M. J., Krick, A. L., Griggs, J., May, S. J., Gogotsi, Y., Barsoum, M. W., & Fafarman, A. T. (2016). Highly conductive optical quality solution-processed films of 2D titanium carbide. Advanced Functional Materials, 26(23), 4162–4168.
Hantanasirisakul, K., Zhao, M.-Q., Urbankowski, P., Halim, J., Anasori, B., Kota, S., Ren, C. E., Barsoum, M. W., & Gogotsi, Y. (2016). Fabrication of Ti3C2Tx MXene transparent thin films with tunable optoelectronic properties. Advanced Electronic Materials, 2(6), 1600050.
Lin, H., Wang, X., Yu, L., Chen, Y., & Shi, J. (2017). Two-dimensional ultrathin MXene ceramic nanosheets for photothermal conversion. Nano Letters, 17(1), 384–391.
Lin, H., Wang, Y., Gao, S., Chen, Y., & Shi, J. (2018). Theranostic 2D tantalum carbide (MXene). Advanced Materials, 30(4), 1703284.
Jiang, X., Liu, S., Liang, W., Luo, S., He, Z., Ge, Y., Wang, H., Cao, R., Zhang, F., Wen, Q., et al. (2018). Broadband nonlinear photonics in few-layer MXene Ti3C2Tx (T = F, O, or OH). Laser & Photonics Reviews, 12(2), 1700229.
Maier, S. A. (2007). Plasmonics: Fundamentals and applications. Boston, MA: Springer.
Maier, S. a., & Atwater, H. a. (2005). Plasmonics: Localization and guiding of electromagnetic energy in metal/dielectric structures. Journal of Applied Physics, 98(1), 11101.
Mauchamp, V., Bugnet, M., Bellido, E. P., Botton, G. a., Moreau, P., Magne, D., Naguib, M., Cabioc’h, T., & Barsoum, M. W. (2014). Enhanced and tunable surface plasmons in two-dimensional Ti3C2 stacks: Electronic structure versus boundary effects. Physical Review B, 89(23), 235428.
Kumar, A., & Ahluwalia, P. K. K. (2012). Tunable dielectric response of transition metals dichalcogenides MX2 (M=Mo, W; X=S, Se, Te): Effect of quantum confinement. Physica B: Condensed Matter, 407(24), 4627–4634.
Boersch, H., Geiger, J., Imbusch, A., & Niedrig, N. (1966). High resolution investigation of the energy losses of 30 keV electrons in aluminum foils of various thicknesses. Physics Letters, 22(2), 146–147.
Rast, L., Sullivan, T. J., & Tewary, V. K. (2013). Stratified graphene/noble metal systems for low-loss plasmonics applications. Physical Review B, 87(4), 45428.
Kildishev, A. V., Boltasseva, A., & Shalaev, V. M. (2013). Planar photonics with metasurfaces. Science, 339(6125), 1232009–1232009.
Pors, A., Albrektsen, O., Radko, I. P., & Bozhevolnyi, S. I. (2013). Gap plasmon-based metasurfaces for total control of reflected light. Scientific Reports, 3, 2155.
Jung, J., Søndergaard, T., & Bozhevolnyi, S. I. (2009). Gap plasmon-polariton nanoresonators: Scattering enhancement and launching of surface plasmon polaritons. Physical Review B, 79(3), 35401.
Bozhevolnyi, S. I., & Søndergaard, T. (2007). General properties of slow-plasmon resonant nanostructures: Nano-antennas and resonators. Optics Express, 15(17), 10869–10877.
Boyd, R. W. (Ed.). (2008). Nonlinear optics (3rd ed.). Amsterdam/Boston: Academic Press.
Huang, X., Jain, P. K., El-Sayed, I. H., & El-Sayed, M. A. (2008). Plasmonic Photothermal Therapy (PPTT) using gold nanoparticles. Lasers in Medical Science, 23(3), 217–228.
Robinson, J. T., Tabakman, S. M., Liang, Y., Wang, H., Sanchez Casalongue, H., Vinh, D., & Dai, H. (2011). Ultrasmall reduced graphene oxide with high near-infrared absorbance for photothermal therapy. Journal of the American Chemical Society, 133(17), 6825–6831.
Akhavan, O., & Ghaderi, E. (2013). Graphene nanomesh promises extremely efficient in vivo photothermal therapy. Small, 9(21), 3593–3601.
Liu, T., Wang, C., Gu, X., Gong, H., Cheng, L., Shi, X., Feng, L., Sun, B., & Liu, Z. (2014). Drug delivery with PEGylated MoS2 nano-sheets for combined photothermal and chemotherapy of cancer. Advanced Materials, 26(21), 3433–3440.
Cheng, L., Liu, J., Gu, X., Gong, H., Shi, X., Liu, T., Wang, C., Wang, X., Liu, G., Xing, H., et al. (2014). PEGylated WS2 nanosheets as a multifunctional theranostic agent for in vivo dual-modal CT/photoacoustic imaging guided photothermal therapy. Advanced Materials, 26(12), 1886–1893.
Lin, H., Gao, S., Dai, C., Chen, Y., & Shi, J. (2017). A two-dimensional biodegradable niobium carbide (MXene) for photothermal tumor eradication in NIR-I and NIR-II biowindows. Journal of the American Chemical Society, 139(45), 16235–16247.
Lipatov, A., Alhabeb, M., Lukatskaya, M. R., Boson, A., Gogotsi, Y., & Sinitskii, A. (2016). Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Advanced Electronic Materials, 2(12), 1600255.
Kinsey, N., DeVault, C., Kim, J., Ferrera, M., Shalaev, V. M., & Boltasseva, A. (2015). Epsilon-near-zero Al-doped ZnO for ultrafast switching at telecom wavelengths. Optica, 2(7), 616–622.
Marini, A., & GarcÃa de Abajo, F. J. (2016). Graphene-based active random metamaterials for cavity-free lasing. Physical Review Letters, 116(21), 217401.
Wang, Z., Meng, X., Chaudhuri, K., Alhabeb, M., Azzam, S. I., Kildishev, A. V., Kim, Y. L., Shalaev, V. M., Gogotsi, Y., & Boltasseva, A. (2017). Active metamaterials based on monolayer titanium carbide MXene for random lasing. In Conference on lasers and electro-optics (p. FTu4G.7). Washington, D.C.: OSA.
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Chaudhuri, K. et al. (2019). Optical Properties of MXenes. In: Anasori, B., Gogotsi, Y. (eds) 2D Metal Carbides and Nitrides (MXenes). Springer, Cham. https://doi.org/10.1007/978-3-030-19026-2_17
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