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Comparative Experimental Investigation of Mechanical Properties and Adhesion of Low Temperature PVD Coated TiO2 Thin Films

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Advances in Manufacturing II (MANUFACTURING 2019)

Abstract

Titanium dioxide (TiO2) has been widely used as a biomaterial due to its excellent mechanical and wear resistance properties. In this study, we have deposited TiO2 thin films on stainless steel substrate at low temperature (90 ℃) by middle frequency (MF) magnetron sputtering and cathodic arc PVD techniques at two different substrate surface roughness. Scanning Electron Microscope (SEM) and Energy Dispersive X-ray (EDX) techniques have been utilized for the study of surface morphology and stoichiometric elemental chemical composition of the TiO2 thin films. Scratch adhesion and nano indentation experiments were conducted for the assessment of the film adhesion and mechanical properties of the TiO2 thin films respectively. Results proved that the TiO2 thin film deposited on higher substrate surface roughness (0.7 µm) samples by MF magnetron sputtering PVD process have superior adhesion and mechanical properties. Correlation comparative analysis of the TiO2 thin films deposited by the MF magnetron sputtering PVD process gave the optimum results at 1238 nm film thickness and 0.7 µm substrate surface roughness. The maximum of 14 N adhesion strength, 13.8 GPa hardness and 345.6 GPa elastic modulus values have been recorded.

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References

  1. Zalnezhad, E., Hamouda, A.M.S., Faraji, G., Shamshirband, S.: TiO2 nanotube coating on stainless steel 304 for biomedical applications. Ceram. Int. 41(2), 2785–2793 (2015)

    Article  Google Scholar 

  2. Leng, Y.X., Chen, J.Y., Sun, H., Yang, P., Wan, G.J., Wang, J., Huang, N.: Properties of titanium oxide synthesized by pulsed metal vacuum arc deposition. Surf. Coat. Technol. 176(2), 141–147 (2004)

    Article  Google Scholar 

  3. Lilja, M., Forsgren, J., Welch, K., Åstrand, M., Engqvist, H., Strømme, M.: Photocatalytic and antimicrobial properties of surgical implant coatings of titanium dioxide deposited though cathodic arc evaporation. Biotech. Lett. 34(12), 2299–2305 (2012)

    Article  Google Scholar 

  4. Lilja, M., Welch, K., Åstrand, M., Engqvist, H., Strømme, M.: Effect of deposition parameters on the photocatalytic activity and bioactivity of TiO2 thin films deposited by vacuum arc on Ti-6Al-4 V substrates. J. Biomed. Mater. Res. Part B: Appl. Biomater. 100(4), 1078–1085 (2012)

    Article  Google Scholar 

  5. Mattox, D.M.: Handbook of Physical Vapor Deposition (PVD) Processing. William Andrew, Norwich (2010)

    Google Scholar 

  6. Trzcinski, M., Antończak, A.J., Domanowski, P., Kustra, M., Wachowiak, W., Naparty, M.K., Hiller, T., Bukaluk, A., Wronkowska, A.A.: Characterisation of coloured TiOx/Ti/glass systems. Appl. Surf. Sci. 322, 209–214 (2014)

    Article  Google Scholar 

  7. Bull, S.J., Berasetegui, E.G.: An overview of the potential of quantitative coating adhesion measurement by scratch testing. Tribol. Int. 39, 99–114 (2006)

    Article  Google Scholar 

  8. Mubarak, A., Hamzah, E., Tofr, M.R.M.: Review of physical vapour deposition (PVD) techniques for hard coating. J. Mekanikal 20(2), 42–51 (2005)

    Google Scholar 

  9. Balamurugan, A., Kannan, S., Rajeswari, S.: Evaluation of TiO2 coatings obtained using the sol–gel technique on surgical grade type 316L stainless steel in simulated body fluid. Mater. Lett. 59(24–25), 3138–3143 (2005)

    Article  Google Scholar 

  10. Okimura, K.: Low temperature growth of rutile TiO2 films in modified rf magnetron sputtering. Surf. Coat. Technol. 135(2–3), 286–290 (2001)

    Article  Google Scholar 

  11. Beake, B.D., Ogwu, A.A., Wagner, T.: Influence of experimental factors and film thickness on the measured critical load in the nanoscratch test. Mater. Sci. Eng., A 423(1–2), 70–73 (2006)

    Article  Google Scholar 

  12. Pizzi, A., Mittal, K.L.: Handbook of Adhesive Technology. CRC Press, Boca Raton (2017)

    Google Scholar 

  13. Nie, X.A., Leyland, H.W., Song, A.L., et al.: Thickness effects on the mechanical properties of micro-arc discharge oxide coatings on aluminium alloys. Surf Coat Tech. 116, 1055–1060 (1999)

    Article  Google Scholar 

  14. Yang, J., Roa, J.J., Ode´n, M., et al.: Substrate surface finish effects on scratch resistance and failure mechanisms of TiN-coated hardmetals. Surf. Coat. Tech. 265, 174–184 (2015)

    Article  Google Scholar 

  15. Oliver, W.C., Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7(6), 1564–1583 (1992)

    Article  Google Scholar 

  16. Sasabayashi, T., Ito, N., Nishimura, E., Kon, M., Song, P.K., Utsumi, K., Shigesato, Y.: Comparative study on structure and internal stress in tin-doped indium oxide and indium-zinc oxide films deposited by rf magnetron sputtering. Thin Solid Films 445(2), 219–223 (2003)

    Article  Google Scholar 

  17. Holmberg, K., Mathews, A.: Coatings tribology: a concept, critical aspects and future directions. Thin Solid Films 253(1–2), 173–178 (1994)

    Article  Google Scholar 

  18. Leyland, A., Matthews, A.: On the significance of the H/E ratio in wear control: a nanocomposite coating approach to optimised tribological behaviour. Wear 246, 1–11 (2000)

    Article  Google Scholar 

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Acknowledgments

We would like to extend our sincere gratitude to the Iftikhar Temper Company®, Sialkot for PVD coating.

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Correspondence to Muhammad Ghufran .

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Ghufran, M., Uddin, G.M., Khan, A.A., Hussein, H., Khurshid, K., Arafat, S.M. (2019). Comparative Experimental Investigation of Mechanical Properties and Adhesion of Low Temperature PVD Coated TiO2 Thin Films. In: Gapiński, B., Szostak, M., Ivanov, V. (eds) Advances in Manufacturing II. MANUFACTURING 2019. Lecture Notes in Mechanical Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-16943-5_38

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  • DOI: https://doi.org/10.1007/978-3-030-16943-5_38

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  • Print ISBN: 978-3-030-16942-8

  • Online ISBN: 978-3-030-16943-5

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