Abstract
Phoenix dactylifera L. date palm fruits are consumed largely worldwide. The date stone wastes from the date processing industries are huge and needs attention due to their high lignocellulose content. It is one of the good precursors for activated carbon and can be utilized for heavy metal remediation from wastewaters. Therefore, this chapter reports the metal ions adsorption by activated carbons prepared from date stone considering recent works of literature. This review elaborates the activation methods employed for activated carbon preparation, characterization strategies, parameters affecting the adsorption experiments and adsorption efficiency of the prepared carbons.
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References
Abdulkarim M, Al-Rub FA (2004) Adsorption of lead ions from aqueous solution onto activated carbon and chemically-modified activated carbon prepared from date pits. Adsorpt Sci Technol 22(2):119–134. https://doi.org/10.1260/026361704323150908
Ahmed MJ (2016) Preparation of activated carbons from date (Phoenix dactylifera L.) palm stones and application for wastewater treatments. Process Saf Environ Prot 102:168–182. https://doi.org/10.1016/j.psep.2016.03.010
Ahmed MJ, Theydan SK (2014) Fluoroquinolones antibiotics adsorption onto microporous activated carbon from lignocellulosic biomass by microwave pyrolysis. J Taiwan Inst Chem Eng 45(1):219–226. https://doi.org/10.1016/j.jtice.2013.05.014
Al-Ghouti MA, Li J, Salamh Y, Al-Laqtah N, Walker G, Ahmad MN (2010) Adsorption mechanisms of removing heavy metals and dyes from aqueous solution using date pits solid adsorbent. J Hazard Mater 176:510–520. https://doi.org/10.1016/j.jhazmat.2009.11.059
Al-Muhtaseb SA, El-Naas MH, Abdallah S (2008) Removal of aluminum from aqueous solutions by adsorption on date-pit and BDH activated carbons. J Hazard Mater 158:300–307. https://doi.org/10.1016/j.jhazmat.2008.01.080
AlOthman ZA, Inamuddin NM (2011) Determination of ion-exchange kinetic parameters for the poly- o -methoxyaniline Zr (IV) molybdate composite. Chem Eng J 166:639–645. https://doi.org/10.1016/j.cej.2010.11.036
AlOthman ZA, Alam MM, Naushad M (2013) Heavy toxic metal ion exchange kinetics: validation of ion exchange process on composite cation exchanger nylon 6,6 Zr(IV) phosphate. J Ind Eng Chem 19:956–960
Alqadami AA, Naushad M, Abdalla MA, Ahamad T, AlOthman ZA, Alshehri SM, Ghfar AA (2017a) Efficient removal of toxic metal ions from wastewater using a recyclable nanocomposite: a study of adsorption parameters and interaction mechanism. J Clean Prod 156:426–436. https://doi.org/10.1016/j.jclepro.2017.04.085
Alqadami AA, Naushad M, Alothman ZA, Ghfar AA (2017b) Novel metal–organic framework (MOF) based composite material for the sequestration of U (VI) and Th (IV) metal ions from aqueous environment. ACS Appl Mater Interfaces 9(41):36026–36037. https://doi.org/10.1021/acsami.7b10768
Ameh PO (2013) Modelling of the adsorption of Cu(II) and Cd(II) from aqueous solution by Iraqi palm-date activated carbon (IPDAC). Int J Mod Chem 5:136–144
Amor HB, Ismail M (2015) Adsorption of chromium (VI) on activated carbon prepared by acid activation of date stones. Int J Sci Res 4:309–314
Awwad NS, El-Zahhar AA, Fouda AM, Ibrahium HA (2013) Removal of heavy metal ions from ground and surface water samples using carbons derived from date pits. J Environ Chem Eng 1(3):416–423. https://doi.org/10.1016/j.jece.2013.06.006
Babakhouya N, Boughrara S, Abad F (2010) Kinetics and thermodynamics of Cd (II) ions sorption on mixed sorbents prepared from olive stone and date pit from aqueous solution. Am J Environ Sci 6(5):470–476
Banat F, Al-Asheh S, Al-Rousan D (2002) A comparative study of copper and zinc ion adsorption on to activated and non-activated date-pits. Adsorpt Sci Technol 20(4):319–335. https://doi.org/10.1260/02636170260295515
Banat F, Al-Asheh S, Al-Makhadmeh L (2003) Kinetics and equilibrium study of cadmium ion sorption onto date pits – an agricultural waste. Adsorpt Sci Technol 21(3):245–260. https://doi.org/10.1260/026361703322404395
Belala Z, Jeguirim M, Belhachemi M, Addoun F, Trouvé G (2011) Biosorption of copper from aqueous solutions by date stones and palm-trees waste. Environ Chem Lett 9(1):65–69. https://doi.org/10.1007/s10311-009-0247-5
Bhansali RR (2010) Date palm cultivation in the changing scenario of Indian arid zones: challenges and prospects. In: Desert plants. Springer, Berlin/Heidelberg, pp 423–459. https://doi.org/10.1007/978-3-642-02550-1_20
Bouhamed F, Elouear Z, Bouzid J (2012) Adsorptive removal of copper (II) from aqueous solutions on activated carbon prepared from Tunisian date stones: equilibrium, kinetics and thermodynamics. J Taiwan Inst Chem Eng 43(5):741–749. https://doi.org/10.1016/j.jtice.2012.02.011
Briones R, Serrano L, Younes RB, Mondragon I, Labidi J (2011) Polyol production by chemical modification of date seeds. Ind Crop Prod 34(1):1035–1040. https://doi.org/10.1016/j.indcrop.2011.03.012
Chaouch N, Ouahrani MR, Chaouch GN (2013) Adsorption of cadmium (II) from aqueous solutions by activated carbon produced from Algerian dates stones of Phoenix dactylifera by H3PO4 activation. Desalin Water Treat 51:2087–2092. https://doi.org/10.1080/19443994.2013.734558
Chayid MA, Ahmed MJ (2015) Amoxicillin adsorption on microwave prepared activated carbon from Arundo donax Linn: isotherms, kinetics, and thermodynamics studies. J Environ Chem Eng 3(3):1592–1601. https://doi.org/10.1016/j.jece.2015.05.021
Depci T, Onal Y, Prisbrey KA (2014) Apricot stone activated carbons adsorption of cyanide as revealed from computational chemistry analysis and experimental study. J Taiwan Inst Chem Eng 45(5):2511–2517. https://doi.org/10.1016/j.jtice.2014.05.015
Djilani C, Zaghdoudi R, Djazi F, Bouchekima B, Lallam A, Modarressi A, Rogalsk M (2015) Adsorption of dyes on activated carbon prepared from apricot stones and commercial activated carbon. J Taiwan Inst Chem Eng 53:112–121. https://doi.org/10.1016/j.jtice.2015.02.025
El Nemr A, Khaled A, Abdelwahab O, El-Sikaily A (2008) Treatment of wastewater containing toxic chromium using new activated carbon developed from date palm seed. J Hazard Mater 152(1):263–275. https://doi.org/10.1016/j.jhazmat.2007.06.091
El-Dars FMSE, Sayed AO, Salah BA, Shalabi MEH (2011) Removal of Nickel (II) from aqueous solution via carbonized date pits and carbonized rice husks. Eurasian Chem Technol J 13:267–277
El-Hendawy ANA (2009) The role of surface chemistry and solution pH on the removal of Pb2+ and Cd2+ ions via effective adsorbents from low-cost biomass. J Hazard Mater 167:260–267. https://doi.org/10.1016/j.jhazmat.2008.12.118
El-Naas MH, Al-Zuhair S, Alhaija MA (2010) Removal of phenol from petroleum refinery wastewater through adsorption on date-pit activated carbon. Chem Eng J 162(3):997–1005. https://doi.org/10.1016/j.cej.2010.07.007
Gupta VK, Nayak A, Bhushan B, Agarwal S (2015) A critical analysis on the efficiency of activated carbons from low-cost precursors for heavy metals remediation. Crit Rev Environ Sci Technol 45(6):613–668
Hamouche A, Zine BM, Krim L (2015) Kinetics and thermodynamics of Cr ions sorption on mixed sorbents prepared from olive stone and date pit from aqueous solution. Int J Food Biosyst Eng 1(1):1–8
Hazzaa R, Hussein M (2015) Adsorption of cationic dye from aqueous solution onto activated carbon prepared from olive stones. Environ Technol Innov 4:36–51. https://doi.org/10.1016/j.eti.2015.04.002
Heschel W, Klose E (1995) On the suitability of agricultural by-products for the manufacture of granular activated carbon. Fuel 74(12):1786–1791. https://doi.org/10.1016/0016-2361(95)80009-7
Hilal NM, Ahmed IA, El-Sayed RE (2012) Activated and nonactivated date pits adsorbents for the removal of Copper (II) and Cadmium (II) from aqueous solutions. ISRN Phys Chem 2012. https://doi.org/10.5402/2012/985853
Jimenez-Cordero D, Heras F, Alonso-Morales N, Gilarranz MA, Rodríguez JJ (2014) Preparation of granular activated carbons from grape seeds by cycles of liquid phase oxidation and thermal desorption. Fuel Process Technol 118:148–155. https://doi.org/10.1016/j.fuproc.2013.08.019
Karthik V, Sivarajasekar N, Padmanaban VC, Nakkeeran E, Selvaraju N (2018) Biosorption of xenobiotic Reactive Black B onto metabolically inactive T. harzianum biomass: optimization and equilibrium studies. Int J Environ Sci Technol 1–12 (in press). https://doi.org/10.1007/s13762-018-1841-5
Kenawy ER, Ghfar AA, Naushad M, ALOthman ZA, Habila MA, Albadarin AB (2017) Efficient removal of Co (II) metal ion from aqueous solution using cost-effective oxidized activated carbon: kinetic and isotherm studies. Desalin Water Treat 70:220–226. https://doi.org/10.5004/dwt.2017.20534
Mahdi Z, Yu QJ, El Hanandeh A (2018) Investigation of the kinetics and mechanisms of nickel and copper ions adsorption from aqueous solutions by date seed derived biochar. J Environ Chem Eng 6:1171–1181. https://doi.org/10.1016/j.jece.2018.01.021
Mechati F, Bouchelta C, Medjram MS, Benrabaa R, Ammouchi N (2015) Effect of hard and soft structure of different biomasses on the porosity development of activated carbon prepared under N2/microwave radiations. J Environ Chem Eng 3(3):1928–1938. https://doi.org/10.1016/j.jece.2015.07.007
Muthusaravanan S, Sivarajasekar N, Vivek JS (2018) Phytoremediation of heavy metals: mechanisms, methods and enhancements. Environ Chem Lett 16:1339–1359. https://doi.org/10.1007/s10311-018-0762-3
Naushad M (2014) Surfactant assisted nano-composite cation exchanger: development, characterization and applications for the removal of toxic Pb2+ from aqueous medium. Chem Eng J 235:100–108. https://doi.org/10.1016/j.cej.2013.09.013
Naushad M, Mittal A, Rathore M, Gupta V (2015) Ion-exchange kinetic studies for Cd (II), Co (II), Cu (II), and Pb (II) metal ions over a composite cation exchanger. Desalin Water Treat 54(10):2883–2890. https://doi.org/10.1080/19443994.2014.904823
Naushad M, Vasudevan S, Sharma G, Kumar A, ALOthman ZA (2016) Adsorption kinetics, isotherms, and thermodynamic studies for Hg2+ adsorption from aqueous medium using alizarin red-S-loaded amberlite IRA-400 resin. Desalin Water Treat 57(39):18551–18559. https://doi.org/10.1080/19443994.2015.1090914
Naushad M, Ahamad T, Al-Maswari BM, Alqadami AA, Alshehri SM (2017) Nickel ferrite bearing nitrogen-doped mesoporous carbon as efficient adsorbent for the removal of highly toxic metal ion from aqueous medium. Chem Eng J 330:1351–1360. https://doi.org/10.1016/j.cej.2017.08.079
Nowicki P, Kazmierczak J, Pietrzak R (2015) Comparison of physicochemical and sorption properties of activated carbons prepared by physical and chemical activation of cherry stones. Powder Technol 269:312–319. https://doi.org/10.1016/j.powtec.2014.09.023
Obregón-Valencia D, del Rosario Sun-Kou M (2014) Comparative cadmium adsorption study on activated carbon prepared from aguaje (Mauritia flexuosa) and olive fruit stones (Olea europaea L.). J Environ Chem Eng 2(4):2280–2288. https://doi.org/10.1016/j.jece.2014.10.004
Okman I, Karagöz S, Tay T, Erdem M (2014) Activated carbons from grape seeds by chemical activation with potassium carbonate and potassium hydroxide. Appl Surf Sci 293:138–142. https://doi.org/10.1016/j.apsusc.2013.12.117
Olivares-Marín M, Fernández-González C, Macías-García A, Gómez-Serrano V (2012) Preparation of activated carbon from cherry stones by physical activation in air. Influence of the chemical carbonisation with H2SO4. J Anal Appl Pyrolysis 94:131–137. https://doi.org/10.1016/j.jaap.2011.11.019
Paramasivan T, Sivarajasekar N, Muthusaravanan S, Subashini R, Prakashmaran J, Sivamani S, Koya PA (2019) Graphene family materials for the removal of pesticides from water. In: A new generation material graphene: applications in water technology. Springer, Cham, pp 309–327. https://doi.org/10.1007/978-3-319-75484-0_13
Saad EM, Mansour RA, El-Asmy A, El-Shahawi MS (2008) Sorption profile and chromatographic separation of uranium (VI) ions from aqueous solutions onto date pits solid sorbent. Talanta 76(5):1041–1046. https://doi.org/10.1016/j.talanta.2008.04.065
Sekirifa ML, Hadj-Mahammed M, Pallier S, Baameur L, Richard D, Al-Dujaili AH (2013) Preparation and characterization of an activated carbon from a date stones variety by physical activation with carbon dioxide. J Anal Appl Pyrolysis 99:155–160. https://doi.org/10.1016/j.jaap.2012.10.007
Sivarajasekar N (2007) Hevea brasiliensis-a biosorbent for the adsorption of Cu (II) from aqueous solutions. Carbon Lett 8(3):199–206. https://doi.org/10.5714/CL.2007.8.3.199
Sivarajasekar N (2014) Biosorption of cationic dyes using waste cotton seeds. Doctoral dissertation, Ph. D thesis. Anna University Chennai
Sivarajasekar N, Balasubramani K, Mohanraj N, Maran JP, Sivamani S, Koya PA, Karthik V (2017a) Fixed-bed adsorption of atrazine onto microwave irradiated Aegle marmelos Correa fruit shell: statistical optimization, process design and breakthrough modeling. J Mol Liq 241:823–830. https://doi.org/10.1016/j.molliq.2017.06.064
Sivarajasekar N, Mohanraj N, Balasubramani K, Prakash Maran J, Ganesh Moorthy I, Karthik V, Karthikeyan K (2017b) Optimization, equilibrium and kinetic studies on ibuprofen removal onto microwave assisted—activated Aegle marmelos correa fruit shell. Desalin Water Treat 84:48–58. https://doi.org/10.5004/dwt.2017.21107
Sivarajasekar N, Mohanraj N, Sivamani S, Moorthy GI (2017c) Response surface methodology approach for optimization of lead (II) adsorptive removal by Spirogyra sp. biomass. J Environ Biotechnol Res 6(1):88–95
Sivarajasekar N, Mohanraj N, Sivamani S, Moorthy IG, Kothandan R, Muthusaravanan S (2017d) Comparative modeling of fluoride biosorption onto waste Gossypium hirsutum seed microwave-bichar using response surface methodology and artificial neural networks. In: Intelligent Computing, Instrumentation and Control Technologies (ICICICT), 2017 international conference on, pp 1631–1635
Sivarajasekar N, Paramasivan T, Subashini R, Kandasamy S, Prakash Maran J (2017e) Central composite design optimization of fluoride removal by spirogyra biomass. Asian J Microbiol Biotechnol Environ Sci 19:S130–S137
Sivarajasekar N, Balasubramani K (2018) A short account on petrochemical industry effluent treatment. Int J Petrochem Sci Eng 3(1):12–13. https://doi.org/10.15406/ipcse.2018.03.00070
Sivarajasekar N, Baskar R (2018) Optimization, equilibrium and kinetic studies of basic red 2 removal onto waste Gossypium hirsutum seeds. Iran J Chem Chem Eng (IJCCE) 37(2):157–169. https://doi.org/1021-9986/2018/2/157-169
Sivarajasekar N, Balasubramani K, Baskar R, Sivamani S, Ganesh Moorthy I (2018a) Eco-friendly acetaminophen sequestration using waste cotton seeds: equilibrium, optimization and validation studies. J Water Chem Technol 40(6):334–342. https://doi.org/10.3103/S1063455X18060048
Sivarajasekar N, Mohanraj N, Sivamani S, Prakash Maran J, Ganesh Moorthy I, Balasubramani K (2018b) Statistical optimization studies on adsorption of ibuprofen onto Albizialebbeck seed pods activated carbon prepared using microwave irradiation. Mater Today Proc 5:7264–7274
Torrellas SÁ, Lovera RG, Escalona N, Sepúlveda C, Sotelo JL, García J (2015) Chemical-activated carbons from peach stones for the adsorption of emerging contaminants in aqueous solutions. Chem Eng J 279:788–798. https://doi.org/10.1016/j.cej.2015.05.104
Uysal T, Duman G, Onal Y, Yash I, Yanik J (2014) Production of activated carbon and fungicidal oil from peach stone by two-stage process. J Anal Appl Pyrolysis 108:47–55. https://doi.org/10.1016/j.jaap.2014.05.017
Yamina G, Abdeltif A, Youcef T, Mahfoud HM, Fatiha G (2013) A comparative study of the addition effect of activated carbon obtained from date stones on the biological filtration efficiency using sand dune bed. Energy Procedia 36:1175–1183. https://doi.org/10.1016/j.egypro.2013.07.133
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Sivarajasekar, N. et al. (2019). Recent Updates on Heavy Metal Remediation Using Date Stones (Phoenix dactylifera L.) – Date Fruit Processing Industry Waste. In: Naushad, M., Lichtfouse, E. (eds) Sustainable Agriculture Reviews 34. Sustainable Agriculture Reviews, vol 34. Springer, Cham. https://doi.org/10.1007/978-3-030-11345-2_10
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