Abstract
Fundamental understanding and control of geochemical processes in soils/rock and groundwater are vital for rational design of new and innovative resilient and sustainable geosystems. Geochemical processes such as adsorption-desorption, ion-exchange, oxidation-reduction, precipitation-dissolution, complexation, acid-base reactions, volatilization, and biodegradation processes are generally interrelated and are highly dependent on the soil/rock and pore-water characteristics such as mineralogy, oxides/carbonate content, organic carbon content, pH, solution chemistry, temperature, among others. Moreover, the geochemical processes in engineered systems can be transient and reversible, drastically impacting the performance of geosystems under different anthropogenic and natural perturbations that could occur over their design life. Non-invasive, less energy-intensive, and less resource intensive strategies and technologies are increasingly being sought for rehabilitation and/or development of sustainable geosystems. Harnessing natural biological processes has been emphasized recently toward sustainable geoengineering such as bio-cementation, bioremediation, phytoremediation, among others. However, an in-depth understanding of the fundamental dynamic geochemical processes in all such cases has been lacking, and the current research should embrace and encourage such fundamental research.
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References
Abend, S., Lagaly, G.: Sol–gel transitions of sodium montmorillonite dispersions. Appl. Clay Sci. 16(3), 201–227 (2000)
Amaya-Santos, G., Reddy, K.R.: Phytoremediation of heavy metals and PAHs in alkaline slag fill at wet meadow site. J. Hazard. Toxic Radioactive Waste 21(4) (2017)
Bishop, M.D., Kim, S., Palomino, A.M., Lee, J.-S.: Deformation of “Tunable” clay-polymer composites. Appl. Clay Sci. 101, 265–271 (2014)
Bohnhoff, G.L., Shackelford, C.D., Malusis, M., Scalia, J., Benson, C., Edil, T., Di Emidio, G., Katsumi, T., Mazzieri, F.: Novel benonites for containment barrier applications. In: Delage,P., Desrues, J., Frank, R., Puech, A., Schlosser, F. (eds.) 18th International Conference on Soil Mechanics and Geotechnical Engineering—Challenges and Innovations in Geotechnics, vol. 4, pp. 2997–3000. Presses des Ponts, Paris (2013)
Bohnhoff, G.L., Shackelford, C.D.: Improving membrane performance via bentonite polymer nanocomposites. Appl. Clay Sci. 86, 83–98 (2013)
Bohnhoff, G.L., Shackelford, C.D.: Salt diffusion through a polymerized bentonite membrane. Clay and Clay Minerals 63(3), 145–162 (2015)
Bohnhoff, G. L., Shackelford, C. D.: Hydraulic conductivity of modified clays for containment barriers. In: 7th International Congress on Environmental Geotechnics, pp. 440–447. ISSMGE, Engineers Australia (2014)
Cameselle, C., Chirakkara, R.A., Reddy, K.R.: Electrokinetic-enhanced phytoremediation of soils: status and Opportunities. Chemosphere 93(4), 626–636 (2013)
Chirakkara, R.A., Cameselle, C., Reddy, K.R.: Assessing the applicability of phytoremediation of soils with mixed organic and heavy metal contaminants. Rev. Environ. Sci. Bio/Technol. 15(2), 299–326 (2016)
Coussot, P.: Rheophysics of pastes: a review of microscopic modelling approaches. Soft Matter 3, 528–540 (2007)
Demoz, A., Mikula, R.J.: Role of mixing energy in the flocculation of mature fine tailings. J. Environ. Eng. 138(1), 129–136 (2011)
Di Emidio, G., Mazzieri, F., Verastegui-Flores, R.-D., Van Impe, W., Bezuijen, A.: Polymer-treated bentonite clay for chemical-resistant geosynthetic clay liners. Geosynthetics Int. 22(1), 1–13 (2015)
Estornell, P., Daniel, D.E.: Hydraulic conductivity of 3 geosynthetic clay liners. J. Geotech. Eng. 118, 1592–1606 (1992)
Evans, J.: Hydraulic conductivity of vertical cutoff walls. In: Daniel, D.E., Trautwein, S. (eds.) Hydraulic Conductivity and Waste Contaminant Transport in Soil, pp. 79–94. ASTM, West Conshohocken, Pennsylvania (1994)
Gates, W.P., Bouazza, A., Churchman, G.J.: Bentonite clay keeps pollutants at bay. Elements 5(2), 105–110 (2009)
Halder, B.K., Palomino, A.M., Hicks, J.: Influence of Polyacrylamide Conformation on the Fabric of a “Tunable” Kaolin-Polymer Composite. https://doi.org/10.1139/cgj-2017-0200 (2018) (In press)
Halder, B.K.: Meso-Scale Behavior Characterization of “Tunable” Clay-Polymer Composites, Ph.D. dissertation, University of Tennessee, Knoxville (2017)
Huang, P.T.: Rheological Properties and Lubrication Performance of Clay-based Drilling Fluids for Trenchless Technologies, Ph.D. thesis, Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (2013)
Johnston. C., Sasar, M., Santagata, M., Bobet. A., Duan, L., Kaminsky, H.A.: Polymer-MFT interactions: from surface chemistry to rheology. In: Sego, D., Wilson, G.W., Beier, N.A. (eds.) Proceedings 5th International Oil Sands Tailings Conference, pp. 201–213. Lake Louise, Canada, 4– December 2016
Kasperski, K.L., Mikula, R.J.: Waste streams of mined oil sands: characteristics and remediation. Elements 7(6), 387–392 (2011)
Kim, S., Moyotyka, M.A., Palomino, A.M., Podraza, N.J.: Conformational effects of adsorbed polymer on the swelling behavior of engineered clay minerals. Clays Clay Miner. 60(4), 363–373 (2012)
Kim, S., Palomino, A.M.: Factors Influencing the Synthesis of tunable clay-polymer nanocomposites using bentonite and polyacrylamide. Appl. Clay Sci. 51, 491–498 (2011)
Kim, S., Palomino, A.M., Colina, C.M.: Responsive polymer conformation and resulting permeability of clay-polymer nanocomposites. Mol. Simul. 38(8–9), 723–734 (2012)
Kolstad, D., Benson, C., Edil, T.: Hydraulic conductivity and swell of nonprehydrated GCLs permeated with multi-species inorganic solutions. J. Geotech. Geoenviron. Eng. 1236–1249 (2004)
Lan, Y., Deng, B., Kim, C., Thornton, E.C.: Influence of soil minerals on chromium (VI) reduction by sulfide under anoxic conditions. Geochem. Trans. 8(4) (2007). http://www.geochemicaltransactions.com/content/8/1/4
Malusis, M.A., Daniyarov, A.S.: Membrane efficiency of a Dense, Prehydrated GCL. In: 7th International Congress on Environmental Geotechnics, pp. 1166–1173. ISSMGE, Engineers Australia (2014)
Malusis, M., Shackelford, C.: Chemico-osmotic efficiency of a geosynthetic clay liner. J. Geotech. Geoenviron. Eng. 128, 97–106 (2002)
Malusis, M., Shackelford, C.: Coupling effects during steady-state solute diffusion through a semipermeable clay membrane. Environ. Sci. Technol. 36, 1312–1319 (2002)
Malusis, M., Shackelford, C., Olsen, H.: A laboratory apparatus to measure chemico-osmotic efficiency coefficients for clay soils. Geotech. Test. J. 24, 229–242 (2001)
Manassero, M., Dominijanni, A.: Modelling the osmosis effect on solute migration through porous media. Geotechnique 53, 481–492 (2003)
Mazzieri, F., Di Emidio, G., Van Impe, P.O.: Diffusion of calcium chloride in a modified bentonite: impact on osmotic efficiency and hydraulic conductivity. Clays Clay Miner. 58(3), 351–363 (2010)
McDougall, J.: A hydro-bio-mechanical model for settlement and other behaviour in landfilled waste. Comput. Geotech. 34(4), 229–246 (2007)
Mitchell, J.K., Soga, K.: Fundamentals of Soil Behavior, 3rd edn. Hoboken, NJ (2005)
Mongondry, P., Nicolai, T., Tassin, J.F.: Influence of pyrophosphate or polyethylene oxide on the aggregation and gelation of aqueous laponite dispersions. J. Colloid Interface Sci. 275(1), 191–196 (2004)
Langmuir, D.: Aqueous environmental geochemistry. Ground Water 35(5), 919–920 (1997)
Ochoa-Cornejo, F., Bobet. A., Johnston. C., Santagata, M., Sinfield, J.: Liquefaction 50 years after Anchorage 1964—how nanoparticles could prevent it. In: 10th U.S. National Conference on Earthquake Engineering—Frontiers of Earthquake Engineering (EERI), Anchorage, 21–25 July 2014
Ochoa-Cornejo, F., Bobet. A., Johnston. C., Santagata, M., Sinfield, J.: Cyclic behavior and pore pressure generation in sand with laponite, a super-plastic nano-particle. Soil Dyn. Earthquake Eng. (2016) (In press)
Images of Clay: Platy Illite from the Rotliegend of Northern Germany. A joint initiative of the Clay Minerals Society and The Clay Minerals Group. http://www.minersoc.org/pages/gallery/claypix/illite/hems24_4.html. Accessed July 16 2009
Reddy, K.R.: Technical challenges to in-situ remediation of polluted sites. Geotech. Geol. Eng. J. 28(3), 211–221 (2010)
Reddy, K.R., Amaya-Santos, G.: Effects of variable site conditions on phytoremediation of mixed contaminants: field-scale investigation at Big Marsh site. J. Environ. Eng. 143(9), 04017057 (2017)
Reddy, K.R., Chirakkara, R.A.: Green and sustainable remedial strategy for contaminated site: case study. Geotech. Geol. Eng. J. 31(6), 1653–1661 (2013)
Reddy, K.R., Kumar, G., Giri, R.K.: Modeling coupled processes in municipal solid waste landfills: an overview with key engineering challenges. Int. J. Geosynthetics Ground Eng. 3(1), 6 (2017a)
Reddy, K.R., Kumar, G., Giri, R.K.: Influence of dynamic coupled hydro-bio-mechanical processes on response of municipal solid waste and liner system in bioreactor landfills. Waste Manag. 63, 143–160 (2017b)
Reddy, K.R., Kumar, G., Giri, R.K.: System effects on bioreactor landfill performance based on coupled hydro-bio-mechanical modeling. J. Hazard. Toxic Radioact. Waste 22(1), 04017024 (2017c)
Reddy, K.R., Kumar, G., Giri, R.K., Basha, B.M.: Reliability assessment of bioreactor landfills using Monte Carlo simulation and coupled hydro-bio-mechanical model. Waste Manag. 72, 329–338 (2018)
Reddy, K.R., Amaya-Santos, G., Yargicoglu, E., Cooper, D.E., Negri, M.C.: Phytoremediation of PAHs and heavy metals at slag disposal site: three-year field investigation. Int. J. Geotech. Eng. 1–16 (2017d)
Reddy, K.R., Amaya-Santos, G., Copper, D.: Field-scale phytoremediation of mixed contaminants in upland area at Big Marsh site, Chicago, USA. Ind. Geotech. J. 1–16 (2017e)
Sample-Lord, K.: Membrane Behavior and Diffusion in Unsaturated Sodium Bentonite. Ph.D. Dissertation, Colorado State University, Fort Collins, CO (2015)
Sample-Lord, K., Shackelford, C.: Dialysis method to control exchangeable cations and remove excess salts from bentonite. Geotech. Test. J. 39(2), 1–11 (2016). https://doi.org/10.1520/GTJ20150065
Santagata, M., Clarke, J.P., Bobet, A., Drnevich, V.P., El Mohtar, C.S., Huang, P.T., Johnston, C.T.: Rheology of concentrated bentonite dispersions treated with sodium pyrophosphate for application in mitigating earthquake-induced liquefaction. Appl. Clay Sci. 99, 24–34 (2014)
Scalia, J.: Bentonite-polymer composites for containment applications, Ph.D. dissertation, University of Wisconsin, Madison, Madison, WI, USA (2012)
Scalia, J., Benson, C.H.: Effect of permeant water on the hydraulic conductivity of exhumed geosynthetic clay liners. Geotech. Test. J. 33(1), 1–11 (2010)
Scalia, J., Benson, C.H., Bohnhoff, G.L., Edil, T.B., Shackelford, C.D.: Long-term hydraulic conductivity of a bentonite polymer nanocomposites permeated with aggressive inorganic solutions. J. Geotech. Geoenviron. Eng. 140(3), 04013025 (2014)
Shackelford, C.D.: The ISSMGE Kerry Rowe Lecture: The role of diffusion in environmental geotechnics. Can. Geotech. J. 51(11), 1219–1242 (2014)
Shackelford, C.: Membrane behavior in engineered bentonite-based containment barriers: State of the art. In: Manassero, M., Dominijanni, A., Foti, S., Musso, G. (eds.) Coupled Phenomena in Environmental Geotechnics, pp. 45–60. CRC Press/Balkema, Taylor & Francis Group, London (2013)
Sharma, H.D., Reddy, K.R.: Geoenvironmental engineering: site remediation, waste containment, emerging waste management technologies. Wiley, Hoboken, New Jersey (2004)
Sposito, G.: The Chemistry of Soils. Oxford University Press, New York (1989)
Tanaka, H., Meunier, J., Bonn, D.: Nonergodic states of charged colloidal suspensions: repulsive and attractive glasses and gels. Phys. Rev. 69(3), 03140 (2004)
Wang, X.T., Feng, X., Xu, Z., Masliyah, J.H.: Polymer aids for settling and filtration of oil sands tailings. Can. J. Chem. Eng. 88(3), 403–410 (2010)
Yargicoglu, E., Sadasivam, B.Y., Reddy, K.R., Spokas, K.: Physical and chemical characterization of waste wood derived biochars. Waste Manag. 36(2), 256–268 (2015)
Yargicoglu, E.Y., Reddy, K.R.: Microbial abundance and activity in biochar-amended landfill cover soils: Evidences from large-scale column and field experiments. J. Environ. Eng. 143(9), 04017058 (2017)
Yargicoglu, E.Y., Reddy, K.R.: Effects of biochar and wood pellets amendments added to landfill cover soil on microbial methane oxidation: A laboratory column study. J. Environ. Manage. 193, 19–31 (2017)
Yargicoglu, E.Y., Reddy, K.R.: Biochar-amended soil cover for microbial methane oxidation: Effect of biochar amendment ratio and cover profile. J. Geotech. Geoenviron. Eng., ASCE 144(3), 04017123 (2018)
Acknowledgements
This chapter is developed based on the deliberations in the Geochemistry session at the workshop entitled “Geotechnical Fundamentals in the Face of New World Challenges” held at the National Science Foundation, Arlington, Virginia, July 17–19, 2016. The authors are grateful for the support of National Science Foundation for funding the workshop. The authors are also thankful to Ning Lu and Girish Kumar for their encouragement and assistance in preparing this chapter.
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Reddy, K.R., Bohnhoff, G.L., Palomino, A.M., Santagata, M.C. (2019). Fundamental Research on Geochemical Processes for the Development of Resilient and Sustainable Geosystems. In: Lu, N., Mitchell, J. (eds) Geotechnical Fundamentals for Addressing New World Challenges. Springer Series in Geomechanics and Geoengineering. Springer, Cham. https://doi.org/10.1007/978-3-030-06249-1_6
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