Abstract
This chapter provides a brief overview of the main directions in research and application of the interaction of laser radiation with explosives. Historically the first application of such interaction based on thermal initiation of explosives is briefly characterized. The main methods of remote detection of explosives using laser radiation are listed. Particular attention is paid to the areas of research that have been recently formed such as spectral selective resonance interaction of laser radiation with explosives and explosives modified by nano-additives. It was noted that depending on the choice of the optical absorption band of the explosives, its excitation can lead either to the effective activation of an explosive or to its decomposition, which is not accompanied by a significant thermal effect. The latter case can be used for remote detection of the explosives and, partly, for passivation of their surface. Finally, it was demonstrated that the absorbing and refractive light nano-additives are able to reduce the threshold intensity of initiation of explosives by laser radiation, while keeping the resistance of explosives to impact or thermal effects that provides the safety conditions of working with them.
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References
M.J. Gifford, W.G. Proud, J.E. Field, Development of a method for qualification of hot-spots. Thermochim. Acta 384, 285–290 (2002)
Y.-C. Liau et al., Laser-induced ignition of RDX monopropellant. Combust. Flame 126, 1680–1698 (2001)
J.M. McAfee, The deflagration to detonation transition, in Shock Wave Science and Technology Reference Library. 5: Non-Shock Initiation of Explosives, ed. by B.W. Asay (Springer, Berlin, 2010), pp. 483–535
M.D. Furnish, N.N. Thadhani, Y. Horie, Am. Inst. Phys. (Melville, NY) 878–881 (2002)
M.S. Abdulazeem et al., Int. J. Therm. Sci. 50, 2117–2121 (2011)
S. Ruiqi, W. Lizhi, Z. Wei, Z. Haonan, Laser ablation of energetic materials, in Laser Ablation—From Fundamentals to Applications. http://dx.doi.org/10.5772/intechopen.71892
L.A. Skvortsov, Laser methods for detection of the explosives traces on the surfaces of distant objects. Quantum Electron. 42(1) (2012)
L.A. Skvortsov, E.M. Maksimov, Quantum Electron. 40(7), 565 (2010)
D. Kremers, L. Radziemsky, Laser-Indused Breakdown Spectroscopy (Technosphere, Moscow, 2009)
A. Popov, T. Labutin, N. Zorov, Mosc. Univ. Chem. Bull. 50(6), 453 (2009)
F. De Lucia, A. Samuels, R. Harmon, R. Walters, K. McNesby, A. LaPointe, R. Winkel, A. Miziolek, IEEE Sens. J. 5, 681 (2005)
J. Gottfried, F.D. Lucia, C.J. Munson, A. Miziolek, Anal. Bioanal. Chem. 395, 283 (2009)
V. Demtreder, Laser Spectroscopy. Basic Principles and Experimental Technique (Science, Moscow, 1985)
S. Sharma, P. Lucey, M. Ghosh, H. Hubble, K. Horton, Spectrochim. Acta A 59, 2391 (2003)
J. Carter, J. Scaffidi, S. Burnett, B. Vasser, S. Sharma, S. Angel, Spectrochim. Acta A 61, 2288 (2005)
D. Tuschel, A. Mikholin, B. Lemoff, S. Asher, Appl. Spectrosc. 64(4), 425 (2010)
K.L. Gares et al., Review of explosive detection methods and the emergence of standoff deep UV resonance Raman. J. Raman Spectrosc. 47, 124–141 (2016)
B.H. Hokra et al., Single-shot stand-off chemical identification of powers using random Raman lasing. PNAS 111(34), 12320–12324 (2014)
S.A. Ahmanov, N.I. Koroteev, UFN 123, 405 (1977)
T. Arusi-Parpar, D. Heflinger, R. Lavi, Appl. Opt. 40, 6677 (2001)
T. Arusi-Parpar, R. Lavi, Remote detection of explosives by enhanced pulsed laser photodissotiation/laser-induced fluorescence method, in Paper Presented at the NA TO Advanced Research Workshop on Stand-off Detection of Suicide Bombers and Mobile Subjects Pfinztal (2006), pp. 13–14
C. Wynn, S. Palmacci, R. Kunz, M. Rothshild, Lincoln Lab. J. 17(2), 27 (2008)
C. Wynn, R. Palmacci, K. Kunz, K. Clow, M. Rothshild, Proc. SPIE Int. Soc Opt. Eng. 6954, 695407 (2008)
C. Wynn, R. Palmacci, K. Kunz, K. Clow, M. Rothshild, Appl. Opt. 37(31), 5767 (2008)
J. White, F. Akin, H. Oser, R. Crosley, Appl. Opt. 50(1), 74 (2011)
C. Bauer, P. Geiser, J. Burgmeier, J. Holl, W. Schade, Appl. Phys. B Lasers Opt. 85, 251 (2006)
C. Bauer, J. Burgmeier, C. Bohling, W. Schade, J.C. Holl, in Proceedings of the NATO Advanced Research Workshop on Stand-off Detection of Suicide-Bombers and Mobile Subjects (Springer, The Netherlands, 2006), p. 27
U. Willer, M. Saraji, A. Khorsandi, P. Geisher, W. Schade, Opt. Lasers Eng. 44, 699 (2006)
C. Bauer, A. Sharma, U. Willer, J. Burgmeier, B. Braunschweig, W. Schade, S. Blaser, L. Hvozdara, A. Mffller, G. Holl, Appl. Phys. B 92(3), 327 (2008)
C. Bauer, U. Willer, W. Schade, Opt. Eng. 49, 111126 (2010)
D. Edward, A. Krechetov, A. Mitrofanov, D. Nurmukhametov, M. Kuklja, J. Phys. Chem. C 115, 6893–6901 (2011)
Y. Sun, X. Tao, Y. Shu, F. Zhong, UV-induced photodecomposition of 2,2′, 4,4′, 6,6′-hexanitrostillbene (HNS), Mater. Sci.-Pol. 31(3), 306–311 (2013), http://www.materialsscience.pwr.wroc.pl/. https://doi.org/10.2478/s13536-013-0105-9
S. Kakar et al., Phys. Rev. B. 62, 15666 (2000)
J.W. McDonald et al., J. Energ. Mater. 19, 101 (2001)
A.S. Tverjanovich, A.O. Averyanov, M.A. Ilyushin, YuS Tverjanovich, A.V. Smirnov, Effect of laser radiation on tetrazolate ammine cobalt III complexes. Bull. SpbSIT (TU) 26(52), 3–7 (2014)
A.S. Tverjanovich, A.O. Averyanov, M.A. Ilyushin, YuS Tverjanovich, A.V. Smirnov, The Raman spectra of nitrotetrazolo(lato) ammine cobalt III perchlorates. Bull. SpbSIT (TU) 27(53), 8–10 (2014)
A.S. Tverjanovich et al., Universum. 12(19) (2015)
Int. J. Energ. Mater. Chem. Propuls. 15(2), 113–122 (2016)
G.O. Abdrashitov, A.O. Aver’yanov, M.D. Bal’makov, M.A. Ilyushin, A.S. Tverjanovich, Yu.S. Tver’yanovich, Decomposition of Pentaammineaquacobalt (III) Perchlorate under laser radiation action. Russ. J. Gen. Chem. 87(7), 1451–1455 (2017)
M.A. Ilyushina, Yu.S. Tverjanovich, A.S. Tverjanovich, A.O. Aver’yanov, A.V. Smirnov, I.V. Shugalei, On the mechanism of Cobalt(III) aminates pyrolysis. Russ. J. Gen. Chem. 87(11), 2600–2604 (2017)
A.S. Tverjanovicha, A.O. Aver’yanov, M.A. Ilyshin, Yu.S. Tverjanovich, A.V. Smirnov, Decomposition of Cobalt(III) Nitrotetrazolato Amminates under the action of laser light. Russ. J. Gen. Chem. 88(2), 226–231 (2017)
M.A. Ilyushin, A.V. Smirnov, V.N. Andreev, I.V. Tselinskii, I.V. Shugalei, O.M Nesterova. Russ. J. Gen. Chem. 85(13), 1620 (2015)
A.V. Smirnov, M.A. Ilyushin, I.V. Tselinskii, Synthesis of Cobalt(III) Ammine complexes as explosives for safe taking charges. Russ. J. Appl. Chem. 77(5), 794–796 (2004)
M.A. Ilyushin, A.M. Sudarikov, I.V. Tselinskii, Metallic Complexes in High-Energy Materials (LGU im A. S. Pushkina Publ., St. Petersburg, 2010), p. 188
M.A. Ilyushin, I.V. Tselinskii, A.A. Kotomin, High Power Substances for Arsenal of Initiation (SPbGTI (TU) Publ., St. Petersburg, 2013), p. 176
Int. J. Energ. Mater. Chem. Propuls. 15(2), 113–122 (2016)
Eng. J. Gun. Than. 88(2) (2017)
JTh Kloprogge, D. Wharton, L. Hickey et al., Infrared and Raman study of interlayer anions CO32−, NO3−, SO42− and ClO4− in Mg/Al-hydrotalcite. Am. Miner. 87(5–6), 623–629 (2002)
E. Ingier-Stocka, M. Maciejewski, Thermal decomposition of [Co(NH3)6]2(C2O4)3·4H2O: I. Identification of the solid products. Thermochim. Acta. 354, 45–57 (2000)
E. Mikulia, A. Migdal-Mikulia, N.S. Gorskaa Wrobelb, J. Sciesinskic, E. Sciesinskac, Phase transition and molecular motions in [Co(MH3)6](ClO4)3 studied by differential scanning calorimetry and infrared spectroscopy. J. Mol. Struct. 651–653 (2003)
Sigma-Aldrich, Catalog of Raman spectra, Hexamminecobalt (III) chloride (2012)
H.A. Block, Vibrational study of the hexamminecobalt (III) ion. Trans. Faraday Soc. 55, 867–875 (1959)
V.K. Golubev, M.A. Ilyushin, The primary mechanism of decomposition of nitrotetrazolium of cobalt(III)//Doha. 87(2), 312 (2017)
V.K. Golubev, M.A. Ilyushin, Primary decomposition mechanism of Cobalt (III) Nitrotetrazolatoammine complexes. Russ. J. Gen. Chem. 87, 286 (2017)
A.S. Tverjanovich, A.O. Aver’yanov, M.A. Ilyushin, YuS Tverjanovich, A.V. Smirnov, Russ. J. Appl. Chem. 88(2), 226 (2015)
A.S. Tverjanovich, e.a. Patent RF 2636525 (2016)
M.A. Ilyushin et al., Effect of additives of ultra fine carbon particles on the laser initiation threshold of a polymer is a photosensitive explosive composition. Chem. Fiz 24(10), 49–56 (2005)
M. Harkoma, Confinement in the diode laser ignition of energetic materials, Thesis for the degree of Doctor of Technology to be presented with due permission for public examination and criticism in Sahkotalo Building, Auditorium S1, at Tampere University of Technology, 2010
A.V. Kalenskii et al., Paradox of small particles in the pulsed laser initiation of explosive decomposition. Combust. Explos. Shock. Waves 52(2), 234–240 (2016)
Acknowledgements
This work was supported by the Russian Foundation for Basic Research, project no. 16-29-01056-ofi_m. Measurements were partly made at the resource center of St. Petersburg State University “Optical and Laser Methods for Analysis of Substances”.
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Tverjanovich, Y., Tverjanovich, A., Averyanov, A., Panov, M., Ilyshin, M., Balmakov, M. (2019). Interaction of Laser Radiation with Explosives, Applications and Perspectives. In: Yamanouchi, K., Tunik, S., Makarov, V. (eds) Progress in Photon Science. Springer Series in Chemical Physics, vol 119. Springer, Cham. https://doi.org/10.1007/978-3-030-05974-3_25
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