Abstract
Fe-3Si-3Al and Fe-4Si-4Cr (wt%) experimental alloys were processed to assess the electrical resistivity and workability effects of substituting Al and Cr for Si in high-Si electrical steel alloys. The experimental alloys were made by arc melting , and processed by hot rolling and cold rolling to produce strips. Samples were characterized by means of metallography, hardness , workability and resistivity . Results showed that the two alloys could be rolled down to 200 µm thickness (90% hot-rolled reduction and 80% cold rolled reduction) without crack formation in the strips. Hardness in the annealed condition and electrical resistivity were 228 HV/74 µΩ cm and 243 HV/85 µΩ cm, respectively, for the Fe-3Si-3Al and for Fe-4Si-4Cr alloys. The resistivity measured for Fe-4Si-4Cr was higher than the resistivity reported for the benchmark high-Si alloy, Fe-6.5Si. Both experimental alloys showed improvement on the workability compared to Fe-6.5Si since there was no edge cracking on the cold-rolled strips up to 80% reduction, and the hardness was approximately 35% lower.
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References
Moses A (1990) Electrical steels: past, present and future developments. IEE Proc A 137(5):233–245
Beckley P (2002) Electrical steels for rotating machines, no. 37. IET
Liu HT, Li HZ, Li HL, Gao F, Liu GH, Luo ZH, Zhang FQ, Chen SL, Cao GM, Liu ZY, Wang GD (2015) Effects of rolling temperature on microstructure, texture, formability and magnetic properties in strip casting Fe-6.5 Wt% Si non-oriented electrical steel. J Magn Magn Mater 391.C:65–74
Yu JH, Shin JS, Bae JS, Lee Z-H, Lee TD, Lee HM, Lavernia EJ (2001) The effect of heat treatments and Si contents on B2 ordering reaction in high-silicon steels. Mater Sci Eng A 307(1):29–34
Takada Y, Abe M, Masuda S, Inagaki J (1988) Commercial scale production of Fe-6.5 Wt. % Si sheet and its magnetic properties. J Appl Phys 64(10):5367–5369
He XD, Li X, Sun Y (2008) Microstructure and magnetic properties of high silicon electrical steel produced by electron beam physical vapor deposition. J Magn Magn Mater 320(3–4):217–221
Schoen JW, Williams RS, Huppi GS (2004) Method of continuously casting electrical steel strip with controlled spray cooling. U.S. Patent No. 6,739,384, 25 May 2004
Tian G, Bi X (2010) Fabrication and magnetic properties of Fe–6.5% Si alloys by magnetron sputtering method. J Alloy Compd 502(1):1–4
Ros-Yanez T, Houbaert Y, Gómez Rodrı́guez V (2002) High-silicon steel produced by hot dipping and diffusion annealing. J Appl Phys 91(10):7857–7859
Mănescu V, Păltânea G, Gavrilă H (2014) Non-oriented silicon iron alloys-state of the art and challenges. Rev Roum Sci Techn-Electrotechn et Energ 59(4):371–380
Littmann M (1971) Iron and silicon-iron alloys. IEEE Trans Magn 7(1):48–60
Jacobs S, Van De Putte T, Saikaly W, Chassang X (2014) Metallurgical solutions for new top performance non-oriented electrical steel for cores. In: 2014 4th international electric drives production conference (EDPC). IEEE, 2014
Stodolny J, Groyecki J (1989) Cold deformability of Fe-Si-Al alloys. Phys Scr 39(2):279
Properties and selection: nonferrous alloys and special-purpose materials (1990) Metals handbook, vol 2, p 713
Hong J, Choi H, Lee S, Kim JK, Mo Koo Y (2017) Effect of Al content on magnetic properties of Fe-Al Non-oriented electrical steel. J Magn Magn Mater 439:343–348
Ghosh G (2008) Aluminium–iron–silicon. Iron systems, part 1. Springer, Berlin, Heidelberg, pp 184–266
Raghavan V (2004) Cr-Fe-Si (Chromium-Iron-Silicon). J Phase Equilibria Diffus 25(6):545–546
Ros T, Houbaert Y, Fischer O, Schneider J (2001) Thermomechanical processing of high Si-steel (up to 6.3% Si). IEEE Trans Magn 37(4):2321–2324
Fang XS, Liang YF, Ye F, Lin JP (2012) Cold rolled Fe-6.5 wt.% Si alloy foils with high magnetic induction. J Appl Phys 111.9:094913
Kim KN, Pan LM, Lin JP, Wang YL, Lin Z, Chen GL (2004) The effect of boron content on the processing for Fe–6.5 wt% Si electrical steel sheets. J Magn Magn Mater 277(3):331–336
Narita K, Teshima N, Mori Y, Enokizono M (1981) Recent researches on high silicon-iron alloys. IEEE Trans Magn 17(6):2857–2862
Shin JS, Bae JS, Kim HJ, Lee H, Lee TD, Lavernia EJ, Lee ZH (2005) Ordering–disordering phenomena and micro-hardness characteristics of B2 phase in Fe–(5–6.5%) Si alloys. Mater Sci Eng A 407(1–2):282–290
Dodd B, Boddington P (1980) The causes of edge cracking in cold rolling. J Mech Work Technol 3(3–4):239–252
Hawezy D (2017) The influence of silicon content on physical properties of non-oriented silicon steel. Mater Sci Technol 33(14):1560–1569
Konadu SN (2006) Non-destructive testing and surface evaluation of electrical steels. Cardiff University
Perrier JC, Brissonneau P (1982) Some physical and mechanical properties of SiAlFe alloys. J Magn Magn Mater 26(1–3):79–82
Schoen JW, Comstock RJ Jr (2008) Method for production of non-oriented electrical steel strip. U.S. Patent No. 7,377,986, 27 May 2008
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The authors would like to acknowledge support from the US DOE under grant no. DE-EE0007866.
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Puentes Rodriguez, B.S., Brice, D., Mann, J.B., Chandrasekar, S., Trumble, K. (2019). Production of High-Resistivity Electrical Steel Alloys by Substitution of Si with Al and Cr. In: TMS 2019 148th Annual Meeting & Exhibition Supplemental Proceedings. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05861-6_57
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