Abstract
In this chapter, a brief account of the recent researches on the properties of POSS-containing polymeric materials, i.e., polyurethanes, resins, and thermoplastics, has been done. On this background, rubbers, generally known as elastomers, have been presented as an important class of polymers and a very essential material in industry due to their unique properties. The general characteristics of elastomers and the common classification of different types, including general-purpose, special-purpose, and specialty elastomers, together with the relevant examples, have been described. To extend service life, reduce cost and therefore improve service efficiency of elastomeric materials, various fillers have always been extensively used in the rubber industry and are addressed in the chapter. Particular attention has been given to POSS. The influence of POSS moieties in rubber matrix on the functional properties of the composites fabricated is discussed. Attempt has been made to explain the role of POSS surface functional groups in controlling the properties of POSS-containing materials, and the reinforcement mechanism is presented.
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References
Prza̧dka D, Jȩczalik J, Andrzejewska E, Szłapka M, Marciniec B, Dutkiewicz M (2013) Novel hybrid polyurethane/POSS materials via bulk polymerization. React Funct Polym 73(1):114–121. https://doi.org/10.1016/j.reactfunctpolym.2012.09.006
Bourbigot S, Turf T, Bellayer S, Duquesne S (2009) Polyhedral oligomeric silsesquioxane as flame retardant for thermoplastic polyurethane. Polym Degrad Stab 94:1230–1237
Pellice SA, Fasce DP, Williams RJJ (2003) Properties of epoxy networks derived from the reaction of diglycidyl ether of bisphenol A with polyhedral oligomeric silsesquioxanes bearing OH-functionalized organic substituents. J Polym Sci B Polym Phys 41:1451–1461 https://doi.org/10.1002/polb.10494
Matejka L, Strachota A, Plestil J, Whelan P, Steinhart M, Slouf M (2004) Epoxy networks reinforced with polyhedral oligomeric silseqioxanes (POSS). Struct Morphol Macromol 37:9449–9456
Zhou Z, Cui L, Zhang Y, Zhang Y, Yin N (2008) Preparation and properties of POSS grafted polypropylene by reactive blending. Eur Polym J 44:3057–3066
Waddon A, Zheng L, Farris R, Coughlin EB (2002) Nanostructured polyethylene-POSS copolymers: control of crystallization and aggregation. Nano Lett 2(10):1149–1155. https://doi.org/10.1021/nl020208d
Turri S, Levi M (2005) Wettability of polyhedral oligomeric silsesquioxane nanostructured polymer surfaces. Macromol Rapid Commun 26:1233–1236
Tao W, Zhou H, Zhang Y, Li G (2008) Novel silsesquioxane mixture-modified high elongation. polyurethane with reduced platelet adhesion. Appl Surf Sci 254:2831–2836
Mirchandani G, Waghoo G, Parmar R, Haseebuddin S, Ghosh SK (2009) Oligomeric silsesquioxane reinforced polyurethane with enhanced coating performance. Prog Org Coat 65(4):444–449. https://doi.org/10.1016/j.porgcoat.2009.03.009
Lewicki JP, Pielichowski K, Tremblot De La Croix P, Janowski B, Todd D, Liggat JJ (2010) Thermal degradation studies of polyurethane/POSS nanohybrid elastomers. Polym Degrad Stab 95(6):1099–1105
Ni Y, Zheng S, Nie K (2004) Morphology and thermal properties of inorganic–organic hybrids involving epoxy resin and polyhedral oligomeric silsesquioxanes. Polymer 45(16):5557–5568. https://doi.org/10.1016/j.polymer.2004.06.008
Liu YR, Huang YD, Liu L (2006) Effects of TriSilanolIsobutyl-POSS on thermal stability of methylsilicone resin. Polym Degrad Stab 91(11):2731–2738. https://doi.org/10.1016/j.polymdegradstab.2006.04.031
Liu YR, Huang YD, Liu L (2007) Thermal stability of POSS/methylsilicone nanocomposites. Comp Sci Tech 67:2864–2876
Fina A, Monticelli O, Camino G (2010) POSS-based hybrids by melt/reactive blending. J Mater Chem 20:9297–9305. https://doi.org/10.1039/C0JM00480D
Zhao J, Fu Y, Liu S (2008) Polyhedral Oligomeric Silsesquioxane (POSS)-modified thermoplastic and thermosetting nanocomposites: a review. Polym Polym Comp 16(8):483–500
Chen JH, Yao BX, Su WB Yang YB (2007) Isothermal crystallization behavior of isotactic polypropylene blended with small loading of polyhedral oligomeric silsesquioxane. Polymer 48(6):1756–1769
Chen JH, Chiou YD (2006) Crystallization behavior and morphological development of isotactic polypropylene blended with nanostructured polyhedral oligomeric silsesquioxane molecules. J Polym Sci Part B Polym Phys 44:2122–2134
Joshi M, Butola BS (2004) Studies on nonisothermal crystallization of HDPE/POSS nanocomposites. Polymer 45(14):4953–4968
Fu BX, Yang L, Somani RH, Zong SX, Hsiao BS, Philips S, Blanski R, Ruth P (2001) Crystallization studiem of isotactic polypropylene containing nanostructured polyhedral oligomeric silsesquioxane molecules under quiescent and shear conditions. J Polym Sci Part B: Polym Phys 39:2727–2739
Huang JC, He CB, Xiao Y, Mya KY, Dai J, Siow YP (2003) Polyimide/POSS nanocomposites: interfacial, interaction, thermal properties and mechanical properties. Polymer 44:4491–4499
Fina A, Abbenhuis HCL, Tabuani D, Camino G (2006) Metal functionalized POSS as fire retardants in polypropylene. Polym Degrad Stab 91:2275–2281
Joshi M, Butola BS, Simon G, Kukaleva N (2006) Rheological and viscoelastic behavior of HDPE/Octamethyl-POSS nanocomposites. Macromolecules 39(5):1839–1849. https://doi.org/10.1021/ma051357w
Zhou Q, Pramoda KP, Lee JM, Wang K, Loo LS (2011) Role of interface in dispersion and surface energetics of polymer nanocomposites containing hydrophilic POSS and layered silicates. J Colloid Interface Sci 355(1):222–230. https://doi.org/10.1016/j.jcis.2010.12.010
Chen D, Yi S, Fang P, Zhong Y, Huang C, Wu X (2011) Synthesis and characterization of novel room temperature vulcanized (RTV) silicone rubbers using octa[(trimethoxysilyl)ethyl]-POSS as cross-linker. React Funct Polym 71:502–511
Chen D, Yi S, Wu W, Zhong Y, Liao J, Huang C (2010) Synthesis and characterization of novel room temperature vulcanized (RTV) silicone rubbers using vinyl-POSS derivatives as cross-linking agents. Polymer 51:3867–3878
Schubert U, Huesing N, Lorenz A (1995) Hybrid inorganic-organic materials by sol-gel processing of organofunctional metal alkoxides. Chem Mater 7(11):2010–2027. https://doi.org/10.1021/cm00059a007
Joshi M, Butola BS (2004) Polymeric nanocomposites—Polyhedral oligomeric silsesquioxanes (POSS) as hybryd nanofillers. J Macromol Sci Part C Polym Rev 44(4):389–410. https://doi.org/10.1081/MC-200033687
Phillips S, Haddad T, Tomczak S (2004) Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers. Curr Opin Solid State Mater Sci 8:21–29. https://doi.org/10.1016/j.cossms.2004.03.002
Bhowmick AK, Stephens HL (2001) Handbook of elastomers, 2nd edn. Marcel Dekker Inc, New York
Franta I (ed) Elastomers and rubber compounding materials. Manufacture, properties and applications, ISBN 9780444601186, Elsevier, 2012
Paul DR, Mark JE (2010) Fillers for polysiloxane (‘‘silicone”) elastomers. Prog Polym Sci 35:893–901
Mark JE, Erman B (2007) Rubber-like elasticity: a molecular primer, 2nd edn. Cambridge University Press, Cambridge
Bokobza L (2007) Polymer 48(17):4907–4920
Payne AR, Whittaker RE (1971) Rubber Chem Technol 44:440
Waddell WH, Beauregard PA, Evans LR (1995) Tire Technol Int 1995:24
Wang MJ (1999) Rubber Chem Technol 72:430
Pliskin I, Tokit NJ (1972) Appl Polym Sci 16:173
http://carbonblacksales.com/carbon-black-reinforcing-agent/the access date: 30 January 2018
Rattanasom N, Saowapark T, Deeprasertkul C (2007) Reinforcement of natural rubber with silica/carbon black hybrid filler. Polym Testing 26(3):369–377
Buchanan RA, Weislogel OE, Russell CR, Rist CE (1968) Starch in rubber. Zinc starch xanthate in latex masterbatching. Prod Res Dev 7(2):155–158. https://doi.org/10.1021/i360026a013
Buchanan RA, Kwolek WF, Katz HC (1971) Die Starke 23:350
Buchanan RA, Katz HC, Russell CR, Rist CE (1971) Rubber J 10:28
Buchanan RA (1974) Peoria Illinois Die Starke 26(5):165
Buchanan RA, Doane WM, Russel CR, Kwolek WF (1975) Elastomers Plast 7:95
Abbott TP, Doane WM, Russell CR (1973) Rubber Age 8:43
Rubber containing starch reinforcement and tire having component thereof. EP1074582 A1 (2001)
Farm tire with tread of rubber composition containing starch/plasticizer composite. EP1514900 A1 (2005)
Rouilly A, Rigal L, Gilbert RG (2004) Polymer 45:7813
Wu CS (2005) Macromol Biosci 5:352
Wang S, Yu J, Yu J (2005) Polym Degrad Stab 87:395
Patel NK, Pandya PD, Kehariya H, Patel H, Sinha VK (2005) Int J Polym Mater 54:985
Qi Q et al (2006) Modification of starch for high performance elastomer. Polymer 47:3896–3903
Gura DV, Sokolova LA, Ovcharov VI, Soroka PI (2015) Assessing the properties of elastomer composites filled with hybrid filler. Int Polym Sci Technol 42(3):T23–T25
Barashkova II, Komova NN, Motyakin MV, Potapov EE, Wasserman AM (2014) Shungite-elastomer interface layers. In: Doklady Physical Chemistry, vol 456. Pleiades Publishing, pp 83–85
Barashkova II et al (2015) EPR Spin Probe Study of Local Mobility at the Shungite/Elastomer Interface. Appl Magn Reson 46(12):1421–1427
Kornev YuV et al (2013) Investigating the influence of the degree of dispersion of mineral shungite on the properties of elastomeric materials based on butadiene-styrene rubber. Int Polym Sci Technol 40(3):T27–T32
Donnet JB (2003) Nano and microcomposites of polymers elastomers and their reinforcement. Compos Sci Technol 63(8):1085–1088. https://doi.org/10.1016/S0266-3538(03)00028-9
Ponnamma D, Maria HJ, Chandra AK, Thomas S (2013) Rubber Nanocomposites: latest trends and concepts. Adv Elastomers II 12:69–107. https://doi.org/10.1007/978-3-642-20928-4_3
Thomas S, Maria HJ (eds) Progress in rubber nanocomposites, Woodhead Publishing, Cambridge 2016
De Falco A, Goyanes S, Rubiolo GH, Mondragon I, Marzocca MA (2007) Carbon nanotubes as reinforcement of styrene-butadiene rubber. Appl Surf Sci 254(1):262–265
Cardoen G, Coughlin EB (2004) Hemi-telechelic polystyrene-POSS copolymers as model systems for the study of well-defined inorganic/organic hybryd materials. Macromolecules 37:5123–5126
Tan BH, Hussain H, Leong YW, Lin TT, Tjiu WW, He C (2013) Tuning self-assembly of hybrid PLA-P(MA-POSS) block copolymers in solution via stereocomplexation. Polym Chem 4:1250–1259
Bliznyuk V, Tereshchenko T, Gumenna M, Gomza YP, Shevchuk A, Klimenko N et al (2008) Structure of segmented poly (ether urethane)s containing amino and hydroxyl functionalized polyhedral oligomeric silsesquioxanes (POSS). Polymer 49:2298–2305
Kuo SW, Chang FC (2011) POSS related polymer nanocomposites. Prog Polym Sci 36:1649–1696
Zhang W, Camino G, Yang R (2017) Polymer/polyhedral oligomeric silsesquioxane (POSS) nanocomposites: An overview of fire retardance. Prog Poly Sci 67:77–125. https://doi.org/10.1016/j.progpolymsci.2016.09.011
Laik S, Galy J, Gérard JF, Monti M, Camino G (2016) Fire behaviour and morphology of epoxy matrices designed for composite materials processed by infusion. Polym Degrad Stab 127:44–55
Rubber compound containing a polyhedral oligomeric silsesquioxanes. Pat. US 6852794 B2 (2005)
Method for making alkoxy-modified silsesquioxanes. Pat. US 7915368 B2 (2011)
Amino alkoxy-modified silsesquioxane and method of preparation. Pat. US 8513371 B2(2013)
Compouding silica-reinforced rubber with low volatile organic compounds (VOC) emission. Pat. US9403969 B2(2016)
Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber. Pat. US 8794282 B2(2014)
Rubber composition comprising a polyhedral oligomeric silsesquioxane additive. Pat. WO 2006027618 A1(2006)
Zhao Y, Jiang X, Zhang X, Hou L (2017) Toughened elastomer/polyhedral oligomeric silsesquioxane (POSS)-intercalated rectorite nanocomposites: preparation, microstructure, and mechanical properties. Polym Compos 38:E443–E450. https://doi.org/10.1002/pc.23784
Deng H et al (2012) Quaternized chitosan-layered silicate intercalated composites based nanofibrous mats and their antibacterial activity. Carbohydr Polym 89(2):307–313
Wang X et al (2010) Preparation and characterization of new quaternized carboxymethyl chitosan/rectorite nanocomposite. Compos Sci Technol 70(7):1161–1167
Li W et al (2013) Poly(vinyl alcohol)/sodium alginate/layered silicate based nanofibrous mats for bacterial inhibition. Carbohydr Polym 92(2):2232–2238
Fox DM, Maupin PH, Harris RH Jr, Gilman JW, Eldred DV, Katsoulis D, Trulove PC, De Long HC (2007) Use of a polyhedral oligomeric silsesquioxane (POSS)-imidazolium cation as an organic modifier for montmorillonite. Langmuir 23:7707–7714
Fox DM, Harris RH Jr, Bellayer S, Gilman JW, Gelfer MY, Hsaio BS, Maupin PH, Trulove PC, De Long HC (2011) The pillaring effect of the 1,2-Dimethyl-3(benzyl ethyl iso-butyl POSS) imidazolium cation in polymer/montmorillonite nanocomposites. Polymer 52:5335–5343
Wan C, Yu J, Shi X, Huang L (2006) Preparation of poly(propylene carbonate)/organophilic rectorite nanocomposites via direct melt intercalation. Trans Nonferrous Metals Soc Chin 16:s508–s511. https://doi.org/10.1016/S1003-6326(06)60245-8
Li B, Dong FX, Wang XL, Yang J, Wang DY, Wang YZ (2009) Organically modified rectorite toughened poly(lactic acid): nanostructures, crystallization and mechanical properties. Eur Polym J 45(11):2996–3003. doi.org/https://doi.org/10.1016/j.eurpolymj.2009.08.015
Ma XY, Liang GZ, Lu HJ, Liu HL, Huang Y (2005) Novel intercalated nanocomposites of polypropylene, organic rectorite, and poly(ethylene octene) elastomer: morphology and mechanical properties. J Appl Polym Sci 97:1907–1914. https://doi.org/10.1002/app.21931
Ma XY, Liang GZ, Liu HL, Fei JY, Huang Y (2005) Novel intercalated nanocomposites of polypropylene/organic-rectorite/polyethylene-octene elastomer: rheology, crystallization kinetics, and thermal properties. J Appl Polym Sci 97:1915–1921. https://doi.org/10.1002/app.21938
Zhao L et al (2018) Morphology and thermomechanical properties of natural rubber vulcanizates containing octavinyl polyhedral oligomeric silsesquioxane. Compos Part B 139:40–46. https://doi.org/10.1016/j.compositesb.2017.11.052
Tanaka K, Chujo Y (2012) Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS). J Mater Chem 22(5):1733–1746
Ghanbari H, Cousins BG, Seifalian AM (2011) A nanocage for nanomedicine: polyhedral oligomeric silsesquioxane (POSS). Macromol Rapid Commun 32(14):1032–1046
Li YW, Dong XH, Guo K, Wang Z, Chen ZR, Wesdemiotis C et al (2012) Synthesis of shape amphiphiles based on POSS tethered with two symmetric/asymmetric polymer tails via sequential “Grafting-from” and thiol–ene “click” chemistry. ACS Macro Lett 1(7):834–839
Wei K, Wang L, Li L, Zheng SX (2015) Synthesis and characterization of bead-like poly(Nisopropylacrylamide) with double decker silsesquioxanes in the main chains. Polym Chem 6(2):256–269
Alvarado-Tenorio B, Romo-Uribe A, Mather PT (2015) Nanoscale order and crystallization in POSS–PCL shape memory molecular networks. Macromolecules 48(16):5770–5779
Franczyk A, He H, Burdyńska J, Hui C, Matyjaszewski K, Marciniec B (2014) Synthesis of high molecular weight polymethacrylates with polyhedral oligomeric silsesquioxane moieties by atom transfer radical polymerization. ACS Macro Lett 3(8):799–802
Zhang WA, Muller AHE (2013) Architecture, self-assembly and properties of well-defined hybridpolymers basedonpolyhedraloligomericsilsesquioxane (POSS) Prog Polym Sci 38(8):1121–62
Shockey EG, Bolf AG, Jones PF, Schwab JJ, Chaffee KP, Haddad TS et al (1999) Functionalized polyhedral oligosilsesquioxane (POSS) macromers: new graftable POSS hydride, POSS a-olefin, POSS epoxy, and POSS chlorosilane macromers and POSS-siloxane triblocks. Appl Organomet Chem 13(4):311–327
Sun DX, Li XJ, Zhang YH, Li YW (2011) Effect of modified nano-silica on the reinforcement of styrene butadiene rubber composites. J Macromol Sci B 50(9):1810–1821
Chen D, Liu Y, Huang C (2012) Synergistic effect between POSS and fumed silica on thermal stabilities and mechanical properties of room temperature vulcanized (RTV) silicone rubbers. Polym Degrad Stab 97:308–315. https://doi.org/10.1016/j.polymdegradstab.2011.12.016
Shi Y, Huang G, Liu Y, Qu Y, Zhang D, Dang Y (2013) Synthesis and thermal properties of novel room temperature vulcanized (RTV) silicone rubber containing POSS units in polysioxane main chains. J Polym Res 20(9):245. https://doi.org/10.1007/s10965-013-0245-y
Zhang Y, He J, Yang R (2016) The effects of phosphorus-based flame retardants and octaphenyl polyhedral oligomeric silsesquioxane on the ablative and flame-retardation properties of room temperature vulcanized silicone rubber insulating composites. Polym Degrad Stab 125:140–147. doi.org/https://doi.org/10.1016/j.polymdegradstab.2015.12.007
Liu L, Tian M, Zhang W, Zhang LQ, Mark JE (2007) Crystallization and morphology study of polyhedral oligomeric silsesquioxane (POSS)/polysiloxane elastomer composites prepared by melt blending. Polymer 48:3201–3212
Meng Y, Wei Z, Liu L, Liu L, Zhang L, Nishi T, Ito K (2013) Significantly improving the thermal stability and dispersion morphology of polyhedral oligomeric silsesquioxane/polysiloxane composites by in-situ grafting re action. Polymer 54:3055–3064
Chen DZ, Nie JR, Yi SP, Wu WB, Zhong YL, Liao J, Huang C (2010) Thermal behaviour and mechanical properties of novel RTV silicone rubbers using divinyl-hexa[(trimethoxysilyl)ethyl]-POSS as cross-linker. Polym Degrad Stab 95:618–626
Chen DZ, Liu Y, Huang C (2012) Synergistic effect between POSS and fumed silica on thermal stabilities and mechanical properties of room temperature vulcanized (RTV) silicone rubbers. Polym Degrad Stab 97:308–315
Sirin H, Kodal M, Karaagac B, Ozkoc G (2016) Effects of octamaleamic acid-POSS used as the adhesion enhancer on the properties of silicone rubber/silica nanocomposites. Composites Part B 98:370–381. https://doi.org/10.1016/j.compositesb.2016.05.024
Stockelhuber KW, Das A, Jurk R, Heinrich G (2010) Contribution of physico-chemical properties of interfaces on dispersibility, adhesion and flocculation of filler particles in rubber. Polymer 51(9):1954–1963
Dong F, Zhao P, Dou R, Feng S (2018) Amine-functionalized POSS as cross-linkers of polysiloxane containing γ-chloropropyl groups for preparing heat-curable silicone rubber. Mater Chem Phys 208:19–27. https://doi.org/10.1016/j.matchemphys.2018.01.024
Madsen FB, Yu L, Daugaard AE, Hvilsted S, Skov AL (2015) A new soft di electric silicone elastomer matrix with high mechanical integrity and low losses. RSC Adv 5:10254–10259
Madsen FB, Yu L, Mazurek P, Skov AL (2016) A simple method for reducing inevitable dielectric loss in high-permittivity dielectric elastomers. Smart Mater Struct 25:075018–075032
Diao S, Dong FY, Meng J, Ma PQ, Zhao YY, Feng SY (2015) Preparation and properties of heat-curable silicone rubber through chloropropyl/amine crosslinking reactions. Mater Chem Phys 153:161–167
Dong FY, Diao S, Ma DP, Zhang SY, Feng SY (2015) Preparation and characterization of 3-chloropropyl polysiloxane-based heat-curable silicone rubber using polyamidoamine dendrimers as cross-linkers. React Funct Polym 96:14–20
Dong FY, Ma DP, Feng SY (2016) Aminopropyl-modified silica as cross-linkers of polysiloxane containing chloropropyl groups for preparing heat-curable silicone rubber. Polym Test 52:124–132
Choi J, Tamaki R, Kim SG, Laine R (2003) Organic/inorganic imide nanocomposites from aminophenylsilsesquioxanes. Chem Mater 15:3365–3375
Iyer P, Iyer G, Coleman MC (2010) Gas transport properties of polyimide-POSS nanocomposites. J Membr Sci 358:26–32
Zhang QH, He H, Xi K, Huang X, Yu XH, Jia XD (2011) Synthesis of N-phenylaminomethyl POSS and its utilization in polyurethane. Macromolecules 44:550–557
Strąkowska A, Kosmalska A, Zaborski M (2012) Silsesquioxanes as modifying agents of methylvinylsilicone rubber. Mater Sci Forum 714:183–189. https://doi.org/10.4028/www.scientific.net/MSF.714.183
Zaborski M, Strąkowska A, Kosmalska A, Maciejewski H, Michał Dutkiewicz (2013) POSS compounds as modifiers and additives for elastomeric composites. Polimery 58:772–782. https://doi.org/10.14314/polimery.2013.772
Joshi V, Srividhya M, Dubey M, Ghosh AK, Saxena A (2013) Effect of functionalization on dispersion of POSS-silicone rubber nanocomposites. J Appl Polym Sci 130:92–99. https://doi.org/10.1002/app.39112
Yang Z, Liu J, Liao R, Yang G, Wu X, Tang Z, Guo B, Zhang L, Ma Y, Nie Q, Wang F (2016) Rational design of covalent interfaces for graphene/elastomer nanocomposites. Compos Sci Technol 132:68–75
Zhong B, Jia Z, Luo Y, Jia D (2015) A method to improve the mechanical performance of styrene-butadiene rubber via vulcanization accelerator modified silica. Compos Sci Technol 117:46–53
Rooj S, Das AStockelhuber KW, Wießner S, Fischer D, Reuter U, Heinrich G (2015) Expanded organoclay assisted dispersion and simultaneous structural alterations of multiwall carbon nanotube (MWCNT) clusters In natural rubber. Compos Sci Technol 107:36–43
Le H, Parsaker M, Sriharish M, Henning S, Menzel M, Wiessner S, Das A, Do Q, Heinrich G, Radusch H (2015) Effect of rubber polarity on selective wetting of carbon nanotubes in ternary blends. Express Polym Lett 9(11):960–971
Liu Q, Ren W, Zhang Y, Zhang Y (2012) A study on the curing kinetics of epoxycyclohexyl polyhedral oligomeric silsesquioxanes and hydrogenated carboxylated nitrile rubber by dynamic differential scanning calorimetry. J Appl Polym Sci 123(5):3128–3136
Liu Q, Ren W, Zhang Y, Zhang Y (2011) Curing reactions and properties of organicinorganic composites from hydrogenated carboxylated nitrile rubber and epoxycyclohexyl polyhedral oligomeric silsesquioxanes. Polym Int 60(3):422–429
Konnola R, Nair CPR, Joseph K (2016) Cross-linking of carboxyl-terminated nitrile rubber with polyhedral oligomeric silsesquioxane. J Therm Anal Calorim 123(2):1479–1489
Sahoo S, Bhowmick AK (2007) Polyhedral oligomeric silsesquioxane (POSS) nanoparticles as new crosslinking agent for functionalized rubber. Rubber Chem Technol 80(5):826–837
Yang S, Fan H, Jiao Y, Cai Z, Zhang P, Li Y (2017) Improvement in mechanical properties of NBR/LiClO4/POSS nanocomposites by constructing a novel network structure. Compos Sci Technol 138:161–168. https://doi.org/10.1016/j.compscitech.2016.12.003
Kosmalska A, Strąkowska A, Zaborski M (2012) Properties of POSS/HNBR elastomer nanocomposites. Mater Sci Forum 714:175–181. https://doi.org/10.4028/www.scientific.net/MSF.714.175
Sperling L (2001) Physical polymer science, 3rd edn. Wiley Interscience and Sons Inc, New York
Odian G (2001) Principles of polymerization, 3rd edn. Wiley Interscience and Sons Inc, New York
Drazkowski DB, Lee A, Haddad TS, Cookson DJ (2006) Chemical substituent effects on morphological transitions in styrene − butadiene − styrene triblock copolymer grafted with polyhedral oligomeric silsesquioxanes. Macromolecules 39(5):1854–1863
Fu BX, Lee A, Haddad TS (2004) Styrene − butadiene − styrene triblock copolymers modified with polyhedral oligomeric silsesquioxanes. Macromolecules 37(14):5211–5218. https://doi.org/10.1021/ma049753m
Drazkowski DB, Lee A, Haddad TS (2007) Morphology and phase transitions in styrene − butadiene − styrene triblock copolymer grafted with isobutyl-substituted polyhedral oligomeric silsesquioxanes. Macromolecules 40(8):2798–2805. https://doi.org/10.1021/ma062393d
Salamore J (1996) Polymeric materials encyclopedia. CRC Press, New York, pp 2264–2271
Seurer B, Coughlin EB (2008) Ethylene–propylene–silsesquioxane thermoplastic elastomers. Macromol Chem Phys 209(12):1198–1209
Cong C, Cui C, Meng X, Zhou Q (2013) Structure and property of tetrafluoroethylene-propylene elastomer-OVPOSS composites. J Appl Polym Sci 130(2):1281–1288. https://doi.org/10.1002/app.39223
Cong C, Cui C, Meng X, Zhou Q (2014) Stability of POSS crosslinks and aggregates in tetrafluoroethylene-propylene elastomers/OVPOSS composites exposed to hydrochloric acid solution. Polym Degrad Stab 100:29–36. https://doi.org/10.1016/j.polymdegradstab.2013.12.032
Kostov GK, Chr PetrovP (1992) Study of synthesis and properties of tetrafluoroethylene-propylene copolymers. J Polym Sci Part A Polym Chem 30:1083–1088
Aminabhavi TM, Harlapur SF, Balundgi RH, Dale Ortego J (1998) Theoretical and experimental investigations of molecular migration and diffusion kinetics of organic esters into tetrafluoroethylene/propylene copolymer membranes. Can J Chem Eng 76:104–112
Kulkarni SB, Kariduraganavar MY, Aminabhavi TM (2003) Sorption, diffusion, and permeation of esters, aldehydes, ketones, and aromatic liquids into tetrafluoroethylene/propylene at 30, 40, and 50 °C. J Appl Polym Sci 89(12):3201–3209. https://doi.org/10.1002/app.2376
Niu M et al (2013) Novel hybrid copolymer by incorporating POSS into hard segments of thermoplastic elastomer SEBS via click coupling reaction. Polymer 54:2658–2667. https://doi.org/10.1016/j.polymer.2013.02.042
Zeng QH, Liu QL, Broadwell I, Zhu AM, Xiong Y, Tu XP (2010) Anion-exchange membranes based on quaternized polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene for direct methanol alkaline fuel cells. J Membr Sci 349:237–243. https://doi.org/10.1016/j.memsci.2009.11.051
Xu W, Cheng Z, Zhang Z, Zhang L, Zhu X (2011) Modification of SEBS rubber via iron-mediated AGET ATRP in the presence of limited amounts of air. React Funct Polym 71(6):634–640. https://doi.org/10.1016/j.reactfunctpolym.2011.03.008
Yadav SK, Mahapatra SS, Cho JW, Lee JY (2010) Functionalization of multiwalled carbon nanotubes with poly(styrene-b-(ethylene-co-butylene)-b-styrene) by click coupling. J Phys Chem C 114(26):11395–11400. https://doi.org/10.1021/jp1028382
Cao Y, Lai Z, Feng J, Wu P (2011) Graphene oxide sheets covalently functionalized with block copolymers via click chemistry as reinforcing fillers. J Mater Chem 21(25):9271–9278. https://doi.org/10.1039/C1JM10420A
Allen NS, Edge J, Wilkinson A, Liauw CM, Mourelatou D, Barrio J et al (2001) Degradation and stabilisation of styrene-ethylene-butadiene-styrene (SEBS) block copolymer. Polym Degrad Stab 71:113–122
Allen NS, Luengo C, Edge M, Wilkinson A, Parellada MD, Barrio JA et al (2004) Photooxidation of styrene-ethylene-butadiene-styrene (SEBS) block copolymer. J Photochem Photobiol A Chem 162:41–51. https://doi.org/10.1016/S1010-6030(03)00311-3
Darling SB (2007) Directing the self-assembly of block copolymers. Prog Polym Sci 32(10):1152–1204. https://doi.org/10.1016/j.progpolymsci.2007.05.004
Shankar R, Krishnan AK, Ghosh TK, Spontak RJ (2008) Triblock copolymer organogels as high performance dielectric elastomers. Macromolecules 41(16):6100–6109. https://doi.org/10.1021/ma071903g
Ganguly A, Bhowmick AK (2009) Quantification of surface forces of thermoplastic elastomeric nanocomposites based on poly(styrene-ethylene-co-butylene-styrene) and clay by atomic force microscopy. J Appl Polym Sci 111:2104–2115. https://doi.org/10.1002/app.29268
Koh K, Sugiyama S, Morinaga T, Ohno K, Tsujii Y, Fukuda T et al (2005) Precision synthesis of a fluorinated polyhedral oligomeric silsesquioxane-terminated polymer and surface characterization of its blend film with poly(methyl methacrylate). Macromolecules 38(4):1264–1270. https://doi.org/10.1021/ma047636l
Tuteja A, Choi W, Ma M, Mabry JM, Mazzella SA, Rutledge GC et al (2007) Designing superoleophobic surfaces. Science 318(5856):1618–1622. https://doi.org/10.1126/science.1148326
Spoljaric S, Shanks RA (2012) Novel elastomer dye-functionalised POSS nanocomposites: enhanced colourimetric, thermomechanical and thermal properties. Express Polymer Letters 6(5):354–372. https://doi.org/10.3144/expresspolymlett.2012.39
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Kosmalska, A., Zaborski, M. (2018). Rubbers Reinforced by POSS. In: Kalia, S., Pielichowski, K. (eds) Polymer/POSS Nanocomposites and Hybrid Materials. Springer Series on Polymer and Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-02327-0_9
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