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Polysaccharides-Based Hybrids with Graphene

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Polysaccharide Based Hybrid Materials

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSBP))

Abstract

Graphene is a single layer of carbon atoms covalently bonded in a hexagonal crystalline structure, isolated for the first time by Geim and Novoselov from the University of Manchester (UK) [1]. Graphene is a flat-like single layer of hybridized sp2 carbon atoms, which are densely packed onto each other into an ordered 2D honeycomb network (Fig. 4.1a), described by IUPAC as a single carbon layer of the graphite structure, describing its nature by analogy to a polycyclic aromatic hydrocarbon of quasi infinite size [2]. A unit hexagonal cell of graphene comprises two equivalent sub-lattices of carbon atoms, joined together by sigma (σ) bonds with a carbon-carbon bond length of 0.142 nm [3]. Each carbon atom in the lattice has a π-orbital that contributes to a delocalized network of electrons, making graphene sufficiently stable compared to other nanosystems and providing graphene with unique properties [4]. The applicability of graphene is based on the advantageous carbon network which provides this material with a combination of a large specific surface area, superior mechanical stiffness and flexibility, remarkable optical transmittance, high electronic and thermal conductivities, permeability to gases, as well as many other supreme properties [4].

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Authors and Affiliations

  1. Department of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal

    Carla Vilela, Ricardo João Borges Pinto, Armando Silvestre & Carmen Sofia da Rocha Freire Barros

  2. Mechanical Engineering Department, TEMA—Centre for Mechanical Technology and Automation, University of Aveiro, Aveiro, Portugal

    Susana Pinto & Paula Marques

Authors
  1. Carla Vilela
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  2. Ricardo João Borges Pinto
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  3. Susana Pinto
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  4. Paula Marques
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  5. Armando Silvestre
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  6. Carmen Sofia da Rocha Freire Barros
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Corresponding author

Correspondence to Carmen Sofia da Rocha Freire Barros .

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Vilela, C., Pinto, R.J.B., Pinto, S., Marques, P., Silvestre, A., da Rocha Freire Barros, C.S. (2018). Polysaccharides-Based Hybrids with Graphene. In: Polysaccharide Based Hybrid Materials. SpringerBriefs in Molecular Science(). Springer, Cham. https://doi.org/10.1007/978-3-030-00347-0_4

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