Abstract
Chlorine has been used as a disinfectant in potable water systems for over 100 yr. Free chlorine and combined chlorine (chloramines) are the two forms of chlorine widely used for the disinfection. Free chlorine is added as chlorine gas or sodium/calcium hypochlorite to the water. The reaction of chlorine in water produces hypochlor-ous acid and hydrochloric acid: Cl2 + H2O ↔ HOC1 + HC1 Chlorine Hypochlorous acid Hyddrochloric acid:
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
L. K. Wang, Y. T. Hung and N. K. Shammas (eds.), Physicochemical Treatment Processes, The Humana Press, Totowa, NJ, 2005.
L. K. Wang, Y. T. Hung, and N. K. Shammas (eds.), Advanced Physicochemical Treatment Processes, The Humana Press, Totowa, NJ, 2006.
G. F. Connell, The Chlorination/Chloramination Handbook. American Water Works Association. Water Disinfection Series, Denver, CO, 1996.
US EPA, Ambient Water Quality Criteria for Ammonia, EPA 440/5-85-001, US Environmental Protection Agency, Washington, DC, 1984.
AWWA, American National Standard for Disinfection of Water-Storage Facilities, ANSI/AWWA C652-92, American Water Works Association, Denver, CO, 1992.
AWWA, American National Standard for Disinfection of Water Treatment Plants, ANSI/AWWA C653-97, American Water Works Association, Denver, CO, 1997.
AWWA, American National Standard for Disinfecting Water Mains, ANSI/AWWA C651-99. American Water Works Association, Denver, CO, 1999.
J. J. Vasconcelos, et al., Kinetics of chlorine decay. J. AWWA 89, 54–65 (1997).
G. C. White, Handbook of Chlorination and Alternative Disinfectants. Wiley-Interscience, NY, 1999.
Metcalf and Eddy, Inc., Wastewater Engineering: Treatment, Disposal and Reuse, McGraw Hill, NY, 1981.
E. Bockman, Catalytic carbon: A new weapon in the chloramine battle. Water Conditioning and Purification 39(7), 36–38 (1997).
R. W Farmer and S. L. Kovacic,Catalytic activated carbon offers breakthrough for dialysis water treatment. Dialysis & Transplantation, November bd26, 771–775 (1997).
V. L. Snoeyink and M. T. Suidan, Dechlorination by activated carbon and other reducing agents. In Water and Wastewater Disinfection, J. D. Johnson, (ed.), Ann Arbor Science Publishers Inc., Ann Arbor, MI, 1975, pp. 339–358.
WPCF, Wastewater Disinfection. Manual of Practice FD-10, Water Pollution Control Federation, Alexandria, VA, 1986.
General Chemical, Water Treatment Dechlorination. Product Bulletin, Parsippany, NJ, 1988.
US EPA, Methods for Aquatic Toxicity Identification Evaluations, Phase I, Toxicity Characterization Procedures, Report No. USEPA-600/3-88/034, US Environmental Protection Agency, Washington, DC, 1988, pp. 8–27 and Table 8.4.
S. L. Bean, Dechlorination alternatives. Environmental Protection, 6(5), 25–26 (1995).
Maria W. Tikkanen, Development of guidance manual for disposal of chlorinated water. Proceedings of the AWWA Annual Conference, June, 2000.
Maria W. Tikkanen, Guidance Manual for Disposal of Chlorinated Water, AWWA Research Foundation Report 90863, Denver, CO, 2001.
R. L. Hardison and M. Hamamoto, An Alternative Dechlorination Process, CWEA Annual Conference, Oakland, CA, 1998.
R. L. Hardison, Best Sulfur Products, Modesto, CA. Personal communication, 1999.
G. Peterka, Vitamin C a promising dechlorination reagent. Opflow 24 (12), 1–5 (1998).
M. Bedner, W. A MacCrehan, and G. R. Helz, Making chlorine cleaner: An investigation of alternate dechlorination agents for chloramine removal in wastewater. Proceedings of the Oxidation and Reduction Technologies for Water Treatment, Division of the Environmental Chemistry, American Chemical Society, August, 2004.
L.K. Wang. New Technologies for Water and Wastewater Treatment. NYS AWWA-NYWEA Joint Tiff Symposium. Liverpool, NY. November, 15–17, 2005.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2006 Humana Press Inc., Totowa, NJ
About this chapter
Cite this chapter
Ganesh, R., Leong, L.Y.C., Tikkanen, M.W., Peterka, G.J. (2006). Dechlorination. In: Wang, L.K., Hung, YT., Shammas, N.K. (eds) Advanced Physicochemical Treatment Processes. Handbook of Environmental Engineering, vol 4. Humana Press. https://doi.org/10.1007/978-1-59745-029-4_13
Download citation
DOI: https://doi.org/10.1007/978-1-59745-029-4_13
Publisher Name: Humana Press
Print ISBN: 978-1-58829-361-9
Online ISBN: 978-1-59745-029-4
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)