Abstract
The need for studying details of the transport mechanisms during sintering is outlined. A technique for doing this is proposed which makes use of the nuclear activation of the rare isotope of oxygen O17 so that it can be used as if it were in effect a radioactive tracer. A test of the feasibility of the use of this as a marker in the region of neck growth between grains of ceramic material is then reported.
Work performed under the auspices of the U.S. Atomic Energy Commission.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. E. Paladino and R. L. Coble, “Effect of Grain Boundaries on Diffusion-Controlled Processes in Aluminum Oxide,” J. Am. Ceram. Soc. 46: 133–36 (1963), 46: 460 (1963).
G. C. Kuczynski, L. Abernathy, and J. Allen, “Sintering Mechanisms of Aluminum Oxide,” in: Kinetics of High Temperature Processes (W. D. Kingery, ed.), John Wiley, New York, 1959, pp. 163–172.
L. F. Norris and G. Parravano, “Sintering of Zinc Oxide,” J. Am. Ceram. Soc. 46: 449–52 (1963).
J. B. Holt and R. H. Condit, “Oxygen-18 Diffusion in Surface Defects on MgO as Revealed by Proton Activation,” in: Materials Science Research, Vol. 3, (W. W. Kriegel and H. Palmour III, eds.), Plenum Press, New York, 1966, pp. 13–29.
D. L. Johnson, to be published.
J. Brett and L. Seigle, “The Role of Diffusion Versus Plastic Flow in the Sintering of Model Compacts,” Acta Met. 14: 575–82 (1966).
R. H. Condit and J. B. Holt, “A Technique for Studying Oxygen Diffusion and Locating Oxide Inclusions in Metals by Using the Proton Radioactivation of Oxygen- 18,” J. Electrochem. Soc. 111: 1192–94 (1964).
J. B. Holt, private communication.
B. G. Harvey, “Recoil Techniques in Nuclear Reaction and Fission Studies,” Ann. Rev. Nucl. Sci. 10: 235–58 (1960).
G. Friedlander and J. W. Kennedy, Introduction to Radiochemistry John Wiley, New York, 1949, p. 165.
R. G. Ward, “Microradiography and Autoradiography,” in: The Physical Examination of Metals, 2nd ed. (B. Chalmers and A. G. Quarrell, eds.), Edward Arnold, London, 1960, pp. 825–53.
R. H. Condit, “Autoradiographic Techniques in Metallurgical Research,” in: Techniques in Metals Research, Vol. 2, part 4 (R. F. Bunshah, ed.), John Wiley, New York,in press.
W. E. Lotz and P. M. Johnson, “Preparation of Microautoradiographs with the Use of Stripping Film,” Nucleonics 11(3): 54 (March, 1953).
D. M. Prescott, “Autoradiography with Liquid Emulsion Methods,” in: Methods in Cell Physiology I (D. M. Prescott, ed.), Academic Press, New York, 1964, pp. 365–70.
C. B. Gilpin, D. H. Paul, S. K. Asunmaa, and N. A. Tiner, “Electron Microautoradiography and its Application to the Study of Hydrogen Distribution in Steel,” in: Advances in Electron Metallography, Special Technical Publication No. 396, Am. Soc. Testing Materials, 1966, pp. 7–20.
J. B. Holt, “Self-Diffusion of Oxygen in Single-Crystal Beryllium Oxide,” J. Nucl. Mater. 11: 107–10(1964).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1969 Springer Science+Business Media New York
About this paper
Cite this paper
Condit, R.H. (1969). The Behavior of Oxygen in Oxides During Sintering. In: Gray, T.J., Fréchette, V.D. (eds) Kinetics of Reactions in Ionic Systems. Materials Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6461-8_20
Download citation
DOI: https://doi.org/10.1007/978-1-4899-6461-8_20
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-6224-9
Online ISBN: 978-1-4899-6461-8
eBook Packages: Springer Book Archive