On the Localized Vibrations of Non-Bridging Oxygen Atoms in Vitreous Silica

  • R. J. Bell
  • P. Dean

Abstract

A structure sensitive band, in the region 900 – 950 cm-1 of the infrared spectrum of vitreous silica, has for some time been thought to be associated with the presence of non-bridging oxygen atoms. In this paper we present supporting theoretical evidence for this idea: we show that the band is probably due to highly localized vibrations of the non-bridging oxygen atoms.

Keywords

Quartz Polystyrene 

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References

  1. 1.
    W. H. Zachariasen, J. Amer. Chem. Soc. 54, 3841 (1932);CrossRefGoogle Scholar
  2. 1a.
    W. H. Zachariasen, J. Chem. Phys. 3, 162 (1935).ADSCrossRefGoogle Scholar
  3. 2.
    L. W. Tilton, N. B. S. J. Res. 59, 139 (1957).CrossRefGoogle Scholar
  4. 3.
    H. A. Robinson, J. Phys. Chem. Solids 26, 209 (1965).ADSCrossRefGoogle Scholar
  5. 4.
    E. A. Porai-Koshits, in The Structure of Glass, edited by E. A. Porai-Koshits (Consultants Bureau, New York, 1966), Vol. 6, p. 3.Google Scholar
  6. 5.
    W. A. Weyl and E. C. Marboe. The Constitution of Glasses (Interscience, New York, 1962), Vol. 1, p. 288.Google Scholar
  7. 6.
    P. Dean and M. D. Bacon, Proc. Roy. Soc. A 283, 64 (1965).MathSciNetADSCrossRefMATHGoogle Scholar
  8. 7.
    I. Simon, in Modern Aspects of the Vitreous State, edited by J. D. Mackenzie (Butterworths, London, 1960), Vol. 1, Chapter 6.Google Scholar
  9. 8.
    I. Simon, J. Amer. Ceramic Soc. 40, 150 (1957).CrossRefGoogle Scholar
  10. 9.
    P. T. Dean, to be published.Google Scholar

Copyright information

© Springer Science+Business Media New York 1968

Authors and Affiliations

  • R. J. Bell
    • 1
  • P. Dean
    • 1
  1. 1.National Physical LaboratoryTeddingtonEngland

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