Abstract
From year to year we become more and more convinced of the important role played by structural phenomena in forming the properties of polymers. Mechanical properties are determined not only by changes in shape conformation and by motion of individual molecules of the polymers, but by the behaviour of larger and more complex structural formations as well. The interphase boundaries of these formations, known as supermolecular structures, are the sites where chemical reactions in polymers are most likely to begin and centres of crack formation and incipient destruction to arise. It has been found that extensive occurrence of ordered structures is typical not only of crystalline, but also of amorphous polymers, namely, glasses and rubbers.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
V. A. Kargin and N. F. Bakeyev. Roll. Zhurn. 19, 133 (1957).
V. A. Kargin, A. L Kitaigorodsky and G. L. Slonimsky. Roll. Zhurn. 19, 131 (1957).
V. A. Kargin. Macromol. Chem. 35A, 77 (1960).
V. A. Kargin and G. A. Koretskaya. Vysokomolek. Soyed. 1, 1721 (1959).
P. I. Zubov, Z. N. Zhurkin and V. A. Kargin. Doklady Akad. Nauk SSSR 67, 659 (1949);
P. I. Zubov, Z. N. Zhurkin and V. A. Kargin. Koll. Zhurn. 16, 179 (1954).
D. N. Bort, E. E. Rylov, N. A. Okladnov, B. P. Starkman and V. A. Kargin. Vysokomolek. Soyed. 7,50 (1965);
D. N. Bort, N. A. Okladnov, B. P. Starkman, L. I. Vidyaikina and V. A. Kargin. Dokl. Akad. Nauk SSSR 160, 413 (1965).
V. A. Kargin, Z. Ya. Berestneva and V. G. Kalashnikova. Dokl. Akad. Nauk SSSR, 166, 874 (1966).
F. Haber. Ber. dtsch. chem. Ges. 55, 1717 (1922).
Z. Ya. Berestneva and V. A. Kargin. Uspekhi Rhimii 24, 249 (1955).
V. A. Kargin. Preprinty přednaešek 1, 104 (1965).
V. A. Kargin, T. A. Koretskaya and T. A. Bogayevskaya. Vysokomolek. Soyed. 6, 441 (1964).
V. A. Kargin, Z. Ya. Berestneva, E. P. Cherneva, T. D. Ignatovich and G. S. Potapova. Dokl. Akad. Nauk SSSR, in the press (1967).
A. M. Kharlamova, E. P. Gherneva and Z. Ya. Berestneva. Vysokomolek. Soyed., in the press.
Tran Hyeu, N. A. Plate, V. P. Shibayev and V. A. Kargin. Vysokomolek. Soyed. 7, 15 (1965).
A. B. Zezin, N. F. Bakeyev, P. V. Kozlov and V. A. Kargin. Mechanism of Processes of Film Formation from Polymer Solutions and Dispersions, Nauka Publishers (in Russian), 1966, p. 9.
V. A. Kargin and T. I. Sogolova. Dokl. Akad. Nauk SSSR, 88, 867 (1953);
V. A. Kargin and T. I. Sogolova. Zhurn. Fiz. Rhim. 27, 1039 (1953).
V. A. Kargin and T. A. Koretskaya. Dokl. Akad. Nauk SSSR, 110, 1015 (1956).
V. A. Kargin, T. I. Sogolova and N. Ya. Rapoport-Molodtsova, Vysokomolek. Soyed. 6, 1562, 1559(1964).
V. A. Kargin, T. I. Sogolova and V. M. Rubstein. Dokl. Akad. Nauk SSSR, in the press (1967).
V. A. Kargin, G. P. Andrianova and G. G. Kardash. Vysokomolek. Soyed. 9A, 267 (1967).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1968 Springer Science+Business Media New York
About this chapter
Cite this chapter
Kargin, V.A. (1968). Structure of Polymer Molecules and Supermolecular Structures. In: La Chimie Macromoléculaire—4 / Macromolecular Chemistry—4. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-6407-6_5
Download citation
DOI: https://doi.org/10.1007/978-1-4899-6407-6_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-6201-0
Online ISBN: 978-1-4899-6407-6
eBook Packages: Springer Book Archive