Abstract
Polysaccharides are homo- or copolymers of sugar residues joined together. Practically all of the sugar residues are hexoses or pentoses of the aldose type; ketose residues occur rarely in polysaccharides. D-Glucose, D-galactose, and D-mannose dominate in the case of the aldohexoses, and L-arabinose, D-ribose, and D-xylose mainly occur among the aldopentoses. Glycosidic bonds occur between the sugar residues. The polysaccharide chains may be linear or have comb- or star-shaped branching. Polysaccharides mostly do not occur in the pure state in nature; they most often possess a stable and probably covalently bonded peptide component to the extent of a few percent. This peptide component is rich in hydroxyl group containing amino acids.
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Literature
31.1 and 31.2. General Literature
W. W. Pigman and R. M. Goegg, Jr., Chemistry of the Carbohydrates, Academic Press, New York, 1948.
R. L. Whistler and C. L. Smart, Polysaccharide Chemistry, Academic Press, New York, 1953.
F. Micheel, Chemie der Zucker und Polysaccharide, Akad. Verlagsges., Leipzig, 1956.
E. Percival and R. H. McDowell, Chemistry and Enzymology of Marine Algae Polysaccharides, Academic Press, London, 1967.
J. Stanek, M. Cerny, and J. Pacak, The Oligosaccharides, Academic Press, New York, 1965.
G. O. Aspinall, Polysaccharides, Pergamon Press, Oxford, 1970.
R. L. Whistler (ed.), Industrial Gums—Polysaccharides and their Derivatives, Academic Press, New York, 1973.
D. A. Rees, Polysaccharide Shapes, Chapman and Hall, London, 1977.
D. A. Rees, Polysaccharide nomenclature, Recommendations 1980. Pure Appl. Chem. 54, 1523 (1982).
D. A. Rees,, Abbreviated terminology of oligosaccharide chains, Recommendations 1980, Pure Appl. Chem. 54, 1517 (1982).
G. O. Aspinall, ed., The Polysaccharides, Academic Press, New York, Vol. 1 (1982).
31.3. Syntheses
C. Schuerch, Systematic approaches to the chemical synthesis of polysaccharides, Acc. Chem. Res. 6, 184 (1973).
31.4. Poly(a-glucoses)
A. Grönwall, Dextran and Its Use in Colloidal Infusion Solutions, Almquist and Wiksell, Stockholm, 1957.
R. L. Whistler and E. P. Paschall, Starch: Chemistry and Technology, Academic Press, New York, Vol. I, 1965; Vol. I1, 1967.
M. Ullmann, Die Stärke, Akademie-Verlag, Berlin, 1967ff (bibliography).
J. A. Radley, Starch and Its Derivatives, Chapman and Hall, London, 1968.
W. Banks and C. T. Greenwood, Starch and Its Components, University Press, Edinburgh, 1975.
J. A. Radley (ed.), Examination and Analysis of Starch and Its Components, Appl. Sci. Publ., Barking, Essex, 1976.
J. A. Radley (ed.), Starch Production Technology, Appl. Sci. Publ., Barking, Essex, 1976.
J. A. Radley (ed.), Industrial Uses of Starch and Its Derivatives, Appl. Sci. Publ., Barking, Essex, 1976.
J. C. Johnson, Industrial Starch Technology, Noyes Publ., Park Ridge, New Jersey, 1979.
R. L. Whistler, J. N. Be Miller, and E. F. Paschall, Starch-Chemistry and Technology, Academic Press, New York, 1984.
31.5. Cellulose
E. Ott and H. M. Spurlin, Cellulose and Cellulose Derivatives, three vols., Interscience, New York, 1954; Vols. 4 and 5, N. M. Bikales and L. Segal, 1971.
H. B. Brown and J. O. Ware, Cotton, third ed., McGraw-Hill, New York, 1958.
J. Honeyman, Recent Advances in the Chemistry of Cellulose and Starch, Heywood, London, 1959.
N. 1. Nikitin, The Chemistry of Cellulose and Wood, Israel Program for Scientific Translations, Jerusalem, 1967.
R. H. Marchessault and A. Sarko, X-ray structure of polysaccharides, Adv. Carbohydrate Chem. 22, 421 (1967).
E. Treiber, Chemie der Pflanzene1lwand, Springer, Berlin, 1957.
A. Frey-Wyssling, Die pflanzliche Zellwand, Springer, Berlin, 1959.
W. D. Paist, Cellulosics, Reinhold, New York, 1958.
G. W. Lock, Sisal, second ed., Longmans, London, 1969.
J. N. Mathers, Carding Jute and Similar Fibres, Iliffe, London, 1969.
J. R. Colvin, The structure and biosynthesis of cellulose, Crit. Rev. Macromol. Sci. 1, 47 (1972).
L. S. Gal’braikh and Z. A. Rogovin, Chemical transformation of cellulose, Adv. Polym. Sci. 14, 87 (1974).
C. R. Wilke (ed.), Cellulose as a Chemical and Energy Source, (Biotechnology and Bioengineering, Symp. No. 5), Interscience, New York, 1975.
H. Rath, Lehrbuch der Teztilchemie, second ed., Springer, Berlin, 1963.
R. H. Peters, Textile Chemistry, Elsevier, Amsterdam, 1963.
H. Fourne, Synthetische Fasern, Wissenschaftliche Verlagsges, Stuttgart, 1964.
K. Götz, Chemiefasern nach dem Viskoseverfahren, Springer, Berlin, 1967.
O. Wurz, Celluloseäther, C. Roether, Darmstadt, 1961.
F. D. Miles, Cellulose Nitrate, Interscience, New York, 1955.
V. E. Yarsley, W. Flavell, P. S. Adamson, and N. G. Perkins, Cellulose Plastics, Iliffe, London, 1964.
R. M. Rowell and R. A. Young (eds.), Modified Cellulosics, Academic Press, New York, 1978.
C. M. Hudson and J. A. Cuculo, The solubility of unmodified cellulose: A critique of the literature, J. Macromol. Sci.-Rev. Macromol. Sci. C18, 1 (1980).
A. Hebeish and J. T. Guthrie, The Chemistry and Technology of Cellulosic Copolymers, Springer, Berlin, 1981.
R. Malcolm Brown, Jr., ed., Cellulose and Other Natural Polymer Systems: Biogenesis, Structure, and Degradation, Plenum, New York, 1982.
R. D. Gilbert and P. A. Patton, Liquid Crystal Formation in Cellulose and Cellulose Derivatives, Prog. Polym. Sci. 9, 115 (1983).
R. W. Jeanloz and E. A. Balasz (eds.), The Amino Sugars,four vols., Academic Press, New York, 1965ff.
J. S. Brimacombe and J. W. Webber, Mucopolysaccharides, Elsevier, Amsterdam, 1964.
R. A. Bradshaw and S. Wessler (eds.), Heparin: Structure, Function and Clinical Implications, Plenum Press, New York, 1975.
R. A. A. Muzzarelli, Chitin, Pergamon Press, London, 1977.
N. M. McDuffie (ed.), Heparin: Structure, Cellular Functions and Clinical Applications, Academic Press, New York, 1979.
W. D. Comper, Heparin (and Related Polysaccharides), Gordon and Breach, New York, 1981.
31.9. Other Polysaccharides
A. Jeanes, Application of extracellular microbial polysaccharide polyelectrolytes: Review of literature, including patents, J. Polym. Sci. (Symp.) C45, 209 (1974).
R. L. Davidson (ed.), Handbook of Water-soluble Gums and Resins, McGraw-Hill, New York, 1980.
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Elias, HG. (1984). Polysaccharides. In: Macromolecules. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2809-2_17
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