Abstract
Molecular crystals1–3 are in general characterized by strong intramolecular forces and much weaker intermolecular forces. The molecular structure remains unaltered and the internal vibrations split off under the influence of the lattice field. One important property of such crystals is their large compressibility, a result of the weak external forces. Therefore pressure dependent investigations on vibrational modes are a good tool to test theoretical models, e.g. forms of potentials, approaches in lattice dynamics. As can be seen later temperature variation gives additional information about anharmonicity.
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Eckert, B., Jodl, H.J., Albert, H.O., Foggi, P. (1991). Sulphur at High Pressure and Low Temperatures. In: Hochheimer, H.D., Etters, R.D. (eds) Frontiers of High-Pressure Research. NATO ASI Series, vol 286. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2480-3_13
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DOI: https://doi.org/10.1007/978-1-4899-2480-3_13
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