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Mössbauer Effect Studies of Nanostructured Materials

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Mössbauer Spectroscopy Applied to Magnetism and Materials Science

Part of the book series: Modern Inorganic Chemistry ((MICE,volume 1))

Abstract

Mössbauer effect spectroscopy has a high-caliber pedigree, of over 30 years standing, as an incisive technique in the delineation of structural details of condensed matter. Nowhere have the contributions of Mössbauer spectroscopy been more effective than in the fields of solid-state physics and materials science. Examples of applications in which measurements of nuclear hyperfine interactions by Mössbauer spectroscopy provide insight into the local atomic environment of the Mössbauer isotope atom, abound in the literature. The hyperfine interactions of prime interest are: the electric monopole interaction (the isomer shift), the electric quadrupole interaction (quadrupole splitting) and the magnetic dipole interaction (nuclear Zeeman effect; magnetic hyperfine splitting).1,2 Just one example of an early application of Mössbauer spectroscopy in this way is the investigation of the cubic Laves phase intermetallic compound ZrFe2. Wertheim et al. 3 were able to account fully for their Mössbauer spectrum in terms of the directions of easy/hard magnetization and the principal axis of the electric field gradient, consistent with the number of iron atoms in the different locations on the corners of tetrahedra.

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Authors and Affiliations

  1. Department of Physics, University College, The University of New South Wales, Australian Defense Force Academy, Canberra, ACT, 2600, Australia

    S. J. Campbell

  2. Werkstoffwissenschaften, University of Saarland, D-6600, Saarbrücken, Germany

    H. Gleiter

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  1. University of Missouri-Rolla, Rolla, Missouri, USA

    Gary J. Long

  2. University of Liège, Sart-Tilman, Belgium

    Fernande Grandjean

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Campbell, S.J., Gleiter, H. (1993). Mössbauer Effect Studies of Nanostructured Materials. In: Long, G.J., Grandjean, F. (eds) Mössbauer Spectroscopy Applied to Magnetism and Materials Science. Modern Inorganic Chemistry, vol 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2409-4_7

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