Abstract
A mathematical model for determining the concentration changes in solution during the dissolution of a uranium dioxide-pyrite mixture has been developed using a Fe2(SO4)3-H2SO4 lixiviant. When modeling such a leaching process, the two dissolution reactions are considered to be slow enough so that the reactions in solution can be assumed to be at continual equilibrium. This situation allows for the partial equilibrium approach to be utilized in modeling the overall leaching process.
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References
D. Langmuir: Geochim. Cosmochim. Acta, vol. 42:547, (1978).
M. E. Grimes: Solution Mining Symposium, Society of Mining Engineers, AIME, New York, N.Y., 338–53, 1974.
P. M. Boomer: Ph.D. Thesis, University of Texas, Austin, TX, 1979.
R. W. Potter: USGS Open File 76-835, U.S. Dept. of the Interior, Washington, D.C., 1977.
A. R. Amell and D. Langmuir: Open File Report 84-79, U.S. Bureau of Mines, Washington, D.C., 1978.
S. Sasmojo: Ph.D. Thesis, The Ohio State University, Columbus, OH, 1969.
W. H. Truesdall and B. F. Jones: J. Res. U.S. Geol. Surv., vol. 2:233–48, No. 2, 1974
W. M. Latimer: Oxidation Potentials, 2nd ed., pp 300–4, Prentice-Hall, Inc., Englewood Cliffs, N.J., 1952.
C. C. Allen: M.S. Thesis, Iowa State University, Ames, IA, 1982.
H. C. Helgeson: Geochim. Cosmochim. Acta, vol. 32:853, 1968.
K. C. Liddell: Ph.D. Thesis, Iowa State Univ., Ames, IA, 1979.
K. C. Liddell and R. G. Bautista: Thermodynamics of Aqueous Systems with Industrial Applications, Am. Chem. Soc, Washington, D.C., pp 741-55, 1980.
K. C. Liddell and R. G. Bautista: Process and Fundamental Considerations of Selected Hydrometallurgical Systems, Society of Mining Engineers of AIME, New York, NY, 339-344, 1981.
K. C. Liddell and R. G. Bautista: Metall. Trans. B, vol. 12B:627–37, 1981.
K. C. Liddell and R. G. Bautista: Metall. Trans. B, vol. 14B: 5–15, (1983).
R. M. Smith and A. E. Martell: Critical Stability Constants, 4:1-12, 79–84, Plenum Press, New York, NY, 1976.
I. I. Chernyaeu, ed.: Complex Compounds of Uranium, pp. 150-171, Israel Program for Scientific Translations, Jerusalem, Israel, 1966
R. S. Sapieszko, R. C. Patel, and Matijevic: J. Phys. Chem., vol. 81:1061–68, 1977.
C. F. Wells and M. A. Salam: J. Chem. Soc, Part A, 1968, pp 308-15.
R. M. Carlson, R. D. Norris, and R. Schellinger: Paper SPE 9483 55th Annual Fall Technical Conference and Exhibition of the Society of Petroleum Engineers of AIME, Dallas, TX, 1980.
P. A. Laxen: Unit Processes in Hydrometallurgy, Society of Mining Engineers of AIME, New York, NY, pp 143-66, 1968.
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Allen, C.C., Bautista, R.G. (1984). A Partial Equilibrium Model Based on the Kinetics of Dissolution and Equilibrium in Solution of the UO2-FeS2-Fe2(SO4)3-H2SO4-System. In: Bautista, R.G. (eds) Hydrometallurgical Process Fundamentals. NATO Conference Series, vol 10. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2274-8_8
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DOI: https://doi.org/10.1007/978-1-4899-2274-8_8
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