Abstract
In the discussion of secondary batteries in Lecture I, two types of reversible electrodes were identified: elemental-metal anodes and insertion-compound cathodes. The elemental-metal anodes found application with aqueous electrolytes (e.g. the Cd-Ni alkali cell and Pb-PbO2 acid cell) and with solid electrolytes (e.g. Na-S cell), but the number of possibilities is limited. Insertion compounds, on the other hand, may be used as anodes as well as cathodes; in fact a composite of two insertion compounds has particular promise for this application [1]. Therefore, my final lecture is devoted to a few observations about insertion compounds and their design as reversible solid electrodes.
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Goodenough, J.B. (1990). Designing a Solid Electrolyte IV. Designing a Reversible Solid Electrode. In: Akridge, J.R., Balkanski, M. (eds) Solid State Microbatteries. NATO ASI Series, vol 217. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2263-2_11
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