Abstract
Nitroxyl free radicals are weak Lewis bases which can function as ligands for a variety of transition metals. The nitroxyl group has been observed to bind to transition-metal ions only under rather special circumstances. In particular, enhancement of the Lewis acidity of the metal center by electron-withdrawing ligands seems to be required. Among the ligands employed for this purpose has been the hexafluoroacetylacetonate ion (hfac).
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Kahn, O; Charlot, M.F. Nouv. J. Chim. 1980, 4, 567.
Lim, Y.Y.; Drago, R.S. Inorg. Chem. 1972, 11, 1334.
Grand, A.; Rey, P.; Subra, R. Inorg. Chem. 1983, 22, 391.
Bencini, A.; Benelli, C.; Gatteschi, D.; Zanchini, C. J. Am. Chem. Soc. 1984, 106, 5813.
Dickman, M.H.; Porter, L.C.; Doedens, R.J. Inorg. Chem. 1986, 25, 2595.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer Science+Business Media New York
About this chapter
Cite this chapter
Caneschi, A., Gatteschi, D., Laugier, J., Rey, P., Sessoli, R., Zanchini, C. (1987). Synthetic Pathways to Low-Dimensional Compounds Containing Transition Metal Ions and Nitroxide Radicals. In: Delhaes, P., Drillon, M. (eds) Organic and Inorganic Low-Dimensional Crystalline Materials. NATO ASI Series, vol 168. Springer, New York, NY. https://doi.org/10.1007/978-1-4899-2091-1_41
Download citation
DOI: https://doi.org/10.1007/978-1-4899-2091-1_41
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4899-2093-5
Online ISBN: 978-1-4899-2091-1
eBook Packages: Springer Book Archive