Skip to main content

Polynuclear Metal Cluster Compounds: A New Chemical Submicron Structure

  • Chapter
Organic and Inorganic Low-Dimensional Crystalline Materials

Part of the book series: NATO ASI Series ((NSSB,volume 168))

Abstract

One of the most important advances in the study of condensed matter of the last few years is that men has started to manipulate matter on the atomic and molecular scales. In line with the spectacular development of ultra-high vacuum techniques, a great many novel materials are being made by chemical or physical vapour deposition, materials which could never have been obtained by means of conventional chemical synthesis. The advent of the scanning tunneling microscope and the enormous increase in resolution of the electron microscopes enable us to actually observe matter “in real space” on the atomic scale. Since the artificially obtained materials often have a layered structure, with a repetition rate that can extend from a single monolayer up to hundreds of layers, the study of surfaces and interfaces has become of prime importance.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. See e.g. L.J. de Jongh in “Magneto Structural Correlations in Exchange Coupled Systems, ed. R.D. Willett, D. Gatteschi and O. Kahn, Reidel, 1983.

    Google Scholar 

  2. P. Chini, Gazetta Chimica Italiana 109:225–240 (1979).

    Google Scholar 

  3. “Transition metal clusters”, ed. B.F.G. Johnson, Wiley, 1980.

    Google Scholar 

  4. G. Schmid in “Structure and Bonding”, 62:51–85 (1985).

    Article  Google Scholar 

  5. M.N. Vargaftik, V.P. Zagorodnikov, I.P. Stolyarov, I.I. Moiseev, V.A. Likholobov, D.I. Kochubey, A.L. Chuvilin, V.I. Zaikovsky, K.I. Zamaraev, and G.I. Timofeeva, J. Chem. Soc, Chem. Commun., 937 (1985).

    Google Scholar 

  6. G. Schmid, Nachr. Chem. Tech. Lab. 34: nr. 3, p.249 (1987).

    Article  Google Scholar 

  7. G. Schmid and N. Klein, Angew. Chem., 98:910 (1986).

    Article  Google Scholar 

  8. B.J. Pronk, H.B. Brom, L.J. de Jongh, G. Longoni and A. Ceriotti, Solid State Commun. 59:349 (1986).

    Article  ADS  Google Scholar 

  9. B.K. Teo, F.J. Disalvo, J.W. Waszczak, G. Longoni and A. Ceriotti, Inorg. Chem. 25:2262 (1986).

    Article  Google Scholar 

  10. A. Mees, J. Darriet, Albino O. de Aguiar, M.J.G.M. Jurgens, to be published.

    Google Scholar 

  11. D.R. Salahub and F. Raatz, Int. J. Quantum Chem. S18:173 (1984).

    Article  Google Scholar 

  12. D.R. Salahub and F. Raatz, Surface Science 146:L609 (1984).

    ADS  Google Scholar 

  13. G.F. Holland, D.E. Ellis, and W.C. Trogler, J. Chem. Phys. 83:3507 (1985).

    Article  ADS  Google Scholar 

  14. B.J. Pronk, H.B. Brom, G. Longoni and A. Ceriotti, submitted to Solid State Commun.

    Google Scholar 

  15. M.P.J. van Staveren, H.B. Brom, L.J. de Jongh and G. Schmid, Solid State Commun. 60:319 (1986); and to be published.

    Article  ADS  Google Scholar 

  16. V. Ambegaokar, B.I. Halperin, and J.S. Langer, Phys. Rev. B4:2612 (1971).

    Article  ADS  Google Scholar 

  17. T. Holstein, Ann. Phys. 8:325 (1959).

    Article  ADS  Google Scholar 

  18. T. Holstein, J. Appel. Solid State Phys. 21:193 (1968).

    Article  Google Scholar 

  19. I.G. Auster and N.F. Mott, Adv. Phys. 18:41 (1969).

    Article  ADS  Google Scholar 

  20. K.Y. Wong and P.N. Schatz, Progr. Inorg. Chem. 28:369 (1981).

    Google Scholar 

  21. K. Nasu and Y. Toyazawa, J. Phys. Soc. Japan 51:2098 (1982); P. Day, contribution to this volume.

    Article  ADS  Google Scholar 

  22. G. Schmid, R. Pfeil, R. Boese, F. Bandermann, S. Meyer, G.H.M. Calis and J.W.A. van der Velden, Chem. Ber. 114:3634 (1981).

    Article  Google Scholar 

  23. H.H.A. Smit, R.C. Thiel, L.J. de Jongh and G. Schmid, to be published.

    Google Scholar 

  24. M.P.A. Viegers and J.M. Trooster, Phys. Rev. B15:72 (1977).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1987 Springer Science+Business Media New York

About this chapter

Cite this chapter

de Jongh, L.J. (1987). Polynuclear Metal Cluster Compounds: A New Chemical Submicron Structure. In: Delhaes, P., Drillon, M. (eds) Organic and Inorganic Low-Dimensional Crystalline Materials. NATO ASI Series, vol 168. Springer, New York, NY. https://doi.org/10.1007/978-1-4899-2091-1_16

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-2091-1_16

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4899-2093-5

  • Online ISBN: 978-1-4899-2091-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics