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Modern Aspects of Electrochemistry pp 61–105Cite as

Potential-Modulated Reflectance Spectroscopy Studies of the Electronic Transitions of Chemisorbed Carbon Monoxide

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Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 28))

Abstract

Carbon monoxide is, without question, the molecule whose chemisorption has been most intensively studied with the full panoply of surface spectroscopies. There is a predominance of infrared spectroscopy studies, since the stretching vibration of chemisorbed CO has one of the highest IR extinction coefficients and, in addition, in most cases the position of this band depends only on the degree of bonding of CO to the metal surface, the band appearing at about 2050, 1950, and 1850 cm−1 for on-top (linear), bridged, and multiply bonded CO, respectively.

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Authors and Affiliations

  1. Instituto de Química Física “Rocasolano,”, Consejo Superior de Investigaciones Científicas, 28006, Madrid, Spain

    C. Gutiérrez

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  1. C. Gutiérrez
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Editors and Affiliations

  1. University of Ottawa, Ottawa, Ontario, Canada

    B. E. Conway

  2. Texas A&M University, College Station, Texas, USA

    J. O’M. Bockris

  3. University of South Carolina, Columbia, South Carolina, USA

    Ralph E. White

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Gutiérrez, C. (1996). Potential-Modulated Reflectance Spectroscopy Studies of the Electronic Transitions of Chemisorbed Carbon Monoxide. In: Conway, B.E., Bockris, J.O., White, R.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 28. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1718-8_2

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  • DOI: https://doi.org/10.1007/978-1-4899-1718-8_2

  • Publisher Name: Springer, Boston, MA

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