Abstract
Surrogate Oak Ridge Reservation (ORR) K-25 B&C Pond sludge and actual ORR Central Neutralization Facility (CNF) sludge were vitrified in a pilot-scale EnVitCo melter operated by the Clemson Environmental Technologies Laboratory (CETL). This demonstration was performed for the Savannah River Technology Center (SRTC) to support demonstrations to be performed in the Transportable Vitrification System (TVS). The intent of the demonstration was to characterize the behavior of a blend of the two sludges when vitrified, including offgas contaminants and final product durability. Both the B&C Pond and CNF sludges are mixed waste with U as the principal radioactive component. The optimum blend of waste was determined to be 70 wt% B&C to 30 wt% CNF, at a total waste loading of 50 wt% in the glass. A durable glass was produced from this demonstration, and offgas analyses indicated minimal metal and radioactive element releases. Details of the demonstration and characterization of the glass products will be discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
C.R. Kirkpatrick, L.G. Hamilton, A.M. Hemken, C.M. Turner, J. Zolyniak, and J.L. Shoemaker. Characterization of the K-1407 B and C Ponds Raw Sludges and Laboratory Cured Concrete Cubes, Report K/TCD-1019, Martin Marietta Energy Systems, Inc., Oak Ridge (1992).
W.D. Bostick, D.P. Hoffmann, R.J. Stevenson, A. Richmond, and D.F. Bickford. Surrogate Formulations for Thermal Treatment of Low-Level Mixed Waste: Part IV-Waste Water Treatment Sludges, DOE.MWIP-18, Rev. 0.3, Oak Ridge (1993).
C.M. Jantzen, N.E. Bibler, D.C Beam, C.L. Crawford, M.A. Pickett. Characterization of the Defense Waste Processing Facility (DWPF) Environmental Assessment (EA) Glass Standard Reference Material, WSRC-TR-92-346, Rev. 1, Westinghouse Savannah River Company, Aiken (1993).
40 CFR 261 App. II, Method 1131 Toxicity Characteristic Leaching Procedure (TCLP), pages 66-81, Revised 7/1/91.
ASTM C 1285-94, Standard Test Methods for Determining Chemical Durability of Nuclear Waste Glasses: The Product Consistency Test (PCT), (1995).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media New York
About this chapter
Cite this chapter
Cicero-Herman, C.A., Whitehouse, J.C., Young, S.R., Erich, D.L. (1998). Pilot-Scale Vitrification of Oak Ridge Central Neutralization Facility (CNF) and B&C Pond Sludges. In: Schulz, W.W., Lombardo, N.J. (eds) Science and Technology for Disposal of Radioactive Tank Wastes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1543-6_27
Download citation
DOI: https://doi.org/10.1007/978-1-4899-1543-6_27
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4899-1545-0
Online ISBN: 978-1-4899-1543-6
eBook Packages: Springer Book Archive