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Photochemistry and Photophysics of Metal Complexes pp 165–215Cite as

Photochemistry, Photophysics, and Photoredox Reactions of Ru(bpy) 2+3 and Related Complexes

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Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

The photochemistry of the tris(bipyridine) ruthenium(II) dication, Ru(bpy) 2+3 , is discussed in a separate chapter because of the pivotal role that this complex has played in the development of inorganic photochemistry, and also because of the continuing role that the complex still plays in the field. The importance of this complex is the result of its having both a rich photophysics and photochemistry. The importance of Ru(bpy) 2+3 is in the way that the photophysics and the photochemistry have developed, this because of discoveries made in the other. A key finding that has spurred much of this development was the initial observation of an orange triplet emission from the complex, an emission that can be observed at ambient temperature. The discovery of such a feature in a stable metal complex has since led to a considerable interest being generated in explaining the nature of this observation, and in exploiting this discovery to develop new photochemical reactions and photoinduced catalytic processes. From the discovery of this emissive property has resulted both a better understanding of the structure of the excited state, and of the photochemistry resulting from it. Well over 1000 papers have been written concerning the chemistry of Ru(bpy) 2+3 and its congeners, and much of the details of this research has been reviewed.(1–20)

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  1. Tulane University, New Orleans, Louisiana, USA

    D. M. Roundhill

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Roundhill, D.M. (1994). Photochemistry, Photophysics, and Photoredox Reactions of Ru(bpy) 2+3 and Related Complexes. In: Photochemistry and Photophysics of Metal Complexes. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1495-8_5

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