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Reactions of Polymers

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Principles of Polymer Chemistry

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Abstract

In consideration of various chemical reactions of macromolecules, the reactivity of their functional groups must be compared to those of small molecules. The comparisons have stimulated many investigations and led to conclusions that functional groups exhibit equal reactivity in both large and small molecules, if the conditions are identical. These conclusions are supported by theoretical evidence.1,2 Specifically, they apply to the following situations1:

  1. 1

    Reactions that take place in homogeneous fluid media with all reactants, intermediates, and end products fully soluble. These conditions exits from the start to the end of the reactions.

  2. 2

    All elementary steps involve only individual functional groups. The other reacting species are small and mobile.

  3. 3

    The steric factors in the low molecular weight compounds selected for comparison must be similar to those of the large molecules.

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Ravve, A. (1995). Reactions of Polymers. In: Principles of Polymer Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1283-1_8

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