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Monomers and Polymers from Hexafluoroacetone

  • Wolfgang K. Appel
  • Bernd A. Blech
  • Michael Stöbbe
Part of the Topics in Applied Chemistry book series (TAPP)

Abstract

It has been known for some years that the incorporation of trifluoromethyl groups, particularly in the form of the 1, 1, 1, 3, 3, 3-hexafluoroisopropylidene function, (CF3)2C (HFIP), into suitable monomers confers a rather unique property profile on the corresponding polymers.1, 2 Among the main advantages are enhanced solubility and processability, higher thermo-oxidative stability, and superior electrical properties. This has led to the synthesis of a large variety of such monomers and polymers, as disclosed in recent reviews.3, 4 The aim of this chapter is to focus on the synthesis of basic intermediates and important monomers, and to highlight important polymer classes containing the 1, 1, 1, 3, 3, 3-hexafluoroisopropylidene moiety.

Keywords

Aromatic Diamine German Patent Aromatic Polyimide Diacid Chloride Terephthaloyl Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1994

Authors and Affiliations

  • Wolfgang K. Appel
    • 1
  • Bernd A. Blech
    • 2
  • Michael Stöbbe
    • 1
  1. 1.HauptlaboratoriumHoechst AGFrankfurt-am-Main 80Germany
  2. 2.RLMTCHoechst Celanese CorporationSummitUSA

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