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Organofluorine Chemistry pp 413–429Cite as

Monomers and Polymers from Hexafluoroacetone

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Part of the book series: Topics in Applied Chemistry ((TAPP))

Abstract

It has been known for some years that the incorporation of trifluoromethyl groups, particularly in the form of the 1, 1, 1, 3, 3, 3-hexafluoroisopropylidene function, (CF3)2C (HFIP), into suitable monomers confers a rather unique property profile on the corresponding polymers.1, 2 Among the main advantages are enhanced solubility and processability, higher thermo-oxidative stability, and superior electrical properties. This has led to the synthesis of a large variety of such monomers and polymers, as disclosed in recent reviews.3, 4 The aim of this chapter is to focus on the synthesis of basic intermediates and important monomers, and to highlight important polymer classes containing the 1, 1, 1, 3, 3, 3-hexafluoroisopropylidene moiety.

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Author information

Authors and Affiliations

  1. Hauptlaboratorium, Hoechst AG, D-6230, Frankfurt-am-Main 80, Germany

    Wolfgang K. Appel & Michael Stöbbe

  2. RLMTC, Hoechst Celanese Corporation, Summit, New Jersey, 07901, USA

    Bernd A. Blech

Authors
  1. Wolfgang K. Appel
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  2. Bernd A. Blech
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  3. Michael Stöbbe
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Editor information

Editors and Affiliations

  1. The University of Manchester Institute of Science and Technology (UMIST), Manchester, UK

    R. E. Banks

  2. DuPont Central Research & Development, Wilmington, Delaware, USA

    B. E. Smart

  3. Editorial Office of the Journal of Fluorine Chemistry, Birmingham, UK

    J. C. Tatlow

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Appel, W.K., Blech, B.A., Stöbbe, M. (1994). Monomers and Polymers from Hexafluoroacetone. In: Banks, R.E., Smart, B.E., Tatlow, J.C. (eds) Organofluorine Chemistry. Topics in Applied Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1202-2_20

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  • DOI: https://doi.org/10.1007/978-1-4899-1202-2_20

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