Abstract
Spontaneous capillary penetration of a liquid into pore spaces filled with a fluid is a flow driven by interfacial pressure differences. The magnitude of the pressure difference across each liquid—fluid interface (meniscus) depends on the local curvature, which is determined by the local wetting properties and pore geometry. The observation that interfacial pressure differences are appreciable only in small pores led to the term capillary, from the Latin capillus for hair. The recorded scientific history of capillary penetration seems to have started with Leonardo da Vinci,(1) who apparently was the first scientist to note capillary rise. More extensive work on the thermodynamics as well as the kinetics of capillary penetration began at the end of the 19th centurv and the beginning of this century.(2–9)
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References
J. J. Bikerman, Physical Surfaces, Academic Press, New York (1970).
F. Bashforth and J. C. Adams, An Attempt To Test the Theories of Capillary Action, University Press, Cambridge, England (1883).
Lord Rayleigh, Proc. R. Soc. London A 92, 184 (1915).
R. Lucas, Kolloid Z. 23, 15 (1918).
S. Sugden, J. Chem. Soc. 119, 1483 (1921).
E. W. Washburn, Phys. Rev. 17, 273 (1921).
F. E. Hackett, Trans. Faraday Soc. 17, 260 (1921).
E. K. Rideal, Philos. Mag. Ser. 6 44, 1152 (1922).
C. H. Bosanquet, Philos. Mag. Ser. 6 45, 525 (1923).
G. M. Homsy, Ann. Rev. Fluid Mech. 19, 271 (1987).
J. A. Wingrave, W. H. Wade, and R. S. Schechter, in Wetting, Spreading and Adhesion (J. F. Padday, ed.), p. 261, Academic Press, New York (1978).
M. R. Moldover and R. W. Gammon, J. Chem. Phys. 80, 528 (1984).
M. Sahimi, B. D. Hughes, L. E. Scriven, and H. T. Davis, Chem. Eng. Sci. 41, 2103 (1986).
J. C. Melrose, Soc. Pet. Eng. J. 5, 259 (1965).
N. R. Morrow, Ind. Eng. Chem. 62, 32 (1970).
J. van Brakel, Powder Technol. 11, 205 (1975).
A. Marmur, Adv. Colloid Interface Sci. 19, 75 (1983).
T. Young, Philos. Trans. R. Soc. London 95, 65 (1805).
A. W. Adamson, Physical Chemistry of Surfaces, 4th ed., Wiley, New York (1982).
E. F. Hare and W. A. Zisman, J. Phys. Chem. 59, 335 (1955).
A. W. Neumann, in Wetting, Spreading and Adhesion (J. F. Padday, ed.), pp. 3–34, Academic Press, New York (1978).
R. J. Good, in Surface and Colloid Science, vol. 11 (R. J. Good and R. R. Stromberg, eds.), p. 1, Plenum Press, New York (1979).
P. G. de Gennes, Rev. Mod. Phys. 57, 827 (1985).
R. N. Wenzel, Ind. Eng. Chem. 28, 988 (1936).
R. E. Johnson, Jr., and R. H. Dettre, in Contact Angle, Wettability, and Adhesion, Adv. Chem. Ser., No. 43, p. 112, Am. Chem. Soc., Washington, DC (1964).
J. D. Eick, R. J. Good, and A. W. Neumann, J. Colloid Interface Sci. 53, 235 (1975).
C. Huh and S. G. Mason, J. Colloid Interface Sci. 60, 11 (1977).
R. G. Cox, J. Fluid Mech. 131, 1 (1983).
J. F. Joanny and P. G. de Gennes, J. Chem. Phys. 81, 552 (1984).
A. B. D. Cassie and S. Baxter, Trans. Faraday Soc. 40, 546 (1944).
L. W. Schwartz and S. Garoff, Langmuir 1, 219 (1985).
G. E. P. Elliott and A. C. Riddiford, J. Colloid Interface Sci. 23, 389 (1967).
R. L. Hoffman, J. Colloid Interface Sci. 50, 228 (1975).
C. G. Ngan and E. B. Dussan V., J. Fluid Mech. 118, 27 (1982).
T-S. Jiang, S. G. Oh, and J. C. Slattery, J. Colloid Interface Sci. 69, 74 (1979).
G. A. Bottomley, Aust. J. Chem. 27, 2297 (1974).
S. Ramakrishnan and S. Hartland, J. Colloid Interface Sci. 80, 497 (1981).
W. J. O’Brien, R. G. Craig, and F. A. Peyton, J. Colloid Interface Sci. 26, 500 (1968).
G. Mason and N. R. Morrow, J. Chem. Soc. Faraday Trans. 1 80, 2375 (1984).
A. Marmur, J. Colloid Interface Sci. 122, 209 (1988).
A. Marmur, J. Colloid Interface Sci. 130, 288 (1989).
D. H. Everett and J. M. Haynes, Z. Phys. Chem. Neue Folge 82, 36 (1972).
D. H. Everett, J. Colloid Interface Sci. 52, 189 (1975).
D. H. Everett and J. M. Haynes, Z. Phys. Chem. Neue Folge 97, 301 (1975).
W. B. Haines, J. Agric. Sci. 17, 264 (1927).
F. E. Hackett and J. S. Strettan, J. Agric. Sci. 18, 671.
W. B. Haines, J. Agric. Sci. 20, 97 (1930).
W. O. Smith, P. D. Foote, and P. F. Busang, Physics 1, 18 (1931).
W. O. Smith, Physics 4, 184 (1933).
N. R. Morrow, J. Can. Pet. Technol. 15, 49 (1976).
Y.-W. Yang, G. Zografi, and E. E. Miller, J. Colloid Interface Sci. 122, 24 (1988).
D. T. Hansford, D. J. W. Grant, and J. M. Newton, Powder Technol. 26, 119 (1980).
J. van Brakel and P. M. Heerthes, Nature 254, 585 (1975).
A. Marmur, J. Colloid Interface Sci. 129, 278 (1989).
L. R. White, J. Colloid Interface Sci. 90, 536 (1982).
S. Ban, E. Wolfram, and S. Rohrsetzer, Colloids Surf. 22, 301 (1987).
Y. Li, W. G. Laidlaw, and N. C. Wardlaw, Adv. Colloid Interface Sci. 26, 1 (1986).
A. Marmur, J. Phys. Chem. 93, 4873 (1989).
A. Marmur, J. Colloid Interface Sci. 123, 161 (1988).
J. M. Bell and F. K. Cameron, J. Phys. Chem. 10, 658 (1906).
R. J. Good, Chem. Ind. 22, 600 (1971).
R. J. Good and N.-J. Lin, J. Colloid Interface Sci. 54, 52 (1976).
J. Szekely, A. W. Neumann, and Y. K. Chuang, J. Colloid Interface Sci. 35, 273 (1971).
J. R. Ligenza and R. B. Bernstein, J. Am. Chem. Soc. 73, 4636 (1951).
L. R. Fisher and P. D. Lark, J. Colloid Interface Sci. 69, 486 (1979).
R. S. Malik, CH. Laroussi, and L. W. de Backer, Soil Sci. 127, 211 (1979).
S. Levine and G. H. Neale, J. Chem. Soc. Faraday Trans. 2 71, 12 (1975).
W. E. Brittin, J. Appl. Phys. 17, 37 (1946).
S. Levine, P. Reed, E. J. Watson, and G. Neale, in Colloid and Interface Science (M. Kerker, ed.), vol. 3, p. 403, Academic Press, New York (1976).
M. F. Letelier S., and H. J. Leutheusser, J. Colloid Interface Sci. 72, 465 (1979).
G. L. Batten, Jr., J. Colloid Interface Sci. 102, 513 (1984).
E. B. Dussan V, Ann. Rev. Fluid Mech. 11, 371 (1979).
T. D. Blake, D. H. Everett, and J. M. Haynes, in Wetting S.C.I. Monog. No. 25, p. 164, Soc. Chem. Ind., London (1967).
C. Huh and S. G. Mason, J. Fluid Mech. 81, 401 (1977).
J. N. Tilton, Chem. Eng. Sci. 43, 1371 (1988).
S. Levine, J. Lowndes, E. J. Watson, and G. Neale, J. Colloid Interface Sci. 73, 136 (1980).
V. V. Berezkin and N. V. Churaev, Colloid J. USSR (USA) 44, 376 (1982).
G. A. Martynov, V. V. Malev, and E. V. Gribanova, Colloid J. USSR (USA) 45, 205 (1983).
T. E. Mumley, C. J. Radke, and M. C. Williams, J. Colloid Interface Sci. 109, 398, 413 (1986).
P.-J. Sell, E. Maisch, and J. Siekmann, Acta Astronaut. 11, 577 (1984).
P.-J. Sell, E. Maisch, and J. Siekmann, Acta Astronaut. 13, 87 (1986).
A. Marmur, Chem. Eng. Sci. 44, 1511 (1989).
H. Fujita, J. Phys. Chem. 56, 625 (1952).
F. W. Minor, A. M. Schwartz, E. A. Wulkow, and L. C. Buckles Text. Res. J. 29, 931 (1959).
T. Gillespie, J. Colloid Sci. 14, 123 (1959).
T. Gillespie and T. Johnson, J. Colloid Interface Sci. 36, 282 (1971).
J. van Brakel and P. M. Heertjes, Powder Technol. 16, 75, 83, 91 (1977).
D. H. Everett, J. M. Haynes, and R. J. L. Miller, in Fiber Water Interactions in Paper Making (Fundamental Research Committee, ed.), BPBIF, London (1978).
R. Williams, J. Colloid Interface Sci. 79, 287 (1981).
Y.-W. Yang, G. Zografi, and E. E. Miller, J. Colloid Interface Sci. 122, 35 (1988).
K. T. Hodgson and J. C. Berg, J. Colloid Interface Sci. 121, 22 (1988).
F. A. L. Dullien, M. S. El-Sayed, and V. K. Batra, J. Colloid Interface Sci. 60, 497 (1977).
S. Levine, J. Lowndes, and P. Reed, J. Colloid Interface Sci. 77, 253 (1980).
S. Levine and G. Neale, in Wetting, Spreading and Adhesion (J. F. Padday, ed.), p. 241, Academic Press, New York (1978).
R. D. Miller and E. E. Miller, J. Appl. Phys. 27, 324 (1956).
T. Gillespie, J. Colloid Sci. 13, 32 (1958).
M. J. Denton, J. Chromatogr. 18, 615 (1965).
E. E. Miller, in Applications of Soil Physics (D. Hillel, ed.), p. 300, Academic Press, New York (1980).
H. S. Carslaw and J. C. Jaeger, Conduction of Heat in Solids, 2nd ed., p. 89, Oxford at the Clarendon Press (1959).
E. Kissa, J. Colloid Interface Sci. 83, 265 (1981).
T. Kawase, S. Gekoguchi, T. Fujii, and M. Minagawa, Text. Res. J. 56, 409 (1986).
A. Marmur, J. Colloid Interface Sci. 124, 301 (1988).
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Marmur, A. (1992). Penetration and Displacement in Capillary Systems. In: Schrader, M.E., Loeb, G.I. (eds) Modern Approaches to Wettability. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1176-6_12
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DOI: https://doi.org/10.1007/978-1-4899-1176-6_12
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