Skip to main content

An Electrochemical Method of Polyimide Metallization

  • Chapter

Abstract

A chemical process for depositing copper films on polyimide substrates is described. The process is dependent upon the reversible electrochemical charge storage of polypyromellitimides in aqueous electrolytes and the reaction of these polymers with aqueous chemical reductants. The process is shown to be continuous, patternable, and produces metal films with high adhesion to the polymer substrate. The adhesion is, however, sensitive to relative humidity. Electrochemical characteristics of chemically and thermally cyclized polyimide are also outlined.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. K.L. Mittal, editor, “Polyimides: Synthesis, Characterization and Applications,” Vols. 1 and 2, Plenum Press, New York, 1984.

    Google Scholar 

  2. R.C. Haushalter and L.J. Krause, Thin Solid Films, 102, 161 (1983).

    Article  CAS  Google Scholar 

  3. R.C. Haushalter and L.J. Krause, in “Polyimides: Synthesis, Characterization and Applications,” K.L. Mittal, editor, Vol. 2, pp. 735–750, Plenum Press, New York, 1984.

    Google Scholar 

  4. S. Mazur and S. Reich, J. Phys. Chem., 90, 1365 (1986).

    Article  CAS  Google Scholar 

  5. Larry J. Krause and Jack A. Rider, U.S. Patent Nos. 4,775,556 (1988) and 4, 710, 403 (1987).

    Google Scholar 

  6. C.E. Sroog, J. Polym. Sci. Macromol. Rev., 11, 161 (1976).

    Article  CAS  Google Scholar 

  7. S. Mazur, P.S. Lugg and C. Yarnitsky, J. Electrochem. Soc, 134, 346 (1987).

    Article  CAS  Google Scholar 

  8. A. Viehbeck, C.A. Kovac, S.L. Buchwalter, M.J. Goldberg and S.L. Tisdale, “Metallization of Polymers,” E. Sacher, J.J. Pireaux and S.P. Kowalczyk, editors, ACS, Washington, D.C., 440. chapter 29 (1990).

    Google Scholar 

  9. S. Mazur, L.E. Manring, M. Levy, G.T. Dee, S. Reich and C.L. Jackson, in “Metallized Plastics 1: Fundamental and Applied Aspects,” K.L. Mittal and J.R. Susko, editors, Plenum Press, New York, 1989.

    Google Scholar 

  10. L.J. Krause and J.L. Bales, J. Electrochem. Soc, 135, 1365 (1988).

    Article  Google Scholar 

  11. L.J. Krause, P.S. Lugg and T.A. Speckhard, J. Electrochem. Soc, 136, 1379 (1989).

    Article  CAS  Google Scholar 

  12. R.L. Pecksok and R.S. Juvet, J. Am. Chem. Soc., 75, 1202 (1953).

    Article  Google Scholar 

  13. R.W. Murray, in “Electroanalytical Chemistry, A Series of Advances,” Allen J. Bard, editor, Marcel Dekker Inc., New York, 13, 191 (1984).

    Google Scholar 

  14. C.P. Andrieux and J.M. Saveant, J. Electroanal. Chem., 111, 377 (1980).

    Article  CAS  Google Scholar 

  15. N.J. Chou and C.H. Tang, J. Vac. Sci. Technol. A2(2), 751 (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media New York

About this chapter

Cite this chapter

Krause, L.J., Speckhard, T.A. (1991). An Electrochemical Method of Polyimide Metallization. In: Mittal, K.L. (eds) Metallized Plastics 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0735-6_1

Download citation

  • DOI: https://doi.org/10.1007/978-1-4899-0735-6_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0737-0

  • Online ISBN: 978-1-4899-0735-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics