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Gold-197 Mössbauer Spectroscopy in the Characterization of Gold Compounds

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Mössbauer Spectroscopy Applied to Inorganic Chemistry

Part of the book series: Modern Inorganic Chemistry ((MICE,volume 1))

Abstract

It was demonstrated about ten years ago that 197Au Mössbauer spectroscopy would be useful in the characterization of gold compounds. Mössbauer,1 Shirley,2 and Nicholls; showed that, although neither the isomer shift (IS) nor the quadrupole splitting (QS) alone would allow gold(I) and gold(III) to be distinguished, when the two parameters are taken together diagnosis of the oxidation state is simple. At that time there was little interest in the chemistry of gold, but recently there has been a revival of activity, with the discovery of compounds of gold(II) and gold(V), the cluster compounds, and the ability of gold(I) to expand its coordination number from two to three or four. In all these cases, the Mössbauer spectra have been of value in characterizing the new compounds.

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References

  1. H.D. Bartunik, W. Potzel, R.L. Mössbauer, and G. Kaindl, Z. Phys. 240, 1 (1970).

    Article  CAS  Google Scholar 

  2. M.O. Fattens and D.A. Shirley, J. Chem. Phys. 53, 4249 (1970).

    Article  Google Scholar 

  3. J.S. Charlton and D.I. Nicholls, J. Chen. Soc. (A) 1970, 1484.

    Google Scholar 

  4. A.G. Blackman, D.A. Landman, and A. Lurio, Phys. Rev. 110, 865 (1958).

    Article  Google Scholar 

  5. R.L. Cohen, Phys. Rev. 171, 343 (1968).

    Article  CAS  Google Scholar 

  6. G.M. Kalvius and G.K. Shenoy, At. Data Nuel. Data Tables 14, 639 (1974).

    Article  CAS  Google Scholar 

  7. M.P.A. Viegers and J.M. Trooster, Nucl. Instrum. Methods 118, 257 (1974).

    Article  CAS  Google Scholar 

  8. R.V. Parish, O. Parry, and C.A. McAuliffe, J. Chem. Soc. Dalton Trans. 1981, 2098.

    Google Scholar 

  9. P.G. Jones, A.G. Maddock, M.J. Mays, M.M. Muir, and A.F. Williams, J. Chem. Soc. Dalton Trans. 1977, 1434.

    Google Scholar 

  10. M.P.A. Viegers, Ph.D. thesis, Catholic University of Nijmegen, Netherlands, 1976. Many of these data are quoted by P. Gütlich, R. Link, and A. Trautwein, Mössbauer Spectroscopy and Transisiton Metal Chemistry,Springer-Verlag, Berlin, 1978.

    Google Scholar 

  11. K. Brown, R.V. Parish, and C.A. McAuliffe, J. Am. Chem. Soc. 103, 4943 (1981).

    Article  CAS  Google Scholar 

  12. C.A. McAuliffe, R.V. Parish, and P.D. Randall, J. Chem. Soc. Dalton Trans. 1977, 1426.

    Google Scholar 

  13. R.V. Parish and J.D. Rush, Chem. Phys. Lett. 63, 37 (1979).

    Article  CAS  Google Scholar 

  14. A.K.H. Al-Saady, K. Brown, R.V. Parish, and C.A. McAuliffe, Proc. Int. Conf. Applications Mössbauer Spectrosc., Jaipur, India, 1982. Proc. Indian Nat. Acad. Sci., Physical Sciences Special Volume, New Delhi, 1982, p. 717.

    Google Scholar 

  15. W. Potzel and G.J. Perlow, Phys. Rev. Lett. 29, 910 (1972).

    Article  Google Scholar 

  16. E. Baggio-Saitovich, U. Wagner, F.E. Wagner, and J. Danon, Proc. Int. Conf. Mlissbauer Spectrosc., Cracow, Vol. 1, p. 223, 1975.

    Google Scholar 

  17. G. van Koten and J.G. Noltes, J. Organometal. Chem. 174, 367 (1979).

    Article  Google Scholar 

  18. H. Prosser, F.E. Wagner, G. Wortmann, G.M. Kalvius, and R. Wäppling, Hyperfine Interact. 1, 25 (1975).

    Article  CAS  Google Scholar 

  19. T.K. Sham, R.E. Watson, and M.L. Perlman, Adv. Chem. Ser. 194, 39 (1981).

    Article  CAS  Google Scholar 

  20. E.L. Muetterties, W.G. Peet, P.A. Wegner, and C.A. Alegranti, Inorg. Chem. 9, 2447 (1970).

    Article  CAS  Google Scholar 

  21. E.L. Muetterties and C. A. Alegranti, J. Am. Chem. Soc. 92, 4114 (1970).

    Article  CAS  Google Scholar 

  22. C.B. Colburn, W.E. Hill, R.V. Parish, and C.A. McAuliffe, J. Chem. Soc. Chem. Commun. 1979, 218.

    Google Scholar 

  23. M.J. Mays and P.A. Vergnano, J. Chem. Soc. Dalton Trans. 1979, 1112.

    Google Scholar 

  24. P.G. Jones, J. Chem. Soc. Chem. Commun. 1980, 1031.

    Google Scholar 

  25. G.C.H. Jones, P.G. Jones, A.G. Maddock, M.J. Mays, P.A. Vergnano, and A.F. Williams, J. Chem. Soc. Dalton Trans. 1977, 1440.

    Google Scholar 

  26. H. Schmidbaur, F.E. Wagner, and A. Wohlleben-Hammer, Chem. Ber. 112, 496 (1979).

    Article  CAS  Google Scholar 

  27. R.V. Parish and J.D. Rush, unpublished data.

    Google Scholar 

  28. W. Clegg, Acta Cryst. B34, 278 (1978).

    Article  Google Scholar 

  29. M.J. Mays and P.L. Sears, J. Chem. Soc. Dalton Trans. 1974, 2254.

    Google Scholar 

  30. R.V. Parish, Coord. Chem. Rev. 42, I (1982).

    Google Scholar 

  31. W. Clegg, Acta Cryst. B32, 2712 (1976).

    Article  Google Scholar 

  32. N.C. Baenziger, W.E. Bennett, and D.M. Soboroff, Acta Cryst. B32, 692 (1976).

    Article  Google Scholar 

  33. P. Bellon, M. Manassero, and M. Sansoni, Ric. Sci. 39, 173 (1969).

    CAS  Google Scholar 

  34. P.D. Gavens, J.J. Guy, M.J. Mays, and G.M. Shedrick, Acta Cryst. B33, 136 (1977).

    Google Scholar 

  35. R.W. Baker and P.J. Pauling, J. Chem. Soc. Dalton Trans. 1972, 2264.

    Google Scholar 

  36. C.J. Gilmore and P. Woodward, Chem. Commun. 1971, 1233.

    Google Scholar 

  37. H. Schmidbaur, A. Wohlleben, F.E. Wagner, O. Orama, and G. Hüttner, Chem. Ber. 110, 1748 (1977).

    Article  CAS  Google Scholar 

  38. J.A. Muir, M.M. Muir, and E. Lorca, Acta Cryst. B 36, 931 (1980).

    Article  Google Scholar 

  39. H.H. Guy, P.G. Jones, and G.M. Sheldrick, Acta Cryst. B32, 1973 (1976).

    Google Scholar 

  40. N.C. Baenziger, K.M. Dittmore, and J.R. Doyle, Inorg. Chem. 13, 805 (1974).

    Article  CAS  Google Scholar 

  41. L.J. Guggenberger, J. Organometal. Chem. 81, 271 (1974).

    Article  Google Scholar 

  42. R.C. Elder, E.H. Kelle-Zieher, M. Onady, and R.L. Whittle, J. Chem. Soc. Chem. Commun. 1981, 900.

    Google Scholar 

  43. J.G. Wijnhoven, W.P.J.H. Bosman, and P.T. Beurskens, J. Cryst. Mol. Struct. 2, 7 (1972).

    Article  CAS  Google Scholar 

  44. R.V. Parish and P.J. Rowbotham, J. Chem. Soc. Dalton Trans. 1973, 37.

    Google Scholar 

  45. P.G. Jones, G.M. Sheldrick, J.A. Muir, M.M. Muir, and L.B. Pulgar, J. Chem. Soc. Dalton Trans. 1982, 2123.

    Google Scholar 

  46. S.H. Hong, A. Olin, and R. Hesse, Acta Chem. Scand. A29, 583 (1975).

    Article  Google Scholar 

  47. I.G. Dance, Inorg. Chim. Acta. 25, L17 (1977).

    Article  CAS  Google Scholar 

  48. I.G. Dance, L.J. Fitzpatrick, A.D. Rae, and M.L. Scudder, Inorg. Chem. 22, 3785 (1983).

    Article  CAS  Google Scholar 

  49. A.K.H. Al-Saady, C.A. McAuliffe, R.V. Parish and R. Fields, J. Chem. Soc. Dalton Trans. 1984, 491.

    Google Scholar 

  50. H.D. Bartunik, W.F. Holzapfel, and R.L. Mössbauer, Phys. Lett. A33, 469 (1970).

    Article  CAS  Google Scholar 

  51. B.W. Dale, R.J. Dickinson, and R.V. Parish, Chem. Phys. Lett. 64, 357 (1979).

    Article  Google Scholar 

  52. M. Katada, Y. Uchida, K. Sato, H. Sano, H. Sakai, and Y. Maeda, Bull. Soc. Chem. Jpn 55, 444 (1982).

    Article  CAS  Google Scholar 

  53. C.A. McAuliffe, K. Moss, and R.V. Parish, unpublished data.

    Google Scholar 

  54. E. Baggio-Saitovich, U. Wagner, F.E. Wagner, and J. Danon, Notas. Fis. 23, 243 (1974).

    Google Scholar 

  55. A. Johnson and R.J. Puddephatt, J. Chem. Soc. Dalton Trans. 1978, 980.

    Google Scholar 

  56. W.T. Robinson and E. Sinn, J. Chem. Soc. Dalton Trans. 1975, 726.

    Google Scholar 

  57. H. van Kempen, J.A.A.J. Pereboom, and M.P.A. Viegers, Proc. 14th Int. Conf. Low Temp. Phys., Ed. M. Krusius and M. Vuoria, eds., North-Holland, New York, 1975, Vol. 4, p. 372.

    Google Scholar 

  58. J.A.J. Jarvis, A. Johnson, and R.J. Puddephatt, J. Chem. Soc. Chem. Commun. 1973, 373.

    Google Scholar 

  59. H.D. Bartunik and G. Kaindl, in Mössbauer Isomer Shifts, G.K. Shenoy and F.E. Wagner, eds., North-Holland, New York, 1978, p. 535.

    Google Scholar 

  60. T.P.A. Viegers, J.M. Trooster, P. Bouten, and T.P. Rit, J. Chem. Soc. Dalton Trans. 1977, 2074.

    Google Scholar 

  61. J. Stanek, J. Chem. Phys. 76, 2315 (1982).

    Article  CAS  Google Scholar 

  62. H. Prosser, Diplomarbeit, Tech. Univ. Munich, (1973) (quoted in Reference 59).

    Google Scholar 

  63. F.H. Brain, C.S. Gibson, J.A.J. Jarvis, R.F. Phillips, H.M. Powell, and A. Tyabji, J. Chem. Soc. 1952, 3686.

    Google Scholar 

  64. W. Denner, H. Schulz, and H. D’Amour, Acta Cryst. A35, 360 (1979).

    Google Scholar 

  65. J. Stanek, S.S. Hafner, and H. Schulz, Phys. Lett. A76, 333 (1980).

    Article  Google Scholar 

  66. P. Gütlich, B. Lehnis, K. Römhild, and J. Strähle, Z. Naturforsch. 37B, 550 (1982).

    Google Scholar 

  67. H. Schmidbaur, A. Wohlleben, F.E. Wagner, D.F. van der Vondel, and G.P. van der Kelen, Chem. Ber. 110, 2758 (1977).

    Article  CAS  Google Scholar 

  68. H. Schmidbaur, J.R. Mandl, F.E. Wagner, D.F. van der Vondel, and G.P. van der Kelen, J. Chem. Soc. Chem. Commun. 1976, 170.

    Google Scholar 

  69. H. Schmidbaur, J.R. Mandl, A. Frank, and G. Hüttner, Chem. Ber. 109, 466 (1976).

    Article  CAS  Google Scholar 

  70. G. Kaindl, K. Leary, and N. Bartlett, J. Chem. Phys. 59, 5050 (1973).

    Article  CAS  Google Scholar 

  71. V.B. Sokolov, V.G. Tsinoev, and A.V. Ryzhkov, Teor. Eksp. Khim. 16 345 (1980). [English version, Theor. Exp. Chem. 16 270 (1980).]

    Google Scholar 

  72. K. Leary, A. Zalkin, and N. Bartlett, Inorg. Chem. 13, 775 (1974).

    Article  CAS  Google Scholar 

  73. F.A. Vollenbroek, P.C.P. Bouten, J.M. Trooster, J.P. van den Berg, and J.J. Bour, Inorg. Chem. 17, 1345 (1978).

    Article  CAS  Google Scholar 

  74. F.A. Vollenbroek, J.J. Bour, J.M. Trooster, and J.W.A. van der Velden, J. Chem. Soc. Chem. Commun. 1978, 907.

    Google Scholar 

  75. J.W.A. van der Velden, J.J. Bour, W.P.J. Bosman, and J.H. Noordik, J. Chem. Soc. Chem. Commun. 1218 (1981).

    Google Scholar 

  76. P. Bellon, M. Manassero, and M. Sansoni, J. Chem. Soc. Dalton Trans. 1972, 1481.

    Google Scholar 

  77. M. Manassero, L. Naldini, and M. Sansoni, J. Chem. Soc. Chem. Commun. 1979, 385.

    Google Scholar 

  78. L.D. Roberts, D.O. Patterson, J.O. Thomson, and R.P. Levy, Phys. Rev. 179, 656 (1969).

    Article  CAS  Google Scholar 

  79. T.K. Sham, R.E. Watson, and M.L. Perlman, Phys. Rev. B 20, 3552 (1979).

    Article  CAS  Google Scholar 

  80. T.K. Sham, M.L. Perlman, and R.E. Watson, Phys. Rev. B 19, 539 (1979).

    Article  CAS  Google Scholar 

  81. G. Schmid, R. Pfeil, R. Boesa, F. Bandermann, S. Meyer, G.H.M. Calls, and J.W.A. van der Velden, Chem. Ber. 114, 3634 (1981).

    Article  CAS  Google Scholar 

  82. J.W.A. van der Velden, J.J. Bour, J.J. Steggerda, P.T. Beurskens, M. Roseboom, and J.H. Noordik, Inorg. Chem. 21, 4321 (1982).

    Article  Google Scholar 

  83. J.W.A. van der Velden, F.A. Vollenbroek, J.J. Bour, P.T. Beurskens, J.M.M. Smits, and W.P. Bosman, Rec. Tray. Chim. Pays Bas 100, 148 (1981).

    Article  Google Scholar 

  84. B.D. Dunlap, J.B. Darby, and C.W. Kimball, Phys. Lett. 25A, 431 (1967).

    Article  CAS  Google Scholar 

  85. R.L. Cohen, R.C. Sherwood, and J.H. Wernick, Phys. Lett. 26A, 462 (1968).

    Article  CAS  Google Scholar 

  86. D.O. Patterson, J.O. Thomson, P.G. Huray, and L.D. Roberts, Phys. Rev. B 2, 2440 (1970).

    Article  Google Scholar 

  87. G.K. Wertheim, R.L. Cohen, G. Crecelius, K.W. West, and J.H. Wernick, Phys. Rev. B 20, 806 (1979).

    Article  Google Scholar 

  88. P. Gütlich, S. Odar, and A. Weiss, J. Phys. Chem. Solids 37, 1011 (1976).

    Article  Google Scholar 

  89. Summary discussion by R.L. Cohen, in Mössbauer Isomer Shifts, G.K. Shenoy and F.E. Wagner, eds., North-Holland, Amsterdam, 1978, p. 548.

    Google Scholar 

  90. P.G. Huray, L.D. Roberts, and J.O. Thomson, Phys. Rev. B 4, 2147 (1971).

    Article  Google Scholar 

  91. T.K. Sham, M.L. Perlman, and R.E. Watson, Phys. Rev. B 19, 539 (1979).

    Article  CAS  Google Scholar 

  92. R.M. Friedman, J. Hudis, M.L. Perlman, and R.E. Watson, Phys. Rev. B 8, 2433 (1973).

    Article  CAS  Google Scholar 

  93. D.J. Erickson and L.D. Roberts, Phys. Rev. B 9, 3650 (1974).

    Article  CAS  Google Scholar 

  94. J.O. Thompson, F.E. Obenshain, P.G. Huray, J.C. Love, and J. Burton, Phys. Rev. B 11, 1835 (1975).

    Article  Google Scholar 

  95. S.L. Lawton, W.J. Rohrbaugh, and G.T. Kokotailo, Inorg. Chem. 11, 2227 (1972).

    Article  CAS  Google Scholar 

  96. T.S. Chou, M.L. Perlman, and R.E. Watson, Phys. Rev. B 14, 3248 (1976).

    Article  CAS  Google Scholar 

  97. K. Moss, R.V. Parish, L.S. Sayegh, and C.A. McAuliffe, unpublished observations.

    Google Scholar 

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  1. Department of Chemistry, The University of Manchester Institute of Science and Technology, Manchester, M60 1QD, England

    R. V. Parish

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  1. Department of Chemistry, University of Missouri-Rolla, 65401, Rolla, Missouri, USA

    Gary J. Long

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Parish, R.V. (1984). Gold-197 Mössbauer Spectroscopy in the Characterization of Gold Compounds. In: Long, G.J. (eds) Mössbauer Spectroscopy Applied to Inorganic Chemistry. Modern Inorganic Chemistry, vol 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0462-1_17

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